Glyceric acid

Base Information

• Chemical Name: Glyceric acid
• CAS No.: 473-81-4
• Molecular Formula: C3H6O4
• Molecular Weight: 106.078
• European Community (EC) Number: 207-472-9,676-425-6
• NSC Number: 9227
• UNII: 70KH64UX7G
• DSSTox Substance ID: DTXSID80861979
• Nikkaji Number: J5.966H
• Wikipedia: Glyceric_acid
• Wikidata: Q424906
• Mol file: 473-81-4.mol

Synonyms:glyceric acid;glyceric acid, (+-)-isomer;glyceric acid, (R)-isomer;glyceric acid, (S)-isomer;glyceric acid, monopotassium salt

Chemical Property of Glyceric acid

Chemical Property:

• Vapor Pressure: 1.65E-08mmHg at 25°C
• Melting Point: <25 °C
• Refractive Index: 1.515
• Boiling Point: 412 °C at 760 mmHg
• PKA: 3.52(at 25℃)
• Flash Point: 217.1 °C
• PSA: 77.76000
• Density: 1.558 g/cm³
• LogP: -1.57580
• Storage Temp.: 2-8°C
• XLogP3: -1.5
• Hydrogen Bond Donor Count: 3
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 2
• Exact Mass: 106.02660867
• Heavy Atom Count: 7
• Complexity: 69.3

Purity/Quality:

98%,99%, ^*data from raw suppliers

2,3-DihydroxypropanoicAcid(20%inwater) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(C(C(=O)O)O)O
• Description: Glyceric acid is a natural three - carbon sugar acid . Salts and esters of glyceric acid are known as glycerates.

Technology Process of Glyceric acid

There total 326 articles about Glyceric acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

meso-erythritol (909878-64-4,10030-58-7,188346-77-2,149-32-6) → D-erythrulose (533-50-6,35007-64-8,40031-31-0,496-55-9) + D-glyceric acid (473-81-4,600-19-1,6000-40-4,28305-26-2,118916-26-0) + D-erythronic acid (488-16-4) + D-erythrose (583-50-6)

Guidance literature:

PtTl; In perchloric acid; water; for 4h; Product distribution; electrocatalytic reaction; also on Pt and on Pt-Pb electrode; oxidation potential varied: 0.45, 0.6, 0.8 V;

DOI:10.1051/jcp:1999157

Reference yield:

glycerol (56-81-5,25618-55-7,64333-26-2,8013-25-0) → glyceric acid (473-81-4,118916-26-0) + hydrogen (1333-74-0) + carbonate(2-) (3812-32-6) + rac-glycerate

Guidance literature:

With water; potassium hydroxide; at 60 ℃; Electrolysis;

DOI:10.1016/j.ica.2021.120245

Reference yield:

D-Galactose (10257-28-0) → glyceric acid (473-81-4,118916-26-0) + D-galactonic acid (133-42-6,488-33-5,526-95-4,526-97-6,576-36-3,642-99-9,1114-17-6,3956-93-2,6906-37-2,7760-07-8,13382-27-9,20246-33-7,20246-35-9,20246-52-0,20246-53-1,21675-42-3,22430-69-9,24871-35-0,28223-42-9,28278-17-3,51547-37-6) + threonic acid + erythronic acid + xylonic acid + lyxonic acid

Guidance literature:

With sodium hydroxide; N-chloro-4-methylbenzenesulfonamide; In water; at 29.9 - 44.9 ℃; for 24h; Kinetics; Thermodynamic data; Product distribution; effects of NaClO₄ and conc. of NaOH; solvent-isotope effects in D₂O/H₂O;

DOI:10.1016/S0008-6215(98)00046-9

upstream raw materials:

D-Fructose

D-Mannose

Glyceraldehyde

2,3-diaminopropanoic acid

Downstream raw materials:

methyl glycerate

methyl (2R)-2,3-dihydroxypropanoate

D-glyceric acid

(S)-glyceric acid

Refernces

• 1、 -. "PROCESSES FOR PREPARING ALDARIC, ALDONIC, AND URONIC ACIDS". Paragraph 0110-0111. . Retrieved 2021/05/29.
• 2、 Deng, Lidan,Liu, Xiaowei,Xu, Jie,Zhou, Zijian,Feng, Shixiang,Wang, Zheng,Xu, Minghou. "Transfer hydrogenation of CO2into formaldehyde from aqueous glycerol heterogeneously catalyzed by Ru bound to LDH". supporting information. p. 5167 - 5170. Retrieved 2021/05/31.