Glyceraldehyde

Base Information

• Chemical Name: Glyceraldehyde
• CAS No.: 56-82-6
• Deprecated CAS: 367-47-5
• Molecular Formula: C3H6 O3
• Molecular Weight: 90.0788
• Hs Code.: 29124990
• European Community (EC) Number: 200-290-0,206-695-9
• NSC Number: 67934
• UNII: DI19XSG16H
• DSSTox Substance ID: DTXSID90861586
• Nikkaji Number: J5.790H
• Wikipedia: Glyceraldehyde
• Wikidata: Q423211
• Pharos Ligand ID: LPXRBM1A5KKY
• Metabolomics Workbench ID: 124294
• ChEMBL ID: CHEMBL173813
• Mol file: 56-82-6.mol

Synonyms:Glyceraldehyde

Chemical Property of Glyceraldehyde

Chemical Property:

• Melting Point: 144-145oC(lit.)
• Refractive Index: 1.4540 (estimate)
• Boiling Point: 107.25°C (rough estimate)
• PKA: 12.60±0.20(Predicted)
• PSA: 57.53000
• Density: 1.593 g/cm3 (-5℃)
• LogP: -1.46150
• Storage Temp.: 2-8°C
• Solubility.: Methanol (Slightly), Water (Slightly, Sonicated))
• Water Solubility.: 29.13g/L(18 oC)
• XLogP3: -1.6
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 2
• Exact Mass: 90.031694049
• Heavy Atom Count: 6
• Complexity: 43.3

Purity/Quality:

GC ≥90% ^*data from raw suppliers

DL-Glyceraldehyde ^*data from reagent suppliers

Safty Information:

• Safety Statements: 24/25

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Biological Agents -> Monosaccharides and Derivatives
• Canonical SMILES: C(C(C=O)O)O
• Uses: Isotope labelled Glyceraldehyde is the simplest of all aldoses and have been shown to be the one of the carbonyl metabolite of dietary fructose. DL-Glyceraldehyde has been used:as modifying reagent in the preparation of crystallization solution as a substrate to measure aldose reductase activityin the preparation of d/l-glyceraldehyde stock to determine the specific activity of GAPDH (glyceraldehyde 3-phosphate dehydrogenase)

Technology Process of Glyceraldehyde

There total 144 articles about Glyceraldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

methanol (67-56-1) + sucrose → D-Mannose (530-26-7) + (S)-Methyl lactate (27871-49-4,2155-30-8) + 2-methoxyethyl vinyl ether (1663-35-0) + methyl 2-hydroxybut-3-enoate (5837-73-0) + 1,1-dihydroxyacetone (1186-47-6) + Glyceraldehyde (56-82-6,367-47-5,26793-98-6) + glycoaldehyde diethyl acetal (621-63-6)

Guidance literature:

With potassium carbonate; at 160 ℃; for 16h; Reagent/catalyst; Flow reactor;

Reference yield: 45.0%

D-glucose (50-99-7) → formic acid (64-18-6) + glycolic Acid (79-14-1) + D-Fructose (57-48-7,18875-34-8) + Glyceraldehyde (56-82-6,367-47-5,26793-98-6)

Guidance literature:

With dihydrogen peroxide; calcium oxide; In water; at 89.84 ℃; for 2h; Reagent/catalyst; Temperature; Concentration; Time;

DOI:10.1002/open.202100074

Reference yield:

ethylene glycol (107-21-1) → methanol (67-56-1) + formaldehyd (50-00-0,30525-89-4,61233-19-0) + formic acid (64-18-6) + methane (34557-54-5,27936-85-2) + carbon dioxide (124-38-9,18923-20-1) + carbon monoxide (201230-82-2) + hydrogen (1333-74-0) + acetaldehyde (75-07-0,9002-91-9) + acetic acid (64-19-7,77671-22-8) + Glyceraldehyde (56-82-6,367-47-5,26793-98-6)

Guidance literature:

With 1 wt.percent mixtures of Rh and RhOx/TiO₂; In water; at 14.84 ℃; for 12h; under 750.075 Torr; Wavelength; Reagent/catalyst; UV-irradiation; Inert atmosphere;

DOI:10.1016/j.jcat.2016.02.021

upstream raw materials:

D-Fructose

L-sorbose

2-Phenyl-4H-[1,3]dioxin

3,3-diethoxypropane-1,2-diol

Downstream raw materials:

dihydroxyacetone

LACTIC ACID

(d,l) isopropylidene glyceraldehyde

L-Lactic acid

Refernces

• 1、 Duo, Jia,Jin, Binbin,Jin, Fangming,Shi, Xiaoyu,Wang, Tianfu,Ye, Xin,Zhong, Heng. "Photothermal strategy for the highly efficient conversion of glucose into lactic acid at low temperatures over a hybrid multifunctional multi-walled carbon nanotube/layered double hydroxide catalyst". . p. 813 - 822. Retrieved 2022/02/09.
• 2、 Takagaki, Atsushi,Obata, Wataru,Ishihara, Tatsumi. "Oxidative Conversion of Glucose to Formic Acid as a Renewable Hydrogen Source Using an Abundant Solid Base Catalyst". . p. 954 - 959. Retrieved 2021/07/14.