Periodate

Base Information

• Chemical Name: Periodate
• CAS No.: 15056-35-6
• Molecular Formula: IO4
• Molecular Weight: 190.902
• UNII: B45A1BUM4Q
• DSSTox Substance ID: DTXSID80164573
• Nikkaji Number: J301.867I
• Wikipedia: Periodate
• Wikidata: Q27104724
• Mol file: 15056-35-6.mol

Synonyms:metaperiodate;NaIO4 compound;periodate;periodate ion;sodium metaperiodate;sodium periodate

Chemical Property of Periodate

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: g/cm³
• XLogP3: -1.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 190.88413
• Heavy Atom Count: 5
• Complexity: 95.8

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [O-]I(=O)(=O)=O

Technology Process of Periodate

There total 5 articles about Periodate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

oxygen (80937-33-3) + ozone (10028-15-6) + potassium iodide (7681-11-0) → iodine pentoxide (12029-98-0,7790-35-4) + periodate (15056-35-6) + iodate (15454-31-6)

Guidance literature:

With Na₂CO₃ or K₂CO₃; In not given; reaction by use of a O3-O2 mixture in a Na2CO3- or K2CO3-containing alcaline 0.1n-KI soln. for a period of 20-30 min.;;

Reference yield:

water (7732-18-5) + iodine (7553-56-2,12190-71-5,8031-47-8) → hydriodic acid (7782-68-5) + periodate (15056-35-6)

Guidance literature:

With HNO₃ (< 2 mol H₂O / mol HNO₃ ); In not given; formation of a yellow powder (probably HNO3, I2, O2), steaming off the HNO3 in dried air at normal temp., residue of HIO3, IO4;;

Reference yield:

iodide (14362-44-8,20461-54-5,69239-56-1) + permanganate(VII) ion (14333-13-2) → manganate(VI) (14333-14-3) + manganese(IV) oxide (1313-13-9) + periodate (15056-35-6)

Guidance literature:

In not given; in presence of Ba(2+), in strong alkaline soln.;

upstream raw materials:

water

iodine

oxygen

ozone

Downstream raw materials:

formaldehyd

formic acid

ammonia

carbon dioxide