Methyl 2-O,3-O,4-O,6-O-tetrakis(trimethylsilyl)-α-D-galactopyranoside

Base Information

Chemical Name:Methyl 2-O,3-O,4-O,6-O-tetrakis(trimethylsilyl)-α-D-galactopyranoside
CAS No.:4133-45-3
Molecular Formula:C19H46O6Si4
Molecular Weight:482.90694
Hs Code.:
Mol file:4133-45-3.mol

Synonyms:Methyl 2-O,3-O,4-O,6-O-tetrakis(trimethylsilyl)-α-D-galactopyranoside

Suppliers and Price of Methyl 2-O,3-O,4-O,6-O-tetrakis(trimethylsilyl)-α-D-galactopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Methyl 2-O,3-O,4-O,6-O-tetrakis(trimethylsilyl)-α-D-galactopyranoside

Chemical Property:

PSA：55.38000
LogP:4.86950

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Methyl 2-O,3-O,4-O,6-O-tetrakis(trimethylsilyl)-α-D-galactopyranoside

There total 11 articles about Methyl 2-O,3-O,4-O,6-O-tetrakis(trimethylsilyl)-α-D-galactopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 999-97-3
1,1,1,3,3,3-hexamethyl-disilazane

: 3396-99-4
methyl α-D-galactopyranoside

: 4133-45-3
methyl 2,3,4,6-tetra-O-trimethylsilyl-α-D-galactopyranoside

Guidance literature:: With trimethylsilyl trifluoromethanesulfonate; In dichloromethane; at 20 ℃; for 0.333333h; Inert atmosphere;
DOI:10.1002/ejoc.201101267

Reference yield:

: 67-56-1
methanol

: 75-77-4
chloro-trimethyl-silane

[GlcA-Rha]27[IdoA-Rha]6[GlcA-Rha-Xyl]7GlcA₉Glc₄[SO₃-]26: [GlcA-Rha]27[IdoA-Rha]6[GlcA-Rha-Xyl]7GlcA₉Glc₄[SO₃-]26

: 25561-30-2
N,O-Bis(trimethylsilyl)trifluoroacetamide

: C₁₃H₂₆O₆Si₂

: 3370-86-3
methyl 2,3,4-tri-O-(trimethylsilyl)-α/β-D-xylopyranoside

: 109100-61-0
O¹-methyl-O²,O⁵-bis-trimethylsilanyl-β-D-glucofuranuronic acid-lactone

: 1769-06-8,2296-39-1,2296-40-4,2641-79-4,3504-67-4,3504-69-6,3504-70-9,3504-71-0,3504-73-2,4002-00-0,4133-45-3,83946-62-7,83946-63-8,83946-64-9
methyl 2,3,4,6-tetrakis-O-(trimethylsilyl)-α/β-D-glucopyranoside

: 56271-60-4,56271-59-1
(3R,4R,5S,6S)-2-Methoxy-6-methyl-3,4,5-tris-trimethylsilanyloxy-tetrahydro-pyran

: C₁₉H₄₄O₇Si₄

Guidance literature:: methanol; [GlcA-Rha]27[IdoA-Rha]6[GlcA-Rha-Xyl]7GlcA₉Glc₄[SO₃-]26; With hydrogenchloride; at 100 ℃; for 4h;

chloro-trimethyl-silane; N,O-Bis(trimethylsilyl)trifluoroacetamide; With pyridine; at 80 ℃; for 0.5h;
DOI:10.1016/j.carbpol.2011.12.041

Reference yield:

: 67-56-1
methanol

: 168138-24-7
Carbamic acid (2R,3R,4S,5S,6R)-3,5-dihydroxy-2-hydroxymethyl-6-((2R,3S,4S,5S,6S)-2,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-3-yloxy)-tetrahydro-pyran-4-yl ester

: 1769-06-8,2296-39-1,2296-40-4,2641-79-4,3504-67-4,3504-69-6,3504-70-9,3504-71-0,3504-73-2,4002-00-0,4133-45-3,83946-62-7,83946-63-8,83946-64-9
(2R,3S,4S,5R,6S)-2-Methoxy-3,4,5-tris-trimethylsilanyloxy-6-trimethylsilanyloxymethyl-tetrahydro-pyran

: Carbamic acid (2S,3S,4S,5R,6R)-2-methoxy-3,5-bis-trimethylsilanyloxy-6-trimethylsilanyloxymethyl-tetrahydro-pyran-4-yl ester

Guidance literature:: With hydrogenchloride; Sylon HTP; Product distribution; multistep reaction; 1.) 85 deg C, 24 h;
DOI:10.1016/0008-6215(88)85043-2