Methyl acrylate

Base Information

• Chemical Name: Methyl acrylate
• CAS No.: 96-33-3
• Deprecated CAS: 102256-29-1,1254182-69-8,2408240-60-6,1254182-69-8
• Molecular Formula: C₄H₆O₂
• Molecular Weight: 86.0904
• Hs Code.: 2916 12 00
• European Community (EC) Number: 202-500-6
• ICSC Number: 0625
• NSC Number: 24146
• UN Number: 1919
• UNII: WC487PR91H
• DSSTox Substance ID: DTXSID0024183
• Nikkaji Number: J3.967E
• Wikipedia: Methyl acrylate,Methyl_acrylate
• Wikidata: Q343028
• RXCUI: 1367155
• Metabolomics Workbench ID: 46320
• ChEMBL ID: CHEMBL9019
• Mol file: 96-33-3.mol

Synonyms:Acrylicacid methyl ester (6CI,8CI);2-Propenoic acid methyl ester;Methoxycarbonylethylene;Methyl acrylic ester;Methylprop-2-enoate;Methyl propenoate;NSC 24146;Methyl Acrylate(MA);

 This product is a nationally controlled contraband, and the Lookchem platform doesn't provide relevant sales information.

Chemical Property of Methyl acrylate

Chemical Property:

• Appearance/Colour: colourless liquid
• Vapor Pressure: 67.5 mm Hg ( 20 °C)
• Melting Point: -75 °C
• Refractive Index: n20/D 1.402(lit.)
• Boiling Point: 80.199 °C at 760 mmHg
• Flash Point: 6.667 °C
• PSA: 26.30000
• Density: 0.924 g/cm³
• LogP: 0.34540
• Storage Temp.: Refrigerator (+4°C) + Flammables area
• Sensitive.: Light Sensitive
• Solubility.: 60g/l
• Water Solubility.: 60 g/L (20 ºC)
• XLogP3: 0.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 86.036779430
• Heavy Atom Count: 6
• Complexity: 65.9
• Transport DOT Label: Flammable Liquid

Purity/Quality:

Safty Information:

• Pictogram(s): F, Xn
• Hazard Codes: F,Xn
• Statements: 11-20/21/22-36/37/38-43
• Safety Statements: 9-25-26-33-36/37-43-43A

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Plastics & Rubber -> (Meth)acrylates
• Canonical SMILES: COC(=O)C=C
• Inhalation Risk: A harmful contamination of the air can be reached very quickly on evaporation of this substance at 20 °C.
• Effects of Short Term Exposure: The substance is severely irritating to the eyes. The substance is irritating to the skin and respiratory tract.
• Effects of Long Term Exposure: Repeated or prolonged contact may cause skin sensitization.
• Description: Methyl acrylate is an organic compound with the formula CH2CHCO2CH3. It is the methyl ester of acrylic acid. It is a colourless liquid with a characteristic acrid odor. It is mainly produced to make acrylate fiber, which is used to weave synthetic carpets. It is also a reagent in the synthesis of various pharmaceutical intermediates.
• Physical properties: Clear, colorless, flammable liquid with a heavy, sweet, pungent odor. An odor threshold concentration of 3.5 ppbv was reported by Nagata and Takeuchi (1990).
• Uses: Methyl acrylate is contained in some nail lacquers.Methyl acrylate is used in many applications as in the production of acrylic fibers, coatings, elastomers or in chemical synthesis. Acrylic polymers, amphoteric surfactants, vitamin B 1, chemical intermediate. Methyl acrylate is a monomer used in themanufacture of plastic films, textiles, papercoatings, and other acrylate ester resins. It isalso used in amphoteric surfactants.

Technology Process of Methyl acrylate

There total 223 articles about Methyl acrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.5%

methanol (67-56-1) + acrolein (107-02-8,25068-14-8) → 3,3-dimethoxyprop-1-ene (6044-68-4) + acrylic acid methyl ester (292638-85-8,9003-21-8,96-33-3)

Guidance literature:

With oxygen; Pd₅-Bi₂-Fe₁/⁽¹⁰⁰⁾SiO₂-MgO; for 4h;

Reference yield: 45.0%

methanol (67-56-1) + acetic acid (64-19-7,77671-22-8) → formaldehyd (50-00-0,30525-89-4,61233-19-0) + acetic acid methyl ester (79-20-9) + acrylic acid methyl ester (292638-85-8,9003-21-8,96-33-3) + acrylic acid (79-10-7)

Guidance literature:

With oxygen; V-Ti-P oxide; at 390 ℃; Product distribution; other temperatures, various oxygen and methanol concentrations;

DOI:10.1246/bcsj.63.199

Reference yield: 42.0%

methanol (67-56-1) + propene (187737-37-7,13987-01-4,15220-87-8,9003-07-0,676-63-1,25085-53-4) → formaldehyd (50-00-0,30525-89-4,61233-19-0) + acetaldehyde (75-07-0,9002-91-9) + acrylic acid methyl ester (292638-85-8,9003-21-8,96-33-3) + acetone (67-64-1) + acrylic acid (79-10-7)

Guidance literature:

With oxygen; CoMoTeO; V-W-Mo-O; silica gel; In gas; at 360 ℃; Product distribution; two catalytic beds - one reactor; other catalysts (Ni-Co-Fe-Bi-K-P-Mo-O/SiO₂, etc.); effect of the composition of the gas mixture (propene/air, propene/air/water, methanol/nitrogen, methanol/air);

upstream raw materials:

methanol

formaldehyd

acetic acid methyl ester

3-Methoxypropionic acid

Downstream raw materials:

4-oxo-6-oxy-3a,5-diphenyl-2,3,3a,4-tetrahydro-pyrazolo[1,5-b]isoxazole-2-carboxylic acid methyl ester

4-oxo-3a,5,6-triphenyl-(3ar)-2,3,3a,4-tetrahydro-pyrrolo[1,2-b]isoxazole-2t-carboxylic acid methyl ester

3-phenylcarbamoyl-4,5-dihydro-isoxazole-5-carboxylic acid methyl ester

3-(hydroxyimino-phenylcarbamoyl-methyl)-4,5-dihydro-isoxazole-5-carboxylic acid methyl ester

Refernces

• 1、 Zhang, Jinquan,Zhang, Shuaizhong,Zou, Hongbin. "Acid- And base-switched palladium-catalyzed γ-C(sp3)-H alkylation and alkenylation of neopentylamine". supporting information. p. 3466 - 3471. Retrieved 2021/05/31.
• 2、 Guo, Hongchao,Li, Hongxiang,Liu, Hao,Shi, Wangyu,Wang, Chang,Wang, Wei,Wu, Yongjun. "Phosphine-Catalyzed Cascade Annulation of MBH Carbonates and Diazenes: Synthesis of Hexahydrocyclopenta[c]pyrazole Derivatives". supporting information. p. 5571 - 5575. Retrieved 2021/07/31.