Diazene, bis(4-methoxyphenyl)-, (1E)-

Base Information

• Chemical Name: Diazene, bis(4-methoxyphenyl)-, (1E)-
• CAS No.: 21650-55-5
• Molecular Formula: C₁₄H₁₄N₂O₂
• Molecular Weight: 242.277
• Mol file: 21650-55-5.mol

Synonyms:

Chemical Property of Diazene, bis(4-methoxyphenyl)-, (1E)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Diazene, bis(4-methoxyphenyl)-, (1E)-

There total 112 articles about Diazene, bis(4-methoxyphenyl)-, (1E)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

benzenesulfenic acid p-anisidide (63235-31-4) → 2,7-dimethoxyphenazine (5051-19-4) + 4-methoxy-aniline (104-94-9) + diphenyldisulfane (882-33-7) + (E)-1,2-bis(4-methoxyphenyl)diazene (501-58-6,21650-55-5,82570-64-7)

Guidance literature:

In various solvent(s); at 150 ℃; for 15h;

Reference yield: 70.0%

1-Chloro-4-iodobenzene (637-87-6) → 4,4'-dichlorobiphenyl (2050-68-2) + 4-chloro-N-(4-methoxyphenyl)aniline (41018-73-9) + 4-chloro-N-(4-chlorophenyl)-N-(4-methoxyphenyl)aniline + (E)-1,2-bis(4-methoxyphenyl)diazene (501-58-6,21650-55-5,82570-64-7)

Guidance literature:

With N,N,N,N,N,N-hexamethylphosphoric triamide; 4-MeOC₆H₄NHMgBr; copper(l) chloride; In toluene; for 5h; Heating;

DOI:10.1002/poc.610070103

Reference yield: 64.0%

para-iodoanisole (696-62-8) + C7H8NO(1-)*Br(1-)*Mg(2+) → bis(4-methoxyphenyl)amine (101-70-2) + tris(4-anisyl)amine (13050-56-1) + (E)-1,2-bis(4-methoxyphenyl)diazene (501-58-6,21650-55-5,82570-64-7)

Guidance literature:

With copper(l) iodide; In pyridine; for 5h; Product distribution; Heating; further substituted ArNHMgBr and ArN(MgBr)2; further reactions with alkyl bromides, dibromides and substituted iodobenzenes; effect of further additives;

DOI:10.1002/poc.610070103

upstream raw materials:

diethyl ether

4-methoxynitrosobenzene

para-methoxynitrobenzene

[1,4]benzoquinone-bis-[N-(4-methoxy-phenyl)-oxime ]

Downstream raw materials:

cis-4,4'-dimethoxyazobenzene

1.2.4.5-Tetra-p-anisyl-3.3.6.6-tetraphenyl-1.2.4.5-tetraaza-3.6-disila-cyclohexan

5-methoxy-2-(4-methoxyphenyl)-2H-indazole

bis(4-methoxyphenyl)hydrazine