Methanamine, N-(phenylmethylene)-, (E)-

Base Information

• Chemical Name: Methanamine, N-(phenylmethylene)-, (E)-
• CAS No.: 25521-74-8
• Molecular Formula: C8H9N
• Molecular Weight: 119.166
• Mol file: 25521-74-8.mol

Synonyms:Benzylidenemethanamine;Methanamine,N-(phenylmethylene);N-[(1E)-phenylmethylene]methanamine;Benzylidene-methyl-amine;N-(benzylidene)methyl-amine;(E)-N-methyl(benzylidene)amine;N-Methylbenzaldimine;Methylamine,N-benzylidene;N-Methylbenzylideneamine;N-(Phenylmethylene)methanamine;

Chemical Property of Methanamine, N-(phenylmethylene)-, (E)-

Chemical Property:

• PSA: 12.36000
• LogP: 1.73530

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Methanamine, N-(phenylmethylene)-, (E)-

There total 5 articles about Methanamine, N-(phenylmethylene)-, (E)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

benzaldehyde (100-52-7) + methylamine (74-89-5) → N-benzylidenemethylamine (25521-74-8)

Guidance literature:

In water; at 20 ℃; for 0.5h;

DOI:10.1002/chem.201403290

Reference yield: 70.0%

N-methylbenzamide (88070-48-8) → benzyl-methyl-amine (103-67-3) + N-benzylidenemethylamine (25521-74-8)

Guidance literature:

With triethyl borane; phenylsilane; potassium tert-butylate; In pentane; at 50 ℃; for 48h; Inert atmosphere; Schlenk technique; Glovebox; Sealed tube;

DOI:10.1021/acs.joc.9b00277

Reference yield:

benzophenone (119-61-9) + (E)-benzaldehyde O-acetyl oxime (80055-49-8) → methane (34557-54-5,27936-85-2) + ethane (74-84-0) + benzylidenamine (16118-22-2) + (Z)-N-methyl-1-phenylmethanimine (29086-12-2) + (Z)-benzaldoxime O-acetate (19433-13-7,80055-49-8) + benzonitrile (100-47-0) + benzaldehyde benzylidenehydrazone (28867-76-7) + N-benzylidenemethylamine (25521-74-8)

Guidance literature:

In benzene-d6; Photolysis;

DOI:10.1021/ma301959n

upstream raw materials:

benzyl-methyl-amine

benzaldehyde

methylamine

benzophenone

Downstream raw materials:

benzyl-methyl-amine

N-methyl-α-2-propenylbenzemethanamine

N,N′-dimethyl-1,2-diphenylethane-1,2-diamine

1,3-dimethyl-2,4,5-triphenyl-imidazolidine