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Name Sodium benzenolate
EINECS205-347-3
CAS No. 139-02-6
Density0,898 g/cm3
PSA23.06000
LogP1.83040
SolubilityVery soluble in water, soluble in alcoholSoluble in water, acetone and alcohol.
Melting Point>300℃
FormulaC6H6 O . Na
Boiling Point181.8 °C at 760 mmHg
Molecular Weight116.095
Flash Point28°C
Transport InformationN/A
Appearancewhite like or light brown crystalline powder
SafetyPoison by subcutaneous route. A corrosive irritant to skin, eyes, and mucous membranes. When heated to decomposition it emits toxic fumes of Na₂O. See also PHENOL and SODIUM HYDROXIDE.
Risk Codes34
Molecular Structure
Hazard SymbolsStrong irritant to skin and tissue.
SynonymsStrong irritant to skin and tissue.
Article Data96

Sodium benzenolate Synthetic route

: 102-09-0
bis(phenyl) carbonate

A: 139-02-6
sodium phenoxide

B: 81256-74-8
sodium salicylat

Conditions

Conditions	Yield
With water; sodium hydroxide In dimethyl sulfoxide at 25℃; Kinetics;	A 100% B n/a

: 108-95-2
phenol

: 139-02-6
sodium phenoxide

Conditions

Conditions	Yield
With sodium hydroxide In methanol; water	98.9%
With sodium In 1,4-dioxane for 4h; Heating;	92%
With methanol; sodium

: 1121-70-6
sodium 4-methylphenoxide

poly(styrene p-tolyliodonium) hydrogensulfate: poly(styrene p-tolyliodonium) hydrogensulfate

: 139-02-6
sodium phenoxide

Conditions

Conditions	Yield
In N,N-dimethyl-formamide at 100℃; for 24h;	65%

: 122-99-6
2-Phenoxyethanol

A: 139-02-6
sodium phenoxide

B: 3598-16-1
2-phenoxyacetic acid sodium salt

Conditions

Conditions	Yield
With oxygen; bismuth(III) nitrate; palladium on activated charcoal In sodium hydroxide at 90℃; for 6h; Product distribution; also with coactivator and other activators, various times, reaction with other 2-phenoxyethanols;	A n/a B 53%

: 67-56-1
methanol

: 10113-28-7
dimethyl phenyl phosphate

: 124-41-4
sodium methylate

A: 512-56-1
trimethyl phosphite

B: 139-02-6
sodium phenoxide

Conditions

Conditions	Yield
at 0℃; Rate constant;
at 19℃; Rate constant;
at 10℃; Rate constant;

: 60-29-7
diethyl ether

: 64-17-5
ethanol

: 13400-05-0
trichloro-methanesulfenic acid phenyl ester

: 141-52-6
sodium ethanolate

A: 13029-05-5
trichloro-methanesulfenic acid ethyl ester

B: 139-02-6
sodium phenoxide

...Expand

: 64-17-5
ethanol

: 1247-19-4
diphenyldiphenoxysilane

: furan-2,3,5(4H)-trione pyridine (1:1)

A: 512-63-0
1,1,3,3,5,5-hexaphenylcyclotrisiloxane

B: 139-02-6
sodium phenoxide

: 339199-98-3
1,3,5-trinitro-2,4,6-triphenoxy-benzene

: 141-52-6
sodium ethanolate

A: 68959-41-1
1,3,5-triethoxy-2,4,6-trinitrobenzene

B: 139-02-6
sodium phenoxide

: 110-54-3
hexane

: 676-54-0
ethyl sodium

: 100-66-3
methoxybenzene

: 139-02-6
sodium phenoxide

: 1247-19-4
diphenyldiphenoxysilane

: furan-2,3,5(4H)-trione pyridine (1:1)

: 67-64-1
acetone

A: 512-63-0
1,1,3,3,5,5-hexaphenylcyclotrisiloxane

B: 139-02-6
sodium phenoxide

Sodium benzenolate Chemical Properties

Synonyms: PHENOL,sodiumsalt;PHENOL,sodiumsalt(solid);PHENOLatesodium;PHENOLsodium;PHENOLsodiumsalt;sodiumcarbolate;sodiumPHENOLate,solid;SODIUM PHENATE
SODIUM PHENOXIDE is the chemical compound with the formula C₆H₅NaO.Its molar mass is 116.09.
density:0,898 g/cm³
Flash point:28°C
storage temp.:below 5° C
Sensitive:Hygroscopic

Sodium benzenolate Toxicity Data With Reference

1.		scu-mus LDLo:350 mg/kg		AEXPBL Archiv fuer Experimentelle Pathologie und Pharmakologie. 52 (1905),220.
2.		scu-frg LDLo:100 mg/kg		AEXPBL Archiv fuer Experimentelle Pathologie und Pharmakologie. 52 (1905),220.

Sodium benzenolate Consensus Reports

Sodium PHENOXIDE's reported in EPA TSCA Inventory.

Sodium benzenolate Safety Profile

Poison by subcutaneous route. A corrosive irritant to skin, eyes, and mucous membranes. When heated to decomposition it emits toxic fumes of Na₂O. See also PHENOL and SODIUM HYDROXIDE.

Sodium benzenolate Standards and Recommendations

DOT Classification: 8; Label: Corrosive

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Product Name

Sodium benzenolate

Sodium benzenolate Synthetic route

Sodium benzenolate Chemical Properties

Sodium benzenolate Toxicity Data With Reference

Sodium benzenolate Consensus Reports

Sodium benzenolate Safety Profile

Sodium benzenolate Standards and Recommendations

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