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139-02-6
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Basic Information
CAS No.: 139-02-6
Name: Sodium benzenolate
Molecular Structure:
Molecular Structure of 139-02-6 (Sodium benzenolate)
Formula: C6H6 O . Na
Molecular Weight: 116.095
Synonyms: Phenol,sodium salt (8CI,9CI); Sodium phenoxide (6CI); Phenol sodium; Sodium carbolate;Sodium phenate; Sodium phenolate; Sodium phenylate
EINECS: 205-347-3
Density: 0,898 g/cm3
Melting Point: >300℃
Boiling Point: 181.8 °C at 760 mmHg
Flash Point: 28°C
Solubility: Very soluble in water, soluble in alcoholSoluble in water, acetone and alcohol.
Appearance: white like or light brown crystalline powder
Hazard Symbols: Strong irritant to skin and tissue.
Risk Codes: 34
Safety: Poison by subcutaneous route. A corrosive irritant to skin, eyes, and mucous membranes. When heated to decomposition it emits toxic fumes of Na2O. See also PHENOL and SODIUM HYDROXIDE.
PSA: 23.06000
LogP: 1.83040
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Synthetic route
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bis(phenyl) carbonate

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139-02-6

sodium phenoxide

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sodium salicylat

Conditions
ConditionsYield
With water; sodium hydroxide In dimethyl sulfoxide at 25℃; Kinetics;A 100%
B n/a
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phenol

139-02-6

sodium phenoxide

Conditions
ConditionsYield
With sodium hydroxide In methanol; water98.9%
With sodium In 1,4-dioxane for 4h; Heating;92%
With methanol; sodium
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sodium 4-methylphenoxide

poly(styrene p-tolyliodonium) hydrogensulfate

poly(styrene p-tolyliodonium) hydrogensulfate

139-02-6

sodium phenoxide

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 100℃; for 24h;65%
122-99-6

2-Phenoxyethanol

A

139-02-6

sodium phenoxide

B

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2-phenoxyacetic acid sodium salt

Conditions
ConditionsYield
With oxygen; bismuth(III) nitrate; palladium on activated charcoal In sodium hydroxide at 90℃; for 6h; Product distribution; also with coactivator and other activators, various times, reaction with other 2-phenoxyethanols;A n/a
B 53%
67-56-1

methanol

10113-28-7

dimethyl phenyl phosphate

124-41-4

sodium methylate

A

512-56-1

trimethyl phosphite

B

139-02-6

sodium phenoxide

Conditions
ConditionsYield
at 0℃; Rate constant;
at 19℃; Rate constant;
at 10℃; Rate constant;
...Expand
60-29-7

diethyl ether

64-17-5

ethanol

13400-05-0

trichloro-methanesulfenic acid phenyl ester

141-52-6

sodium ethanolate

A

13029-05-5

trichloro-methanesulfenic acid ethyl ester

B

139-02-6

sodium phenoxide

...Expand
64-17-5

ethanol

1247-19-4

diphenyldiphenoxysilane

furan-2,3,5(4H)-trione pyridine (1:1)

A

512-63-0

1,1,3,3,5,5-hexaphenylcyclotrisiloxane

B

139-02-6

sodium phenoxide

...Expand
339199-98-3

1,3,5-trinitro-2,4,6-triphenoxy-benzene

141-52-6

sodium ethanolate

A

68959-41-1

1,3,5-triethoxy-2,4,6-trinitrobenzene

B

139-02-6

sodium phenoxide

...Expand
110-54-3

hexane

676-54-0

ethyl sodium

100-66-3

methoxybenzene

139-02-6

sodium phenoxide

...Expand
1247-19-4

diphenyldiphenoxysilane

furan-2,3,5(4H)-trione pyridine (1:1)

67-64-1

acetone

A

512-63-0

1,1,3,3,5,5-hexaphenylcyclotrisiloxane

B

139-02-6

sodium phenoxide

...Expand
Raw Materials
676-54-0
3046-27-3
3229-70-7
2122-46-5
50882-34-3
937-34-8
1822-71-5
1529-50-6
Downstream Products
100-68-5
13509-27-8
3017-71-8
71-43-2
4316-42-1
99-93-4
123-08-0
69-72-7
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Chemistry

Synonyms: PHENOL,sodiumsalt;PHENOL,sodiumsalt(solid);PHENOLatesodium;PHENOLsodium;PHENOLsodiumsalt;sodiumcarbolate;sodiumPHENOLate,solid;SODIUM PHENATE
SODIUM PHENOXIDE is the chemical compound with the formula C6H5NaO.Its molar mass is 116.09.
density:0,898 g/cm3
Flash point:28°C
storage temp.:below 5° C
Sensitive:Hygroscopic

Toxicity Data With Reference

1.   

scu-mus LDLo:350 mg/kg

   AEXPBL    Archiv fuer Experimentelle Pathologie und Pharmakologie. 52 (1905),220.
2.   

scu-frg LDLo:100 mg/kg

   AEXPBL    Archiv fuer Experimentelle Pathologie und Pharmakologie. 52 (1905),220.

Consensus Reports

Sodium PHENOXIDE's reported in EPA TSCA Inventory.

Safety Profile

Poison by subcutaneous route. A corrosive irritant to skin, eyes, and mucous membranes. When heated to decomposition it emits toxic fumes of Na2O. See also PHENOL and SODIUM HYDROXIDE.

Standards and Recommendations

DOT Classification:  8; Label: Corrosive