One of the key intermediates in this synthesis appears to be a non-enolizable 1,3-diketone. This intermediate is likely formed through a series of carefully controlled reactions.
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((R)-2,2,4-Trimethyl-3-oxo-cyclohexyl)-acetic acid methyl ester
(+)-Norpatchoulenol
Sitagliptin monohydrochloride
(+/-)-cis-(4-hydroxymethyl)cyclopent-2-en-1-ylamine
1-Propanone, 1-(2,6-dichloro-4-pyridinyl)-
(3S,5S)-5-Methyl-3-prop-2-ynyloxy-1-vinyl-cyclohexene
2,4-Pentanedione, 3-[(1S)-1,3-diphenyl-2-propenyl]-
(6SR)-6-hydroxy-(2,3,5-tri-O-benzoyl-α-D-ribofuranosyl)-2H-pyran-3(6H)-one
1,3-dipropionyloxy-2-(2,4-difluorophenyl)-2-propanol
4-cyclohexyl-2,5-diphenylthiazole
4-methoxy-2,6-bis-[2-(trimethylsilyl)ethoxymethoxy]phenylboronic acid
3-[(2R)-2-[(2R,3S)-3-[(1R)-1-[tert-butyl(dimethyl)silyl]oxyethyl]-4-oxo-azetidin-2-yl]propanoyl]-4,4-dimethyl-oxazolidin-2-one
trans-2-<3-methyl-3-(1-vinyltrimethyl-silyl)cyclohexa-1-one-2-yl> acetate
