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10049-08-8

Basic Information
CAS No.: 10049-08-8
Name: Ruthenium trichloride
Molecular Structure:
Molecular Structure of 10049-08-8 (Ruthenium trichloride)
Formula: RuCl3
Molecular Weight: 207.42
Synonyms: Dichlororutheniumchloride ((RuCl2)Cl) (7CI);Ruthenium chloride;Ruthenium(III) chloride;
EINECS: 233-167-5
Density: 3.11 g/mL at 25 °C(lit.)
Melting Point: 500 °C
Boiling Point:
Flash Point:
Solubility: Insoluble in water
Appearance: Dark red solution
Hazard Symbols: CorrosiveC
Risk Codes: 34-52/53-22
Safety: 26-36/37/39-45-61
Transport Information: UN 3260 8/PG 2
PSA: 0.00000
LogP: -8.98800
Synthetic route
13465-52-6

ruthenium(IV) chloride

A

7647-01-0

hydrogenchloride

B

Ru(4+)*3OH(1-)*Cl(1-)=Ru(OH)3Cl

C

10049-08-8

ruthenium(III)chloride

Conditions
ConditionsYield
With water In water byproducts: Cl2; Cl2 removed by CO2 before hydrolysis completed;;A n/a
B n/a
C 30%

sodium azide

13465-52-6

ruthenium(IV) chloride

A

7727-37-9

nitrogen

B

10049-08-8

ruthenium(III)chloride

C

7647-14-5

sodium chloride

Conditions
ConditionsYield
In hydrogenchloride
In hydrogenchloride

ruthenium(III) chloride trihydrate

10049-08-8

ruthenium(III)chloride

Conditions
ConditionsYield
In neat (no solvent) 140°C, 48 h;
In neat (no solvent) drying under vacuum at 125°C for 15 h;
With thionyl chloride In neat (no solvent) refluxed for 2 h;
1039726-55-0, 882561-97-9

H(1+)*{Ru(H2O)2Cl4}(1-)=H{Ru(H2O)2Cl4}

10049-08-8

ruthenium(III)chloride

Conditions
ConditionsYield
In not given heating;; pure RuCl3 obtained;;
1039726-55-0, 882561-97-9

H(1+)*{Ru(H2O)2Cl4}(1-)=H{Ru(H2O)2Cl4}

10049-08-8

ruthenium(III)chloride

Conditions
ConditionsYield
In not given heating;; pure RuCl3 obtained;;
7647-01-0

hydrogenchloride

ruthenium(III) hydroxide

10049-08-8

ruthenium(III)chloride

Conditions
ConditionsYield
In not given fuming off with HCl;; impure RuCl3 obtained;;
In neat (no solvent) dried air-free HCl; at 105 °C;;
7440-18-8

ruthenium

10049-08-8

ruthenium(III)chloride

Conditions
ConditionsYield
In neat (no solvent) chlorination of specially prepd., finely divided Ru at 800 °C;;
With chlorine
In neat (no solvent) chlorination of specially prepd., finely divided Ru at 800 °C;;
With chlorine
75-44-5

phosgene

7440-18-8

ruthenium

10049-08-8

ruthenium(III)chloride

Conditions
ConditionsYield
In neat (no solvent) at 400 °C;; RuCl3 free from carbon;;
In neat (no solvent) at 400 °C;; carbon-free RuCl3 obtained;;
7782-50-5

chlorine

7440-18-8

ruthenium

10049-08-8

ruthenium(III)chloride

Conditions
ConditionsYield
In neat (no solvent) finely dispersed Ru;;
With carbon monoxide In neat (no solvent) at 600-800 °C;; may contain RuCl2*2CO;;
With carbon monoxide In neat (no solvent) passing a stream of carefully dried Cl2 and CO over powdered Ru in a glass tube at 700-800 °C; air excluded;; crystn. after cooling down in a Cl2 stream;;
7782-50-5

chlorine

7440-18-8

ruthenium

A

13465-52-6

ruthenium(IV) chloride

B

10049-08-8

ruthenium(III)chloride

Conditions
ConditionsYield
In neat (no solvent) react. of Ru in a stream of Cl2; react. of formed RuCl3 with Cl2 forming volatile RuCl4; decompn. of RuCl4 on cooling;;
7782-50-5

chlorine

7440-18-8

ruthenium

A

Ru2OCl6

B

10049-08-8

ruthenium(III)chloride

Conditions
ConditionsYield
In neat (no solvent) chlorination of Ru at 600-700 °C in SiO2 vessels;; formation of Ru2OCl6 as by-product;;
7647-01-0

hydrogenchloride

20427-56-9

ruthenium tetroxide

10049-08-8

ruthenium(III)chloride

Conditions
ConditionsYield
In not given soln. evapd. at 180 °C under a well dried HCl stream;; product contains 0.04% H;;
In neat (no solvent) byproducts: H2O; dry educts; at 105-115 °C;;
In not given concd. HCl;;

ammonium hexachlororuthenate

10049-08-8

ruthenium(III)chloride

Conditions
ConditionsYield
heating in Cl2 atmosphere at 600°C; elem. anal.; X-ray diffraction, thermogravimetric and differential thermal anal.;

ruthenium(IV) oxide

7782-50-5

chlorine

10049-08-8

ruthenium(III)chloride

Conditions
ConditionsYield
With carbon monoxide In neat (no solvent) passing the gas stream over RuO2 at red heat;;

ruthenium(IV) oxide

10049-08-8

ruthenium(III)chloride

Conditions
ConditionsYield
With carbon monoxide; chlorine In neat (no solvent)
With CO; Cl2 In neat (no solvent)

ruthenium(IV) oxide

75-71-8

Dichlorodifluoromethane

10049-08-8

ruthenium(III)chloride

Conditions
ConditionsYield
In neat (no solvent)

ruthenium nitrosylchloride

A

ruthenium(IV) oxide

B

10049-08-8

ruthenium(III)chloride

Conditions
ConditionsYield
In neat (no solvent) heating to 440 °C in a CO2 atmosphere or in vac.;;

Ru(4+)*3OH(1-)*Cl(1-)=Ru(OH)3Cl

10049-08-8

ruthenium(III)chloride

Conditions
ConditionsYield
With alc. In not given heating;;
With tin(ll) chloride In not given
20427-56-9

ruthenium tetroxide

10049-08-8

ruthenium(III)chloride

Conditions
ConditionsYield
With hydrogenchloride In not given in concd. HCl;;
With HCl In not given in concd. HCl;;
13465-52-6

ruthenium(IV) chloride

10049-08-8

ruthenium(III)chloride

Conditions
ConditionsYield
In not given in presence of KI;;>99
With hydrogenchloride In not given byproducts: Cl2; in 15% HCl;;
13465-52-6

ruthenium(IV) chloride

A

10049-08-8

ruthenium(III)chloride

B

7782-50-5

chlorine

Conditions
ConditionsYield
In neat (no solvent) irreversible decomposition under pressure rise of 2 Torr into Cl2 and amorphous RuCl3 on warming at -29 to -31°C;;
In neat (no solvent) irreversible decomposition under pressure rise of 2 Torr into Cl2 and amorphous RuCl3 on warming at -29 to -31°C;;
In neat (no solvent) equilibrum of gasous RuCl4 with solid RuCl3 and gasous Cl2;;
1039726-55-0, 882561-97-9

hydrogen tetrachlorodiaquoruthenate(III)

10049-08-8

ruthenium(III)chloride

Conditions
ConditionsYield
In neat (no solvent) heating in a HCl stream to 200 °C;;
In neat (no solvent) heating in a HCl stream to 200 °C;;
14521-18-7

ruthenium(V) fluoride

10049-08-8

ruthenium(III)chloride

Conditions
ConditionsYield
With dichloromethane In dichloromethane byproducts: CHCl2F, HF, CH2ClF; inert atmosphere; excess of CH2Cl2, warming to room temp.; further byproducts;

{Ru(NO)Cl3(water)2} * 3 H2O

A

ruthenium(IV) oxide

B

124-38-9

carbon dioxide

C

7732-18-5

water

D

10049-08-8

ruthenium(III)chloride

Conditions
ConditionsYield
In neat (no solvent) loss of 2 mol H2O on heating at 100 °C or at 25 °C in vac. forming a pink product; further loss of 2 mol H2O at 120-150 °C forming a brick-red product that becomes brown at 360 °C; at 440 °C in vac complete decompn.;; formation of RuCl3, RuO2 and CO2;;
10049-08-8

ruthenium(III)chloride

16369-40-7

dicarbonyldichlororuthenium(II)

Conditions
ConditionsYield
With CO In 2-methoxy-ethanol RuCl3 dissolved in 2-methoxyethanol, soln. heated at reflux as stream of CO passed into it for 170-210 min; solvent removed at reduced pressure;100%
17084-13-8

potassium hexafluorophosphate

282118-31-4

5,5'-bis(3-octylthienyl)-2,2'-pyridine

10049-08-8

ruthenium(III)chloride

tris(5,5'-bis(3-octylthienyl)-2,2'-pyridine)ruthenium(II) hexafluorophosphate

Conditions
ConditionsYield
In ethylene glycol under Ar atm. ethyleneglycol soln. RuCl3 and tpbpy was refluxed at 180°C for 2 h, solvent was removed in vacuo, residue was purified by chromy. on silica using acetone/water/sat.aq.KNO3 94.3/5.6/0.1 as eluent, KPF6 was added;100%

disodium salt of 4,7-diphenyl-1,10-phenanthrolinedisulfonic acid

10049-08-8

ruthenium(III)chloride

Ru(C12H6N2(SO3Na)2)3(2+)*2Cl(1-)=[Ru(C12H6N2(SO3Na)2)3]Cl2

Conditions
ConditionsYield
With sodium hypophosphite In water mixt. (P-salt as reducing agent) refluxing for 40 min, soln. vac. concn., pptn. into acetone; ppt. repptn. from MeOH into acetone twice or three times; elem. anal.;99%
10049-08-8

ruthenium(III)chloride

diammonium pentachloronitrosylruthenate

Conditions
ConditionsYield
In not given prepn. according to V. A. Emel'yanov et al., Russ. J. Inorg. Chem. 46, 346 (2001);97%
10049-08-8

ruthenium(III)chloride

542-92-7

cyclopenta-1,3-diene

1287-13-4

bis(η5-cyclopentadienyl)ruthenium

Conditions
ConditionsYield
With zinc In ethanol a mixt. of RuCl3 and ethanol was stirred for 2-3 h at 20°C; cyclopentadiene (frehly distd.) was added; Zn powder was added gradually (temp. < 30-35°C); the mixt. was stirred at 20°C for 3-4 d; ppt. filtered off, washed (hot C6H6 on filter); filtrates concd. (vac.), chromd. (SiO2, C6H6);95%
10049-08-8

ruthenium(III)chloride

78-79-5

isoprene

dichloro-bis-μ-chloro-bis[(1-3η:6-8η)-2,7-dimethyloctadienediyl]diruthenium(II)

Conditions
ConditionsYield
In 2-methoxy-ethanol soln. of RuCl3 in a mixt. of isoprene and 2-methoxyethanol was refluxed for 10 d under N2; crystals were filtered, washed with Et2O and dried in vac, elem. anal.;95%
10049-08-8

ruthenium(III)chloride

773883-32-2

2,9-di(pyridin-2-yl)-1,10-phenanthroline

A

[Ru(2,9-di-(2'-pyridyl)-1,10-phenathroline)2]Cl2

[Ru(2,9-di-(2'-pyridyl)-1,10-phenathroline)(4-dimethylaminopyridine)2]Cl2

Conditions
ConditionsYield
In ethanol phenathroline-compound was treated with RuCl3 in refluxing ethanol followed by the introduction of 4-dimethylaminopyridine;A 5%
B 95%

(p-isopropyltoluene)Ru(Et2C2B3H3)CoC5H5

10049-08-8

ruthenium(III)chloride

(p-isopropyltoluene)Ru(Et2C2B3H2-4-Cl)CoC5H5

Conditions
ConditionsYield
In water; acetone Ru-Co complex was dissolved in acetone-water and treated with anhydrous RuCl3, after 2 h stirring the solvent was removed; residue was extd. with CH2Cl2, ext. was filtered through silica, filtrate gave on evapn. black-green solid;93%

[{Li(bis(3,5-dimethylpyrazol-1-yl)acetate)(H2O)}4]

10049-08-8

ruthenium(III)chloride

667938-04-7

[(Ru(((bis(3,5-dimethylpyrazol-1-yl)acetate)2]

Conditions
ConditionsYield
In methanol RuCl3 (0.24 mmol) was dissolved in MeOH contg. ligand (0.48 mmol) and stirred for 12 h; soln. was evapd. and the liq. was rotoevapd. and extd. several times with an acetone:MeOH (4:1) soln. and evapd. to dryness under vac.; elem. anal.;93%
10049-08-8

ruthenium(III)chloride

279674-33-8

4′-(4-phenylphenyl)-2,2′:6′,2″-terpyridine

279674-19-0

Ru(4′-biphenyl-2,2′:6′,2″-terpyridine)Cl3

Conditions
ConditionsYield
In ethanol ligand and RuCl3 in EtOH were heated at reflux for 1 h; cooled, ppt. filtered off, washed with ice-cold EtOH;92%

[{Li(bis(3,5-dimethylpyrazol-1-yl)acetate)(H2O)}4]

10049-08-8

ruthenium(III)chloride

[(Ru((bis(3,5-dimethylpyrazol-1-yl)acetate)Cl(H2O))2]

Conditions
ConditionsYield
In methanol RuCl3 (0.24 mmol) was dissolved in MeOH contg. ligand (0.24 mmol) and stirred for 12 h; soln. was evapd. and the liq. was rotoevapd. and extd. several times with an acetone:MeOH (4:1) soln. and evapd. to dryness under vac.; elem. anal.;92%
10049-08-8

ruthenium(III)chloride

112362-30-8

2,6-bis(1-methyl-1H-benzo[d]imidazol-2-yl)pyridine

Ru(2,6-bis(1-methylbenzimidazol-2-yl)pyridine)Cl3 * 2.5 H2O

Conditions
ConditionsYield
In ethanol equimolar amts.; refluxing under Ar in dark for 1 h; cooling to 25°C, collection (filtration), washing (EtOH), drying (vac.); elem. anal.;92%

[(Li((bis(3,5-dimethylpyrazol-1-yl)methane sulfonate)(H2O))4

10049-08-8

ruthenium(III)chloride

667938-03-6

[(Ru(((bis(3,5-dimethylpyrazol-1-yl)methane sulfonate)2]

Conditions
ConditionsYield
In methanol RuCl3 (0.24 mmol) was dissolved in MeOH contg. ligand (0.48 mmol) and stirred for 12 h; soln. was evapd. and the liq. was rotoevapd. and extd. several times with an acetone:MeOH (4:1) soln. and evapd. to dryness under vac.; elem. anal.;91%
14742-26-8

[13C]methanol

10049-08-8

ruthenium(III)chloride

6476-36-4

tris(1-methylethyl)phosphine

RuHCl((13)CO)(PiPr3)2

Conditions
ConditionsYield
With KHCO3 In further solvent(s) (inert atm.); reaction of ruthenium compd. with methanol-(13)C in presecnce of phosphine deriv. and KHCO3; Marchenko A.V., Huffman J.C., ValergaP., Jimenez Tenorio M., Puerta M.C., Caulton K.G., Inorg. Chem., 2001, 40, 6444;91%
7758-09-0

potassium nitrite

10049-08-8

ruthenium(III)chloride

potassium sodium hexanitroruthenate(II)*H2O

Conditions
ConditionsYield
With Na(1+); Cl2 In hydrogenchloride heating on a water bath for 30 min; filtn. and dissolving in a minimum of water; elem. anal.;90%
201230-82-2

carbon monoxide

10049-08-8

ruthenium(III)chloride

15243-33-1

dodecacarbonyl-triangulo-triruthenium

Conditions
ConditionsYield
With caesium carbonate In methanol other Radiation; mixt. of RuCl3, Cs2CO3 and MeOH was sealed in microwave app.; CO (50 psi) was introduced; sealed; heated with stirring to 110°C using power of 300 W; held for 10 min; cooled to 50°C; evapd. (vac.); hexane added; heated; solvent removed;90%
With Cu or Zn In ethanol other Radiation; γ irradiation of 1E-3 mol/l RuCl3 in ethanol under CO atmosphere at room temp. in presence of Cu or Zn powder;
With zinc In methanol heating RuCl3 with Zn at a CO pressure of 5-10 atm at 65 °C for 30 h;; extraction of thr solid residue of the filtration; pptn. on concentrating;;
With Zn In methanol heating RuCl3 with Zn at a CO pressure of 5-10 atm at 65 °C for 30 h;; extraction of thr solid residue of the filtration; pptn. on concentrating;;

[{Li(bis(3,5-dimethylpyrazol-1-yl)acetate)(H2O)}4]

10049-08-8

ruthenium(III)chloride

107-15-3

ethylenediamine

667938-06-9

[Ru(((bis(3,5-dimethylpyrazol-1-yl)acetate)(ethylenediamine)(Cl)]

Conditions
ConditionsYield
In methanol RuCl3 (0.24 mmol) was dissolved in MeOH contg. ligand (0.24 mmol) and ethylenediamine (0.24 mmol) and stirred for 12 h; soln. was evapd. and the liq. was rotoevapd. and extd. several times with an acetone:MeOH (4:1) soln. and evapd. to dryness under vac.; elem. anal.;90%

tetra[(bis(1,3-dimethylpyrazol-1-yl)dithioacetate)aqualithium]

10049-08-8

ruthenium(III)chloride

872977-80-5

[bis(bis(1,3-dimethylpyrazol-1-yl)dithio-κ3-N,N,S-acetate)ruthenium(II)]

Conditions
ConditionsYield
In methanol Kinetics; byproducts: LiCl; inert atm., stoich., a soln. of Ru compd. added to a soln. of Li compd. (4 portions), stirred for 4 h; solvent removed, dissolved (CH2Cl2), filtered, solvent removed (vac.); elem. anal.;90%
68696-06-0

5-chlorosalicylaldehyde thiosemicarbazone

10049-08-8

ruthenium(III)chloride

RuCl(H2O)(H2NC(S)NNC(H)C6H3Cl(OH))2*H2O

Conditions
ConditionsYield
In methanol soln. of RuCl3 mixed with soln. of Schiff base (molar ratio 1:2), mixt. stirred under reflux for 1 h; ppt. septd. by filtration, washed (CH3OH), dried over P4O10; elem. anal.;90%

[(Li((bis(3,5-dimethylpyrazol-1-yl)methane sulfonate)(H2O))4

10049-08-8

ruthenium(III)chloride

[(Ru((bis(3,5-dimethylpyrazol-1-yl)methane sulfonate)Cl(H2O))2]

Conditions
ConditionsYield
In methanol RuCl3 (0.24 mmol) was dissolved in MeOH contg. ligand (0.24 mmol) and stirred for 12 h; soln. was evapd. and the liq. was rotoevapd. and extd. several times with an acetone:MeOH (4:1) soln. and evapd. to dryness under vac.; elem. anal.;90%
1015459-97-8

4'-(p-decyloxyphenyl)terpyridine

10049-08-8

ruthenium(III)chloride

1000374-09-3

[(4'-(p-decyloxyphenylyl)terpyridine)RuCl3]

Conditions
ConditionsYield
In ethanol 1:1 mixt. refluxed;90%
10049-08-8

ruthenium(III)chloride

trans-hydroxotetraamminenitrosoruthenium(II)

Conditions
ConditionsYield
In not given prepn. according to V. A. Emel'yanov et al., Russ. J. Inorg. Chem., 46, 346 (2001); M. A. Il'in et al., Russ. J. Inorg. Chem. 53, 1070 (2008);90%
1148-79-4

2,2':6,2''-terpyridine

13826-83-0

ammonium tetrafluroborate

2569-57-5

2-(phenylazo)pyridine

10049-08-8

ruthenium(III)chloride

7632-00-0

sodium nitrite

359864-76-9

(nitro-κN)[2-(phenyldiazenyl-κN2)pyridine-κN](2,2':6',2''-terpyridine-κ3N)ruthenium(II) tetrafluoroborate

Conditions
ConditionsYield
With AgNO3 In water; acetone byproducts: AgCl; RuCl3, 2,2':6',2''-terpyridine gave trichloro(terpyridine)Ru(III); 2-(phenylazo)pyridine added; soln. intermediate Cl(2-(phenyldiazenyl)pyridine)(terpyridine)Ru(II) chloride, AgNO3 in Me2CO/H2O reflux 15 min; NaNO2 added; 1 h heated; NH4BF4 added; 5 d; filtered off; washed (cool H2O, Et2O); crystn. (MeOH:M2CO = 1:1 v/v);88%

[(Li((bis(3,5-dimethylpyrazol-1-yl)methane sulfonate)(H2O))4

10049-08-8

ruthenium(III)chloride

107-15-3

ethylenediamine

667938-05-8

[Ru(((bis(3,5-dimethylpyrazol-1-yl)methane sulfonate)(ethylenediamine)(Cl)]

Conditions
ConditionsYield
In methanol RuCl3 (0.24 mmol) was dissolved in MeOH contg. ligand (0.24 mmol) and ethylenediamine (0.24 mmol) and stirred for 12 h; soln. was evapd. and the liq. was rotoevapd. and extd. several times with an acetone:MeOH (4:1) soln. and evapd. to dryness under vac.; elem. anal.;88%
85949-64-0

2-hydroxy-1-naphthaldehydethiosemicarbazone

10049-08-8

ruthenium(III)chloride

RuCl(H2O)(H2NC(S)NNC(H)C10H6(OH))2*H2O

Conditions
ConditionsYield
In methanol soln. of RuCl3 mixed with soln. of Schiff base (molar ratio 1:2), mixt. stirred under reflux for 1 h; ppt. septd. by filtration, washed (CH3OH), dried over P4O10; detd. by elem. anal., ESR;87%
10049-08-8

ruthenium(III)chloride

67-68-5

dimethyl sulfoxide

1193751-12-0

Ru6(methylthiolate)12

Conditions
ConditionsYield
With HCl In hydrogenchloride; methanol; dimethyl sulfoxide heating mixt. of ruthenium compd., bipyridine deriv., aq. HCl, methanol and DMSO at 85°C for 1 wk; addn. of methanol, keeping at room temp. for 2 d, filtration, washing with ethanol and diethyl ether, drying at room temp., elem. anal.;87%
With HOOCC5H3NC5H3N(COOH); HCl In hydrogenchloride; methanol; dimethyl sulfoxide heating mixt. of ruthenium compd., bipyridine deriv., aq. HCl, methanol and DMSO at 65°C for 1 wk; isolation of crystals, elem. anal.;8.9%

O3SCH(N2C3H(CH3)2)2(1-)

10049-08-8

ruthenium(III)chloride

107-15-3

ethylenediamine

1192123-91-3

[RuCl2((CH2NH2)2)(O3SCH(N2C3H(CH3)2)2)]

Conditions
ConditionsYield
In acetonitrile N2, equimol., stirred for 6 h; evapd., extd. (acetone), evapd. to dryness (vac.); elem. anal.;87%
10049-08-8

ruthenium(III)chloride

5144-89-8

1,10-phenanthroline hydrate

tris(1,10-phenanthroline)ruthenium(II) dichloride

Conditions
ConditionsYield
In N,N-dimethyl-formamide stoich. amt of N-compd. was added to Ru-compd., reflux for 6 h; solvent was evapd., recrystn. hot water;85%
10049-08-8

ruthenium(III)chloride

55552-24-4

ethyl (diphenylphosphino)acetate

103961-34-8

mer-RuCl3(Ph2PPCH2COOEt)2

Conditions
ConditionsYield
In hydrogenchloride; ethanol a soln. of phosphinoacetate in ethanol added slowly to a mixture of RuCl3 in ethanol and aq. HCl; stirred for 15 min; filtered; cooled to -15°C; recrystd. from ethanol/hexane; elem. anal.;85%
1137-68-4

2-(2'-pyridyl)benzimidazole

10049-08-8

ruthenium(III)chloride

348079-89-0

[Ru(C5H4NC7H5N2)2Cl2](1+)*Cl(1-)=[Ru(C5H4NC7H5N2)2Cl2]Cl

Conditions
ConditionsYield
In ethanol mixed, degassed, refluxed for 72 h; solvent evapd. (vac), washed with boiling petrolium ether, recrystd. from hot benzene-ethanol; elem. anal.;85%
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    RutheniuM(III) chloride, anhydrous RuCl3

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    Quick Details ProName: Ruthenium trichloride CasNo: 10049-08-8 Molecular Formula: RuCl3 Appearance: Dark red crystalline powder Application: materials,chemical DeliveryTime: in stock, deliver against payment

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    10049-08-8

    Ruthenium(III) chloride

    Min.Order: 1 Gram

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    Hangzhou KieRaychem Co.,Ltd.is located in Yuhang District of Hangzhou City and specialized in the chemical product customization, development, sales, import and export. Current bus

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  • Ruthenium chloride(RuCl3)

  • Casno:

    10049-08-8

    Ruthenium chloride(RuCl3)

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    1, High quality with competitive price:2, Fast and safe delivery3.Excellent pre-sales and after-sales service4. Well-trained and professional technologist and sales with rich experience in the field for 5-10 yearsAppearance:see detailed specification

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  • Ruthenium(III) chloride

  • Casno:

    10049-08-8

    Ruthenium(III) chloride

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0/

    high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

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  • Ruthenium chloride(RuCl3)

  • Casno:

    10049-08-8

    Ruthenium chloride(RuCl3)

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0/

    R & D enterprises have their own stock in stock Package:1kg Application:pharmaceutical intermediates

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    Business Type:Manufacturers

    Tel:86-571-86465881,86-571-87157530,86-571-88025800

    Address:RM.1118,NO.1 Building, Baiyun Tower,Jianggan Area, Hangzhou city, China,310004

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Consensus Reports

EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory.

Specification

The Ruthenium trichloride, with the CAS registry number 10049-08-8, is also known as Ruthenium(III) chloride. It belongs to the product categories of Inorganics; Catalysts for Organic Synthesis; Classes of Metal Compounds; Homogeneous Catalysts; Ru (Ruthenium) Compounds; Synthetic Organic Chemistry; Titanium Alkoxides, etc. (Homogeneous Catalysts); Transition Metal Compounds; Catalysis and Inorganic Chemistry; Ru Catalysts Metal and Ceramic Science; Ruthenium; Ruthenium Salts; Salts; Metal Halide. Its EINECS registry number is 233-167-5. This chemical's molecular formula is Cl3Ru and molecular weight is 207.43. What's more, its systematic name is called Ruthenium(+2) cation trichloride. It should be stored in a cool, dry and well-ventilated place. Crystalline material is usually prepared by heating powdered ruthenium metal to 700 °C under a 4:1 mixture of chlorine and carbon monoxide: the product is carried by the gas stream and crystallises upon cooling.

Physical properties about Ruthenium trichloride are: (1)#H bond acceptors: 0; (2)#H bond donors: 0; (3)#Freely Rotating Bonds: 0; (4)Polar Surface Area: Å2.

Uses of Ruthenium trichloride: it is used to produce other chemicals. For example, RuCl3(H2O)x reacts with carbon monoxide under mild conditions. Reduction of carbonylated solutions with Zn affords the orange triangular cluster [Ru3(CO)12].

3 RuCl3·xH2O + 4.5 Zn + 12 CO (high pressure) → Ru3(CO)12 + 3 H2O + 4.5 ZnCl2

When you are dealing with this chemical, you should be very careful. This chemical may destroy living tissue on contact and may cause burns. it is harmful if swallowed and may cause long-term adverse effects in the aquatic environment. Therefore, you should wear suitable protective clothing, gloves and eye/face protection. In addition, you must avoid releasing to the environment and refer to special instructions/safety data sheet. In case of contacting with eyes, you should rinse immediately with plenty of water and seek medical advice. And in case of accident or if you feel unwell seek medical advice immediately.

You can still convert the following datas into molecular structure:
(1) SMILES: [Ru+2].[Cl-].[Cl-].[Cl-]
(2) InChI: InChI=1S/3ClH.Ru/h3*1H;/q;;;+2/p-3
(3) InChIKey: SJBXHTJATUAXJN-UHFFFAOYSA-K

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
rat LD50 intraperitoneal 360mg/kg (360mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.