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10049-08-8

Basic Information
CAS No.: 10049-08-8
Name: Ruthenium trichloride
Article Data: 88
Molecular Structure:
Molecular Structure of 10049-08-8 (Ruthenium trichloride)
Formula: RuCl3
Molecular Weight: 207.429
Synonyms: Dichlororutheniumchloride ((RuCl2)Cl) (7CI);Ruthenium chloride;Ruthenium(III) chloride;
EINECS: 233-167-5
Density: 3.11 g/mL at 25 °C(lit.)
Melting Point: 500 °C
Solubility: Insoluble in water
Appearance: Dark red solution
Hazard Symbols: CorrosiveC
Risk Codes: 34-52/53-22
Safety: 26-36/37/39-45-61
Transport Information: UN 3260 8/PG 2
PSA: 0.00000
LogP: -8.98800
Synthetic route
13465-52-6

ruthenium(IV) chloride

A

7647-01-0

hydrogenchloride

B

Ru(4+)*3OH(1-)*Cl(1-)=Ru(OH)3Cl

C

10049-08-8

ruthenium(III)chloride

Conditions
ConditionsYield
With water In water byproducts: Cl2; Cl2 removed by CO2 before hydrolysis completed;;A n/a
B n/a
C 30%

sodium azide

13465-52-6

ruthenium(IV) chloride

A

7727-37-9

nitrogen

B

10049-08-8

ruthenium(III)chloride

C

7647-14-5

sodium chloride

Conditions
ConditionsYield
In hydrogenchloride
In hydrogenchloride

ruthenium(III) chloride trihydrate

10049-08-8

ruthenium(III)chloride

Conditions
ConditionsYield
In neat (no solvent) 140°C, 48 h;
In neat (no solvent) drying under vacuum at 125°C for 15 h;
With thionyl chloride In neat (no solvent) refluxed for 2 h;
1039726-55-0, 882561-97-9

H(1+)*{Ru(H2O)2Cl4}(1-)=H{Ru(H2O)2Cl4}

10049-08-8

ruthenium(III)chloride

Conditions
ConditionsYield
In not given heating;; pure RuCl3 obtained;;
1039726-55-0, 882561-97-9

H(1+)*{Ru(H2O)2Cl4}(1-)=H{Ru(H2O)2Cl4}

10049-08-8

ruthenium(III)chloride

Conditions
ConditionsYield
In not given heating;; pure RuCl3 obtained;;
7647-01-0

hydrogenchloride

ruthenium(III) hydroxide

10049-08-8

ruthenium(III)chloride

Conditions
ConditionsYield
In not given fuming off with HCl;; impure RuCl3 obtained;;
In neat (no solvent) dried air-free HCl; at 105 °C;;
7440-18-8

ruthenium

10049-08-8

ruthenium(III)chloride

Conditions
ConditionsYield
In neat (no solvent) chlorination of specially prepd., finely divided Ru at 800 °C;;
With chlorine
In neat (no solvent) chlorination of specially prepd., finely divided Ru at 800 °C;;
With chlorine
75-44-5

phosgene

7440-18-8

ruthenium

10049-08-8

ruthenium(III)chloride

Conditions
ConditionsYield
In neat (no solvent) at 400 °C;; RuCl3 free from carbon;;
In neat (no solvent) at 400 °C;; carbon-free RuCl3 obtained;;
7782-50-5

chlorine

7440-18-8

ruthenium

10049-08-8

ruthenium(III)chloride

Conditions
ConditionsYield
In neat (no solvent) finely dispersed Ru;;
With carbon monoxide In neat (no solvent) at 600-800 °C;; may contain RuCl2*2CO;;
With carbon monoxide In neat (no solvent) passing a stream of carefully dried Cl2 and CO over powdered Ru in a glass tube at 700-800 °C; air excluded;; crystn. after cooling down in a Cl2 stream;;
7782-50-5

chlorine

7440-18-8

ruthenium

A

13465-52-6

ruthenium(IV) chloride

B

10049-08-8

ruthenium(III)chloride

Conditions
ConditionsYield
In neat (no solvent) react. of Ru in a stream of Cl2; react. of formed RuCl3 with Cl2 forming volatile RuCl4; decompn. of RuCl4 on cooling;;
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Consensus Reports

EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory.

Specification

The Ruthenium trichloride, with the CAS registry number 10049-08-8, is also known as Ruthenium(III) chloride. It belongs to the product categories of Inorganics; Catalysts for Organic Synthesis; Classes of Metal Compounds; Homogeneous Catalysts; Ru (Ruthenium) Compounds; Synthetic Organic Chemistry; Titanium Alkoxides, etc. (Homogeneous Catalysts); Transition Metal Compounds; Catalysis and Inorganic Chemistry; Ru Catalysts Metal and Ceramic Science; Ruthenium; Ruthenium Salts; Salts; Metal Halide. Its EINECS registry number is 233-167-5. This chemical's molecular formula is Cl3Ru and molecular weight is 207.43. What's more, its systematic name is called Ruthenium(+2) cation trichloride. It should be stored in a cool, dry and well-ventilated place. Crystalline material is usually prepared by heating powdered ruthenium metal to 700 °C under a 4:1 mixture of chlorine and carbon monoxide: the product is carried by the gas stream and crystallises upon cooling.

Physical properties about Ruthenium trichloride are: (1)#H bond acceptors: 0; (2)#H bond donors: 0; (3)#Freely Rotating Bonds: 0; (4)Polar Surface Area: Å2.

Uses of Ruthenium trichloride: it is used to produce other chemicals. For example, RuCl3(H2O)x reacts with carbon monoxide under mild conditions. Reduction of carbonylated solutions with Zn affords the orange triangular cluster [Ru3(CO)12].

3 RuCl3·xH2O + 4.5 Zn + 12 CO (high pressure) → Ru3(CO)12 + 3 H2O + 4.5 ZnCl2

When you are dealing with this chemical, you should be very careful. This chemical may destroy living tissue on contact and may cause burns. it is harmful if swallowed and may cause long-term adverse effects in the aquatic environment. Therefore, you should wear suitable protective clothing, gloves and eye/face protection. In addition, you must avoid releasing to the environment and refer to special instructions/safety data sheet. In case of contacting with eyes, you should rinse immediately with plenty of water and seek medical advice. And in case of accident or if you feel unwell seek medical advice immediately.

You can still convert the following datas into molecular structure:
(1) SMILES: [Ru+2].[Cl-].[Cl-].[Cl-]
(2) InChI: InChI=1S/3ClH.Ru/h3*1H;/q;;;+2/p-3
(3) InChIKey: SJBXHTJATUAXJN-UHFFFAOYSA-K

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
rat LD50 intraperitoneal 360mg/kg (360mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.