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Basic Information
CAS No.: 109-59-1
Name: 2-ISOPROPOXYETHANOL
Article Data: 17
Molecular Structure:
Molecular Structure of 109-59-1 (2-ISOPROPOXYETHANOL)
Formula: C5H12 O2
Molecular Weight: 104.149
Synonyms: Ethanol,2-isopropoxy- (6CI,7CI,8CI); 2-Isopropoxyethanol; 2-Isopropyloxyethanol;2-[(1-Methylethyl)oxy]ethanol; Dowanal EiPAT; Ethylene glycol isopropyl ether;Ethylene glycol monisopropyl ether; Ethylene glycol monoisopropyl ether;Isopropyl Cellosolve; Isopropyl Oxitol; NSC 1259; Ucar AC; b-Hydroxyethyl isopropyl ether
EINECS: 203-685-6
Density: 0.903
Melting Point: -60 °C
Boiling Point: 131.8 °C at 760 mmHg
Flash Point: 43 ºC
Solubility: Toxicity">

Stability

    Stable. Incompatible with strong oxidizing agents. Combustible.

Toxicology

    Harmful if inhaled or absorbed through the skin.Eye irritant. Typical OEL 22 mg/m3.

    Toxicity

Appearance: clear colorless liquid
Hazard Symbols:
Risk Codes: R20/21;R36   
Safety: Moderately toxic by skin contact and intraperitoneal routes. Mildly toxic by inhalation and ingestion. A skin and eye irritant. When heated to decomposition it emits acrid smoke and fumes. See also GLYCOL ETHERS.
Transport Information: UN 2929
PSA: 29.46000
LogP: 0.40370
Synthetic route
75-21-8

oxirane

67-63-0

isopropyl alcohol

109-59-1

2-(1-methylethoxy)-ethanol

Conditions
ConditionsYield
With boron trifluoride at 80℃;
With hydro silicate bei Siedehitze;
With ortho-tungstic acid at 90 - 95℃; under 7355.08 - 8826.09 Torr;
107-21-1

ethylene glycol

75-26-3

isopropyl bromide

109-59-1

2-(1-methylethoxy)-ethanol

Conditions
ConditionsYield
With sodium carbonate
105-36-2

ethyl bromoacetate

67-63-0

isopropyl alcohol

109-59-1

2-(1-methylethoxy)-ethanol

Conditions
ConditionsYield
(i) Na, (ii) LiAlH4; Multistep reaction;
75-21-8

oxirane

64-17-5

ethanol

67-63-0

isopropyl alcohol

75-65-0

tert-butyl alcohol

A

110-80-5

2-ethoxy-ethanol

B

109-59-1

2-(1-methylethoxy)-ethanol

C

7580-85-0

tert-butyl glycidyl ether

Conditions
ConditionsYield
Trimethyl borate; hydrogen fluoride In water at 30℃; for 0.166667h;

A

109-59-1

2-(1-methylethoxy)-ethanol

B

C13H20ClNO2*ClH

Conditions
ConditionsYield
With hydrogenchloride In water at 70.04℃; Kinetics; Mechanism; Temperature; Concentration;

A

109-59-1

2-(1-methylethoxy)-ethanol

B

C13H20BrNO2*BrH

Conditions
ConditionsYield
With hydrogen bromide; potassium bromide In water at 70.04℃; Kinetics; Mechanism; Temperature; Reagent/catalyst;

A

109-59-1

2-(1-methylethoxy)-ethanol

B

C13H20INO2*HI

Conditions
ConditionsYield
With hydrogen iodide; potassium iodide In water at 70.04℃; Kinetics; Mechanism; Temperature; Reagent/catalyst;
109-59-1

2-(1-methylethoxy)-ethanol

124-63-0

methanesulfonyl chloride

235097-76-4

methanesulfonic acid 2-isopropoxyethyl ester

Conditions
ConditionsYield
With triethylamine In dichloromethane at 20℃; for 1.5h; Cooling with ice;100%
With triethylamine In dichloromethane at 20℃;80%
With triethylamine In dichloromethane at 0 - 20℃; for 3h;80%

Y5(OiPr)13O

109-59-1

2-(1-methylethoxy)-ethanol

794521-39-4

[Y4(μ3,η2-OC2H4OCH(CH3)2)3(μ,η2-OC2H4OCH(CH3)2)2(η1-OC2H4OCH(CH3)2)4(μ,η1-OC2H4OCH(CH3)2)3]2

Conditions
ConditionsYield
In toluene reactions carried out under argon; Y5O(OCH(CH3)2)13 reacted with 2-isopropoxyethanol in toluene at room temp. for 12 h; elem. anal.;99%
109-59-1

2-(1-methylethoxy)-ethanol

8-bromo-7-(4-chlorobenzyl)-3-methyl-1-(3-(tetrahydro-2H-pyran-2-yloxy)propyl)-1H-purine-2,6(3H,7H)-dione

7-(4-chlorobenzyl)-8-(2-isopropoxyethoxy)-3-methyl-1-(3-(tetrahydro-2H-pyran-2-yloxy)propyl)-1H-purine-2,6(3H,7H)-dione

Conditions
ConditionsYield
Stage #1: 2-(1-methylethoxy)-ethanol With sodium In tetrahydrofuran at 0℃; for 0.5h;
Stage #2: 8-bromo-7-(4-chlorobenzyl)-3-methyl-1-(3-(tetrahydro-2H-pyran-2-yloxy)propyl)-1H-purine-2,6(3H,7H)-dione In tetrahydrofuran at 20℃; for 16h;
95.2%
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Chemistry

Synonyms:Dowanal EiPAT;dowanaleipat;Dowanol EiPAT;beta-hydroxyethylisopropylether;2-isopropoxy-ethano;beta-Hydroxyethyl isopropyl ether; 2-(1-methylethoxy)-ethano;2-(1-methylethoxy)-Ethanol;
The Molecular formula of 2-ISOPROPOXYETHANOL(109-59-1): C5H12O2
The Molecular Weight of 2-ISOPROPOXYETHANOL(109-59-1): 104.15
Molecular Structure : 
EINECS: 203-685-6
Melting point: -60 °C 
Boiling point: 42-44 °C13 mm Hg(lit.)
Flash point: 114 °F
density: 0.903 g/mL at 25 °C(lit.)
refractive index: n20/D 1.41(lit.)
storage temp.:Flammables area

Toxicity Data With Reference

1.   

skn-rbt 20 mg/24H MOD

   85JCAE    Prehled Prumyslove Toxikologie; Organicke Latky Marhold, J.,Prague, Czechoslovakia.: Avicenum,1986,627.
2.   

eye-rbt 500 mg/24H MLD

   85JCAE    Prehled Prumyslove Toxikologie; Organicke Latky Marhold, J.,Prague, Czechoslovakia.: Avicenum,1986,627.
3.   

orl-rat LD50:5660 mg/kg

   AIHAAP    American Industrial Hygiene Association Journal. 30 (1969),470.
4.   

ihl-rat LC50:3100 mg/m3/4H

   85GMAT    Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure Izmerov, N.F., et al.,Moscow, USSR.: Centre of International Projects, GKNT,1982,67.
5.   

ipr-rat LD50:800 mg/kg

   85GMAT    Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure Izmerov, N.F., et al.,Moscow, USSR.: Centre of International Projects, GKNT,1982,67.
6.   

orl-mus LD50:4900 mg/kg

   85GMAT    Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure Izmerov, N.F., et al.,Moscow, USSR.: Centre of International Projects, GKNT,1982,67.
7.   

ihl-mus LC50:1930 ppm/7H

   JIHTAB    Journal of Industrial Hygiene and Toxicology. 25 (1943),157.
8.   

ipr-mus LD50:1860 mg/kg

   85GMAT    Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure Izmerov, N.F., et al.,Moscow, USSR.: Centre of International Projects, GKNT,1982,67.
9.

Consensus Reports

Glycol ether compounds are on the Community Right-To-Know List. Reported in EPA TSCA Inventory.

Safety Profile

Moderately toxic by skin contact and intraperitoneal routes. Mildly toxic by inhalation and ingestion. A skin and eye irritant. When heated to decomposition it emits acrid smoke and fumes. See also GLYCOL ETHERS.
The Hazard Codes of 2-ISOPROPOXYETHANOL(109-59-1):   Xn
HazardClass: 3
The Risk Statements information of 2-ISOPROPOXYETHANOL(109-59-1):
36:  Irritating to the eyes 
20/21:  Harmful by inhalation and in contact with skin 
The Safety Statements information of 2-ISOPROPOXYETHANOL(109-59-1):
24/25:  Avoid contact with skin and eyes 
RIDADR: UN 2929 6.1/PG 2
WGK Germany: 1
RTECS: KL5075000
PackingGroup: III

Standards and Recommendations

OSHA PEL: TWA 25 ppm
ACGIH TLV: TWA 25 ppm
DFG MAK: 5 ppm (22 mg/m3)