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109-59-1

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Cretcher,Pittenger
p. 1503
(1924)
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Kinetics of hydrolysis of bisoprolol hemifumarate in aqueous acidic solutions
The kinetics of hydrolysis of bisoprolol hemifumarate in acidic conditions was studied using high-performance liquid chromatography. For this purpose, different hydrohalic acids and one weak carboxylic acid were used. The rate constants, the order of the reaction, and the activation parameters: enthalpy, entropy, and energy of activation were calculated. A proposition for the mechanism of degradation was provided.
Szalka, Mateusz,Rokaszewski, Edward,Kaczmarski, Krzysztof
p. 744 - 754
(2013)
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PROCESS FOR PREPARING AN ALKOXYLATED ALCOHOL OR PHENOL
Process for preparing an alkoxylated alcohol comprising reacting a starting monohydroxy alcohol selected from secondary alcohols, tertiary alcohols and mixtures thereof with an alkylene oxide in the presence of hydrogen fluoride and a boron-containing compound comprising at least one B-O bond. The alcohol may also be a primary monohydroxy alcohol when the boron containing compound is boric acid or boric acid anhydride or a mixture thereof, or may be a primary mono hydroxy alcohol, except a C14/C15 alcohol when reacted with ethylene oxide in the presence of HF and trimethyl borate. A phenol may be alkoxylated in the same way instead of the mono-hydroxyalcohol.
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Page/Page column 19-20

(2008/06/13)

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Chemical Properties

Appearance/Colour :clear colorless liquid
Melting Point: -60 °C
Boiling Point: 131.8 °C at 760 mmHg
Flash Point:43 ºC
Density: 0.903
Solubility:>100g/l soluble
Storage Temp.:Flammables area
Vapor Pressure: 0.00467mmHg at 25°C
Refractive Index: n20/D 1.41(lit.)
PKA: 14.47±0.10(Predicted)
Explosive Limit: 1.6-13.0%(V)
BRN: 1732184
PSA: 29.46000
LogP: 0.40370

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