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15630-89-4

Basic Information
CAS No.: 15630-89-4
Name: Sodium percarbonate
Molecular Structure:
Molecular Structure of 15630-89-4 (Sodium percarbonate)
Formula: 2Na2CO3.3(H2O2)
Molecular Weight: 314.02
Synonyms: SPC-Q 1;SPC-Q 4;SPC-Q 2;Oxyper;ECOX-C;FB Sodium Percarbonate;Perdox;Carbonic acid disodium salt,compounds,compd. with hydrogen peroxide (2:3);SPC-Q 3;Natriumpercarbonat, nicht gecoated;disodium carbonate, compound with hydrogen peroxide (2:3);
EINECS: 239-707-6
Density: 0.90 g/cm3 (20oC)
Melting Point:
Boiling Point: 333.6 °C at 760 mmHg
Flash Point: 169.8 °C
Solubility: Soluble in water.
Appearance: Free flowing white granular powder
Hazard Symbols: OxidizingO,HarmfulXn
Risk Codes: 8-22-41-36/38
Safety: 17-26-37/39
Transport Information: UN 1479
PSA: 247.76000
LogP: -4.84180
Downstream Products
497-19-8
144-55-8
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    Chemical Name: Sodium Percarbonate Synonyms: Sodium carbonate peroxide; Sodium carbonate hydrogen peroxide; sodium carbonate peroxyhydrate CAS No.: 15630-89-4 Molecular Formula: 2Na2CO3·3H2O2 Specifications: Appearance:

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    Chemical Name: Sodium Carbonate Peroxyhydrate Synonyms: Sodium Percarbonate, Sodium Carbonate Peroxide, PCS Molecular Formula: 2Na2CO3.3H2O2 Molecular Weight: 314.02 CAS Number: 15630-89-4 A…

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  • Sodium percarbonate

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    Sodium percarbonate

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    Sodium carbonate peroxide

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  • Sodium percarbonate

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    15630-89-4

    Sodium percarbonate

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Consensus Reports

Moderately toxic by ingestion. When heated to decomposition it emits acrid smoke and irritating vapors.

Standards and Recommendations

Reported in EPA TSCA Inventory.

Specification

Sodium percarbonate is a chemical, an adduct of sodium carbonate and hydrogen peroxide (a perhydrate), with formula 2Na2CO3 · 3H2O2. It is a colorless, crystalline, hygroscopic and water-soluble solid. It is used in some eco-friendly cleaning products and as a laboratory source of anhydrous hydrogen peroxide.

Physical properties about Sodium percarbonate are: (1)ACD/LogP: -0.809; (2)ACD/LogD (pH 5.5): -1.98; (3)ACD/LogD (pH 7.4): -3.77; (4)ACD/BCF (pH 5.5): 1.00; (5)ACD/BCF (pH 7.4): 1.00; (6)ACD/KOC (pH 5.5): 1.00; (7)ACD/KOC (pH 7.4): 1.00; (8)#H bond acceptors: 3; (9)#H bond donors: 2; (10)Flash Point:169.8 °C; (11)Enthalpy of Vaporization: 63.37 kJ/moc; (12)Boiling Point: 333.6 °C at 760 mmHg; (13)Vapour Pressure: 2.58E-05 mmHg at 25°C

Preparation of Sodium percarbonate: Sodium percarbonate(CAS NO.15630-89-4) is easily decomposed by water, so it is produced commercially by reacting powdered anhydrous Na2CO3 with H2O2 dissolved in carbon tetrachloride CCl4. It can be obtained in the laboratory by reacting the two substances in aqueous solution with proper control of the pH or concentrations.

Uses of Sodium percarbonate: As an oxidizing agent, sodium percarbonate is an ingredient in a number of home and laundry cleaning products, including bleach products such as OxiClean, Tide laundry detergent, and Vanish. It contains no phosphorus or nitrogen. Dissolved in water, it yields a mixture of hydrogen peroxide (which eventually decomposes to water and oxygen) and sodium carbonate ("soda ash").
2Na2CO3.3H2O2 → 2Na2CO3 + 3H2O2
Sodium percarbonate can be used in organic synthesis as a convenient source of anhydrous H2O2, in particular in solvents that cannot dissolve the carbonate but can leach the H2O2 out of it.

When you are using this chemical, please be cautious about it as the following:
1. Keep away from combustible material;
2. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice;
3. Wear eye/face protection;
4. Wear suitable gloves and eye/face protection;

You can still convert the following datas into molecular structure:
(1)InChI=1S/2CH2O3.4Na.3H2O2/c2*2-1(3)4;;;;;3*1-2/h2*(H2,2,3,4);;;;;3*1-2H/q;;4*+1;;;/p-4;
(2)InChIKey=MSLRPWGRFCKNIZ-UHFFFAOYSA-J;
(3)Smiles[Na+].[Na+].C([O-])(=O)[O-].OO.[Na+].[Na+].C([O-])(=O)[O-].OO.OO;

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 oral 2200mg/kg (2200mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

LUNGS, THORAX, OR RESPIRATION: DYSPNEA
Toksikologicheskii Vestnik. Vol. (3), Pg. 46, 1994.
rat LD50 intraperitoneal 542mg/kg (542mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

LUNGS, THORAX, OR RESPIRATION: DYSPNEA
Toksikologicheskii Vestnik. Vol. (3), Pg. 46, 1994.
rat LD50 oral 2400mg/kg (2400mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

LUNGS, THORAX, OR RESPIRATION: DYSPNEA
Toksikologicheskii Vestnik. Vol. (3), Pg. 46, 1994.