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624-78-2

Basic Information
CAS No.: 624-78-2
Name: Ethanamine, N-methyl-
Article Data: 60
Cas Database
Molecular Structure:
Molecular Structure of 624-78-2 (Ethanamine, N-methyl-)
Formula: C3H9N
Molecular Weight: 59.1112
Synonyms: N-methyl-aminoethane;Methylaminoethane;2-MAE;N-METHYLETHYLAMINE;Methylethylamine;n-methyl-ethanamin;(CH3)(C2H5)NH;Ethylmethylamine;methyl-N-ethylamine;N-ethyl-N-methylamine;
EINECS: 210-862-1
Density: 0.68 g/cm3
Melting Point: -70.99°C (estimate)
Boiling Point: 36.7 °C at 760 mmHg
Flash Point: <?30°F
Solubility: N/A
Appearance: clear colorless to light yellow liquid
Hazard Symbols: FlammableF; CorrosiveC
Risk Codes: 11-20/21/22-35
Safety: 26-36/37/39-45
Transport Information: UN 2733 3/PG 1
PSA: 12.03000
LogP: 0.61660
Synthetic route
75-07-0

acetaldehyde

74-89-5

methylamine

624-78-2

N-Ethylmethylamine

Conditions
ConditionsYield
With hydrogen; sodium hydroxide; Raney nickel at 65 - 67℃; under 22502.3 Torr; for 4.3h; Product distribution / selectivity; Autoclave; Industry scale;90%
With potassium hydroxide; dipotassium hydrogenphosphate; phosphoric acid at 10 - 12℃; for 4h; electrochemical reductive amination, lead cathode, current density 0.05 A/cm2, pH 12; Yield given;
With imine reductase from Streptomyces ipomoeae; NADPH In water at 30℃; for 0.166667h; pH=9.5; Catalytic behavior; Reagent/catalyst; Enzymatic reaction;
6898-67-5

N-ethylidenemethylamine

624-78-2

N-Ethylmethylamine

Conditions
ConditionsYield
With hydrogen; platinum(IV) oxide In ethanol80%
3710-84-7

N-ethyl-N-hydroxy-ethanamine

A

50-00-0

formaldehyd

B

624-78-2

N-Ethylmethylamine

C

75-04-7

ethylamine

D

75-07-0

acetaldehyde

Conditions
ConditionsYield
With phosphorus pentachloride In toluene at 18 - 20℃; Mechanism; Product distribution; object of study: Stieglitz rearrangement (prototype);A n/a
B 1.4%
C 76%
D n/a
6852-54-6

N-(benzylidene)ethylamine

5187-82-6

(ethoxycarbonylmethyl)dimethylsulfonium bromide

A

624-78-2

N-Ethylmethylamine

B

94117-87-0

1-methylthio-3-phenyl-1,2-cyclopropanedicarboxylic acid diethyl ester

Conditions
ConditionsYield
With potassium hydroxide; N-benzyl-N,N,N-triethylammonium chloride In tetrahydrofuran at 20℃; for 4h;A n/a
B 50%
110-86-1

pyridine

616-39-7

N,N-diethylnmethylamine

94-36-0

dibenzoyl peroxide

A

50-00-0

formaldehyd

B

624-78-2

N-Ethylmethylamine

C

75-07-0

acetaldehyde

D

109-89-7

diethylamine

60-29-7

diethyl ether

6154-14-9

N-chloromethylamine

557-20-0

diethylzinc

A

624-78-2

N-Ethylmethylamine

B

74-89-5

methylamine

7651-91-4

N,N-dichloromethylamine

557-20-0

diethylzinc

624-78-2

N-Ethylmethylamine

Conditions
ConditionsYield
With Petroleum ether
10595-95-6

N-nitrosomethylethylamine

624-78-2

N-Ethylmethylamine

Conditions
ConditionsYield
With hydrogenchloride
4788-37-8

N-ethyl-N-methylbenzylamine

624-78-2

N-Ethylmethylamine

Conditions
ConditionsYield
With platinum(IV) oxide; acetic acid at 65 - 75℃; under 2206.5 Torr; durch Hydrogenolyse;
75-04-7

ethylamine

74-88-4

methyl iodide

624-78-2

N-Ethylmethylamine

Conditions
ConditionsYield
With ethanol at 100℃;
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    Name: N-Ethylmethylamine. Synonym:N-METHYLETHYLAMINE;N-ETHYLMETHYLAMINE;(CH3)(C2H5)NH;Ethylamine,N-methyl-;Ethylmethylamine;ethyl-methyl-amine;Methylaminoethane;Methylethylamine CAS No.: 624-78-2. Molecular formula: C3H9N. Molecular weight:

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Specification

The N-Ethylmethylamine, with the CAS registry number 624-78-2 and EINECS registry number 210-862-1, has the systematic name and IUPAC name of N-methylethanamine.  And the molecular formula of this chemical is C3H9N. It is a kind of clear colorless to light yellow liquid which is also hygroscopic. And it should be stored at 0-6°C.

The physical properties of N-Ethylmethylamine are as following: (1)ACD/LogP: 0.10; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): -3; (4)ACD/LogD (pH 7.4): -2.81; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)ACD/KOC (pH 5.5): 1; (8)ACD/KOC (pH 7.4): 1; (9)#H bond acceptors: 1; (10)#H bond donors: 1; (11)#Freely Rotating Bonds: 1; (12)Polar Surface Area: 3.24 Å2; (13)Index of Refraction: 1.367; (14)Molar Refractivity: 19.54 cm3; (15)Molar Volume: 86.8 cm3; (16)Polarizability: 7.74×10-24cm3; (17)Surface Tension: 18.2 dyne/cm; (18)Density: 0.68 g/cm3; (19)Enthalpy of Vaporization: 28.16 kJ/mol; (20)Boiling Point: 36.7 °C at 760 mmHg; (21)Vapour Pressure: 488 mmHg at 25°C.

Uses of N-Ethylmethylamine: It can react with trifluoroacetic acid anhydride to produce N-ethyl-N-methyltrifluoroacetamide. This reaction will need solvent diethyl ether.

N-Ethylmethylamine can react with trifluoroacetic acid anhydride to produce N-ethyl-N-methyltrifluoroacetamide

You should be cautious while dealing with this chemical. It is a kind of highly flammable chemical ehich may also cause severe burns. And it is also harmful by inhalation, in contact with skin and if swallowed. Therefore, you had better take the following instructions: Wear suitable protective clothing, gloves and eye/face protection, and in case of contacting with eyes, rinse immediately with plenty of water and seek medical advice; In case of accident or if you feel unwell, seek medical advice immediately (show label where possible); Keep away from sources of ignition - No smoking.

You can still convert the following datas into molecular structure:
(1)SMILES: N(CC)C
(2)InChI: InChI=1/C3H9N/c1-3-4-2/h4H,3H2,1-2H3
(3)InChIKey: LIWAQLJGPBVORC-UHFFFAOYAE

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