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63-05-8

Basic Information
CAS No.: 63-05-8
Name: Androstenedione
Article Data: 201
Cas Database
Molecular Structure:
Molecular Structure of 63-05-8 (Androstenedione)
Formula: C19H26O2
Molecular Weight: 286.414
Synonyms: 17-Ketotestosterone;3,17-Dioxoandrost-4-ene;4-Androstene-3,17-dione;Androstenedione;Fecundin;NSC 9563;SKF 2170;D4-Androstene-3,17-dione;Androstenedione;4-Androstenedione;
EINECS: 200-554-5
Density: 1.11 g/cm3
Melting Point: 170-171 °C(lit.)
Boiling Point: 431.4 °C at 760 mmHg
Flash Point: 161.1 °C
Solubility: 57.28mg/L(25 oC)
Appearance: white to off-white solid
Hazard Symbols: HarmfulXn
Risk Codes: 40
Safety: 22-24/25-36
PSA: 34.14000
LogP: 4.08740
Synthetic route
58-22-0

testosterone

63-05-8

Androstenedione

Conditions
ConditionsYield
With Jones reagent In acetone at 0℃; Jones Oxidation;100%
With oxygen; nitrosonium tetrafluoroborate In dichloromethane at 20℃; for 4h;99%
With N-chloro-succinimide; dodecyl methyl sulfide; triethylamine In toluene at -40℃; for 16h; Corey-Kim oxidation;97%
25375-38-6

3-hydroxy-5-androsten-17-one

63-05-8

Androstenedione

Conditions
ConditionsYield
With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; ferric nitrate In ethyl acetate at 0℃; for 65h; Reagent/catalyst;100%
68-96-2

17-hydroxyprogesterone

63-05-8

Androstenedione

Conditions
ConditionsYield
In water; acetonitrile at 20℃; Electrochemical reaction;99%
With tetrapropylammonium perruthennate; 4 A molecular sieve; 4-methylmorpholine N-oxide In dichloromethane; acetonitrile for 0.75h;95%
With chromium(VI) oxide; acetic acid
4966-70-5

3,3,17,17-diethylenedioxyandrost-5-ene

63-05-8

Androstenedione

Conditions
ConditionsYield
With hydrogenchloride In ethanol; water at 40℃; for 2h; pH=3; Temperature; Green chemistry;98.6%
With sulfuric acid; water; silica gel In toluene for 2h;92%
Multi-step reaction with 4 steps
1: hydrogenchloride / water; acetone / pH 1-6
2: potassium tert-butylate / tetrahydrofuran / Inert atmosphere; Reflux
3: tetrahydrofuran / Acidic conditions
4: sodium hydrogencarbonate; ruthenium trichloride; Oxone / ethyl acetate; acetonitrile; water / -20 - 30 °C
View Scheme
2283-82-1

3α-hydroxy-androst-5-en-17-one

63-05-8

Androstenedione

Conditions
ConditionsYield
With calcium hypochlorite; acetic acid In ethyl acetate at 30℃; for 1h; Temperature; Green chemistry;98.5%
81176-75-2

(8R,9S,10R,13S,14S,17S)-10,13-dimethyl-2,3,6,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[α]phenanthrene-3,17-diol

63-05-8

Androstenedione

Conditions
ConditionsYield
With tetrapropylammonium perruthennate; 4 A molecular sieve; 4-methylmorpholine N-oxide In dichloromethane for 0.5h;98%
With 9-fluorenone; oxygen In dimethyl sulfoxide at 20℃; Irradiation;72%
571-36-8

5-androstenedione

63-05-8

Androstenedione

Conditions
ConditionsYield
With potassium hydroxide In methanol; water Ambient temperature;97%
With sodium hydroxide In methanol; water at 25℃;
With sodium hydroxide; 3-oxo-Δ5-steroid isomerase In methanol; water Rate constant; pH 5.0 to 5.1;
162657-73-0

3-cycloethylenedithio-17-cycloethylenedioxy-androst-4-ene

63-05-8

Androstenedione

Conditions
ConditionsYield
With silica gel; copper(II) sulfate In benzene at 80℃; for 5h;90%
53-43-0

dehydroepiandrosterone

A

63-05-8

Androstenedione

B

5982-99-0

androstane-3,17-dione

Conditions
ConditionsYield
aluminum oxide; copper In toluene at 60℃;A 12%
B 88%
152-58-9

Cortexolone

63-05-8

Androstenedione

Conditions
ConditionsYield
In water; acetonitrile at 20℃; Electrochemical reaction;86%
With ammonium hydroxide; iodine In water; acetonitrile at 50℃; for 24h;78%
With manganese(IV) oxide In chloroform for 4h; Heating;67.6%
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    Androstenedione Basic information Biological Metabolism Product Name: Androstenedione Synonyms: 3,17-Dioxoandrost-4-Ene;Androstenedione (CRM);Testosterone EP Impurity A;4-Androstene-3;4-androsten-3,17-dione (4-AD);4-Androstene-3,17-dione Soluti

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  • Greast quality CAS 63-05-8  Androst-4-Ene-3, 17-Dione

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  • Androstenedione (4-AD)

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    63-05-8

    Androstenedione (4-AD)

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    Androstenedione (4-AD) 4-Androstenedione [63-05-8] Product Name: 4-Androstenedione Synonyms: 4-Androstene-3,17-dione; androstenedione; Androst-4-ene-3,17-dione; androst-4-ene-3,17-dione; 4AD; 4-AD

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  • Factory price, quick delivery CAS63-05-8

  • Casno:

    63-05-8

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  • Androstenedione CAS NO.63-05-8

  • Casno:

    63-05-8

    Androstenedione CAS NO.63-05-8

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History

Androstenedione was manufactured as a dietary supplement, often called andro for short.
Andro was legal and able to be purchased over the counter and consequently it was common use in Major League Baseball throughout the 1990s by record-breaking sluggers like Mark McGwire. The supplement is banned by the World Anti-Doping Agency, and hence from the Olympic Games.
On March 12, 2004, the Anabolic Steroid Control Act of 2004 was introduced into the United States Senate. The law took effect on January 20, 2005. Surprisingly, andro was legally defined as an anabolic steroid, even though there is scant evidence that androstenedione itself is anabolic in nature.
On April 11, 2004, the United States Food and Drug Administration banned the sale of Andro.
Androstenedione is currently banned by the US military.

Specification

The Androstenedione is an organic compound with the formula C19H26O2. The IUPAC name of this chemical is (8R,9S,10R,13S,14S)-10,13-dimethyl-2,6,7,8,9,11,12,14,15,16-decahydro-1H-cyclopenta[a]phenanthrene-3,17-dione. With the CAS registry number 63-05-8, it is also named as 4-Androsten-3,17-dione. The product's categories are Pharmaceutical Intermediates; Steroids; Metabolites & Impurities. Besides, it is a white to off-white solid, which should be stored in a closed place. It is used for biochemical studies.

Physical properties about Androstenedione are: (1)ACD/LogP: 2.90; (2)ACD/LogD (pH 5.5): 2.9; (3)ACD/LogD (pH 7.4): 2.9; (4)ACD/BCF (pH 5.5): 93.64; (5)ACD/BCF (pH 7.4): 93.64; (6)ACD/KOC (pH 5.5): 896.96; (7)ACD/KOC (pH 7.4): 896.96; (8)#H bond acceptors: 2; (9)Polar Surface Area: 34.14 Å2; (10)Index of Refraction: 1.551; (11)Molar Refractivity: 81.71 cm3; (12)Molar Volume: 255.8 cm3; (13)Polarizability: 32.39×10-24cm3; (14)Surface Tension: 42.6 dyne/cm; (15)Density: 1.11 g/cm3; (16)Flash Point: 161.1 °C; (17)Enthalpy of Vaporization: 68.71 kJ/mol; (18)Boiling Point: 431.4 °C at 760 mmHg; (19)Vapour Pressure: 1.2E-07 mmHg at 25°C.

Preparation: this chemical can be prepared by 17-hydroxy-androst-4-en-3-one. This reaction will need reagent CrO3 and acetic acid.



Uses of Androstenedione: it can be used to produce 5,17-dioxo-3,5-seco-A-nor-androstan-3-oic acid. It will need reagent KMnO4 and acetone.

When you are using this chemical, please be cautious about it as the following:
It has limited evidence of a carcinogenic effect. When you are using it, wear suitable protective clothing, do not breathe dust and avoid contact with skin and eyes.

You can still convert the following datas into molecular structure:
(1)SMILES: O=C4/C=C3/CC[C@@H]2[C@H](CC[C@@]1(C(=O)CC[C@H]12)C)[C@@]3(C)CC4
(2)InChI: InChI=1/C19H26O2/c1-18-9-7-13(20)11-12(18)3-4-14-15-5-6-17(21)19(15,2)10-8-16(14)18/h11,14-16H,3-10H2,1-2H3/t14-,15-,16-,18-,19-/m0/s1
(3)InChIKey: AEMFNILZOJDQLW-QAGGRKNEBJ
(4)Std. InChI: InChI=1S/C19H26O2/c1-18-9-7-13(20)11-12(18)3-4-14-15-5-6-17(21)19(15,2)10-8-16(14)18/h11,14-16H,3-10H2,1-2H3/t14-,15-,16-,18-,19-/m0/s1
(5)Std. InChIKey: AEMFNILZOJDQLW-QAGGRKNESA-N