107-84-6 Usage
Description
1-Chloro-3-methylbutane, also known as isooctyl chloride, is a colorless or slightly yellow liquid that is combustible and has several isomers. It is slightly soluble in water but soluble in alcohol and ether. This organic compound is commonly used in various applications across different industries due to its unique properties.
Uses
Used in Chemical Industry:
1-Chloro-3-methylbutane is used as a solvent for various applications, including nitrocellulose, varnishes, lacquers, and neoprene. Its solubility properties make it an ideal choice for dissolving and processing these materials.
Used in Printing Industry:
In the printing industry, 1-chloro-3-methylbutane is utilized as a component in rotogravure inks. Its ability to dissolve certain materials and its compatibility with the printing process contribute to the quality and performance of the inks.
Used in Agriculture:
1-Chloro-3-methylbutane is employed in soil fumigation as a means to control pests and improve crop yield. Its effectiveness in this application is attributed to its ability to penetrate the soil and target pests without causing significant harm to the environment.
Used in Organic Compounds:
1-CHLORO-3-METHYLBUTANE is also used in the synthesis of various organic compounds, where its unique properties can be leveraged to create new molecules with specific characteristics and applications.
Purification Methods
Shake the chloride vigorously with 95% H2SO4 until the acid layer no longer becames coloured during 12hours, then wash it with water, saturated aqueous Na2CO3, and more water. Dry it with MgSO4, filter and fractionally distil it. Alternatively, a stream of oxygen containing 5% of ozone is passed through the chloride for a time, three times longer than is necessary to cause the first coloration of starch iodide paper by the exit gas. Subsequent washing of the liquid with aqueous NaHCO3 hydrolyses the ozonides and removes organic acids. After drying and filtering, the isoamyl chloride is distilled. [Chien & Willard J Am Chem Soc 75 6160 1953, Beilstein 1 IV 287.]
Check Digit Verification of cas no
The CAS Registry Mumber 107-84-6 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 1,0 and 7 respectively; the second part has 2 digits, 8 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 107-84:
(5*1)+(4*0)+(3*7)+(2*8)+(1*4)=46
46 % 10 = 6
So 107-84-6 is a valid CAS Registry Number.
InChI:InChI=1/C5H11Cl/c1-5(2)3-4-6/h5H,3-4H2,1-2H3
107-84-6Relevant articles and documents
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Gerrard,French
, p. 263 (1947)
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Ross,Bibbins
, p. 255 (1939)
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Oxidation of monohydric and dihydric alcohols with CCl4 catalyzed by molybdenum compounds
Khusnutdinov,Shchadneva,Burangulova,Muslimov,Dzhemilev
, p. 1615 - 1621 (2007/10/03)
Mo(CO)6 catalyzed oxidation of alcohols and diols with tetrachloromethane. Primary oxidation products in reaction of alcohols with CCl4 are alkyl hypochlorites, and final products depending on the structure of initial alcohol are aldehydes (as acetals), ketones, chloroketones, and esters.
Oxidative alkoxylation of zinc phosphide in alcoholic solutions of copper(II) chloride
Dorfman,Ibraimova,Polimbetova
, p. 50 - 55 (2007/10/03)
Oxidative alkoxylation of Zn3P2 with the formation of valuable phosphoric and phosphorous acid esters occurred at a high rate and with a high selectivity in alcoholic solutions of CuCl2 under the action of oxygen at 30-60°C. Depending on the nature of the alcohol, two products were formed, namely, trialkyl phosphates (RO)3PO and dialkyl phosphites (RO)2HPO. Water favored the formation of dialkyl phosphates (RO)2(HO)PO. The kinetics and mechanism of the new catalytic reaction were studied, and the optimal conditions for conducting this reaction were found. The reaction proceeded in a topochemical mode by a separate redox mechanism.
CHLORINATION OF PHOSPHINE IN ALCOHOLS
Dorfman, Ya. A.,Polimbetova, G. S.,Aibasov, E. Zh.,Borangazieva, A. K.,Kokpanbaeva, A. O.,Faizova, F. Kh.
, p. 1860 - 1864 (2007/10/02)
Trialkyl phosphates are rapidly and selectively formed when dilute gaseous PH-Ar and Cl2-Ar mixtures are passed into alcohols (ROH, R=Bu, i-Bu, Am, i-Am, Oct) at 50-70 deg C.Analogous results are obtained in the presence of pyridine at 8-25 deg C.The reaction was studied by gas chromatography, 31P NMR spectroscopy, and potentiometry.The reaction was shown to pass successively through the stages of the chlorination of phosphine to PCl5, the alcoholysis of phosphorus pentachloride to phosphoryl chloride, and finally by the esterification of phsophoryl chloride to trialkyl and dialkyl phosphates.Pyridine, excess af alcohol, and high temperature accelerate the stage of the esterification of phosphoryl chloride to the trialkyl phosphate.
