105409-39-0

Basic information

• Product Name: 1,3-Dioxolane-4-methanol, 2,2-dimethyl-, acetate, (4S)-
• CAS NO: 105409-39-0
• Molecular Formula: C8H14O4
• Molecular Weight: 174.197
• Mol File: 105409-39-0.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 1,3-Dioxolane-4-methanol, 2,2-dimethyl-, acetate, (4S)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-Dioxolane-4-methanol, 2,2-dimethyl-, acetate, (4S)-(105409-39-0)
• EPA Substance Registry System: 1,3-Dioxolane-4-methanol, 2,2-dimethyl-, acetate, (4S)-(105409-39-0)

Safety Data

• Hazardous Substances Data: 105409-39-0(Hazardous Substances Data)

Upstream product

• 75-36-5 acetyl chloride 
• 141-78-6 ethyl acetate 
• 14347-78-5 1,2-O-isopropylidene-D-glycerol 
• 64-19-7 acetic acid 
• 100-79-8 (R,S)-2,2-dimethyl-1,3-dioxolane-4-methanol 
• 108-24-7 acetic anhydride 
• 109429-01-8 (S)-2-(benzyloxy)-3-hydroxypropyl acetate 
• 105409-38-9 1,3-di-O-acetyl-2-O-benzylglycerol 
• 6946-10-7 1,3-diacetoxyacetone 
• 105498-20-2 1-O-acetyl-sn-glycerol 
• 116-11-0 2-Methoxypropene 
• 108-05-4 vinyl acetate 
• 121348-86-5 (2,2-dimethyl-1,3-dioxolan-4-yl)methyl acetate 

Downstream Products

• 14347-78-5 1,2-O-isopropylidene-D-glycerol 

Relevant articles and documents

Enantioselective hydrolysis of (RS)-isopropylideneglycerol acetate with Kluyveromyces marxianus

The hydrolysis of (RS)-isopropylideneglycerol acetate with whole cells of the yeast Kluyveromyces marxianus is reported. The biotransformation furnished (R)-isopropylideneglycerol as major enantiomer with good enantioselectivity (E=28) under optimised conditions. The reaction can be performed in an ultrafiltration-membrane reactor allowing for the obtainment of 19.2g/L of enantiomerically pure (R)-isopropylideneglycerol acetate starting from 60g/L of racemic mixture.

Ethyl acetate as an acetyl surrogate for the iodine catalyzed acetylation of alcohols

The use of readily available ethyl acetate in the presence of iodine as an alternative acetylating agent is reported. Amines and phenols were unreactive under the examined reaction conditions, indicating that the method is highly chemoselective.

Enzymatic synthesis of 2,3-O-isopropylidene-sn-glycerol, a chiral building block for platelet-activating factor

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