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13141-08-7

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13141-08-7 Usage

General Description

3-Methoxy-2-methylpropanal is an organic compound classified as a methoxy aldehyde. Its chemical formula is C6H12O2. It is used as a flavoring in the food industry with a buttery, nutty, and sweet aroma, also found naturally in a variety of foodstuffs including fruits and roasted peanuts. This chemical substance is typically a colorless to pale yellow clear liquid and insoluble in water; however, it is soluble in alcohol. The use of this chemical should be carefully managed, as it can potentially cause skin and eye irritations in its concentrated form. Its inclusion in consumable products is regulated by agencies like the FDA to ensure safety.

Check Digit Verification of cas no

The CAS Registry Mumber 13141-08-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,3,1,4 and 1 respectively; the second part has 2 digits, 0 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 13141-08:
(7*1)+(6*3)+(5*1)+(4*4)+(3*1)+(2*0)+(1*8)=57
57 % 10 = 7
So 13141-08-7 is a valid CAS Registry Number.

13141-08-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 13, 2017

Revision Date: Aug 13, 2017

1.Identification

1.1 GHS Product identifier

Product name 3-methoxy-2-methylpropanal

1.2 Other means of identification

Product number -
Other names 3-methoxy-2-methyl-propanal

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:13141-08-7 SDS

13141-08-7Synthetic route

2-methylpropenal
78-85-3

2-methylpropenal

sodium methylate
124-41-4

sodium methylate

β-methoxy-isobutyraldehyde
13141-08-7

β-methoxy-isobutyraldehyde

Conditions
ConditionsYield
With methanol
C8H16N2O4

C8H16N2O4

A

methanol
67-56-1

methanol

B

β-methoxy-isobutyraldehyde
13141-08-7

β-methoxy-isobutyraldehyde

Conditions
ConditionsYield
With sodium perchlorate In acetonitrile at 25℃; Rate constant;
β-methoxy-isobutyraldehyde
13141-08-7

β-methoxy-isobutyraldehyde

3-methoxy-2-methyl propanoic acid
10500-24-0

3-methoxy-2-methyl propanoic acid

Conditions
ConditionsYield
With oxygen; copper diacetate; acetic acid
β-methoxy-isobutyraldehyde
13141-08-7

β-methoxy-isobutyraldehyde

3-methoxy-2-methylpropionic acid methyl ester
3852-11-7

3-methoxy-2-methylpropionic acid methyl ester

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: copper (II)-acetate; acetic acid; oxygen
2: sulfuric acid
View Scheme
β-methoxy-isobutyraldehyde
13141-08-7

β-methoxy-isobutyraldehyde

methylamine
74-89-5

methylamine

C6H15NO

C6H15NO

Conditions
ConditionsYield
With imine reductase-22 from Streptomyces sp.; NADPH In methanol at 30℃; for 0.166667h; pH=9.5; Reagent/catalyst; Enzymatic reaction;
β-methoxy-isobutyraldehyde
13141-08-7

β-methoxy-isobutyraldehyde

ethylamine
75-04-7

ethylamine

C7H17NO

C7H17NO

Conditions
ConditionsYield
With imine reductase-33 from Aeromonas veronii; NADPH In methanol at 30℃; for 0.166667h; pH=9.5; Reagent/catalyst; Enzymatic reaction;
β-methoxy-isobutyraldehyde
13141-08-7

β-methoxy-isobutyraldehyde

dimethyl amine
124-40-3

dimethyl amine

(3-Methoxy-2-methyl-propyl)-dimethyl-amine

(3-Methoxy-2-methyl-propyl)-dimethyl-amine

Conditions
ConditionsYield
With imine reductase-33 from Aeromonas veronii; NADPH In methanol at 30℃; for 0.166667h; pH=9.5; Reagent/catalyst; Enzymatic reaction;
pyrrolidine
123-75-1

pyrrolidine

β-methoxy-isobutyraldehyde
13141-08-7

β-methoxy-isobutyraldehyde

C9H19NO

C9H19NO

Conditions
ConditionsYield
With imine reductase-22 from Streptomyces sp.; NADPH In methanol at 30℃; for 0.166667h; pH=9.5; Reagent/catalyst; Enzymatic reaction;
β-methoxy-isobutyraldehyde
13141-08-7

β-methoxy-isobutyraldehyde

1-methoxy-2-methyl-3-propanol
51866-93-4

1-methoxy-2-methyl-3-propanol

Conditions
ConditionsYield
With imine reductase from Streptomyces ipomoeae; NADPH In methanol at 30℃; for 0.166667h; pH=9.5; Enzymatic reaction;
β-methoxy-isobutyraldehyde
13141-08-7

β-methoxy-isobutyraldehyde

γ-methoxy-isobutylamine
26331-99-7

γ-methoxy-isobutylamine

Conditions
ConditionsYield
With imine reductase-22 from Streptomyces sp.; ammonia; NADPH In methanol at 30℃; for 0.166667h; pH=9.5; Reagent/catalyst; Enzymatic reaction;

13141-08-7Relevant articles and documents

α-(Acyloxy)dialkylnitrosamines: Effects of structure on the formation of N-nitrosiminium ions and a predicted change in mechanism

Hongliang, Cai,Fishbein, James C.

, p. 1826 - 1833 (2007/10/03)

The decay of α-(acyloxy)dialkylnitrosamines in aqueous solutions has been studied with a view toward elucidating mechanistic details and effects of structure on mechanism and reactivity. Rate constants (k1) for the pH-independent decay of 43 α-(acyloxy)dialkylnitrosamines have been determined. Observations from these and other experiments rule out decomposition via an anchimeric assistance mechanism involving the Z isomer that had previously been suggested. All of the reported data for most of the compounds is consistent with a mechanism involving the formation of N-nitrosiminium ions in or before the rate-limiting step. Structure -reactivity correlations indicate that the stability of α-(acyloxy)dialkylnitrosamines is determined by electronic properties of substituents at RN and RC as well as by the ability of substituents RC to engage in hyperconjugative interactions of C-H bonds with the developing cationic center in the transition state for nitrosiminium ion formation. Attachment of substituents of sufficient electron-withdrawing power at RN and RC results in a predicted change in mechanism to what appears to be an acyl group attack mechanism.

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