149286-01-1Relevant articles and documents
Efficient ring opening reactions of N-tosyl aziridines with amines and water in presence of catalytic amount of cerium(IV) ammonium nitrate
Chakraborty, Tushar K.,Ghosh, Animesh,Raju, T. Venugopal
, p. 82 - 83 (2003)
While methyl- and benzylamines opened N-tosyl aziridines 1 very efficiently in acetonitrile with complete regio- and stereoselectivity to give the corresponding diamines 2 and 3, respectively, in excellent yields, similar openings with water could only be achieved in the presence of a catalytic amount of cerium(IV) ammonium nitrate under very mild conditions furnishing the amino alcohols 4.
Conversion of aziridines to oxazolidines through geminal difunctionalization of vinyl arenes or by tandem ring-opening/closing reaction of aziridine itself
Ghosal, Nirnita Chakraborty,Santra, Sougata,Zyryanov, Grigory V.,Hajra, Alakananda,Majee, Adinath
, p. 3551 - 3555 (2016)
One pot synthesis of 1,3-oxazolidines derivatives was developed by two different approaches. Aziridines were used in the first approach instead of amino alcohol. Whereas, in the second approach we have developed an unprecedented reaction where aziridine i
Zirconyl nitrate mediated regioselective ring opening of epoxides and aziridines: an easy synthesis of β-nitrato-alcohols and -sulfonamides
Das, Biswanath,Krishnaiah, Maddeboina,Venkateswarlu, Katta
, p. 6027 - 6029 (2006)
Epoxides and aziridines are cleaved efficiently and regioselectively in the presence of zirconyl nitrate at room temperature to afford the corresponding β-nitrato-alcohols and -sulfonamides, respectively, in high yields.
Cobalt-Catalyzed Hydroalkynylation of Vinylaziridines
Biletskyi, Bohdan,Kong, Lingyu,Tenaglia, Alphonse,Clavier, Hervé
supporting information, p. 2578 - 2585 (2021/03/18)
Transition metal-catalyzed hydroalkynylation reactions are efficient transformations allowing the straightforward formation of functionalized alkynes. Therein, we disclose the cobalt-catalyzed hydroalkynylation of vinylaziridines giving rise to both linea
Visible-light-triggered Catalytic Halohydrin Synthesis from Epoxides and Trichloroacetonitrile by Copper and Iron Salts
Toda, Yasunori,Tanaka, Katsumi,Matsuda, Riki,Suga, Hiroyuki
supporting information, p. 1469 - 1471 (2019/12/02)
Preparation of vicinal halohydrins, in which copper or iron chlorides catalyze the ring-opening reaction of epoxides with visible light effectively, is described. The use of trichloroacetonitrile as a halogen source enables catalytic HCl generation under the mild conditions. This method can also be applied to the aziridine ring-opening reaction.