20498-71-9

Upstream product

• 138744-94-2 1,2-bis(4-methoxyphenyl)-2-oxoethyl acetate 
• 98-86-2 acetophenone 
• 105-13-5 4-Methoxybenzyl alcohol 
• 637-69-4 4-Methoxystyrene 
• 459-64-3 4-methoxybenzenediazonium tetrafluoroborate 
• 123-11-5 4-methoxy-benzaldehyde 
• 475250-52-3 2-[(4-methoxyphenyl)methyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 119-52-8 4,4'-dimethoxybenzoin 
• 64-17-5 ethanol 
• 100-07-2 4-methoxy-benzoyl chloride 

Downstream Products

• 4705-34-4 1,2-bis(4-methoxyphenyl)ethene 
• 155142-87-3 methyl 5,6-bis(4'-methoxyphenyl)-4-thiahexanoate 
• 4705-34-4 4,4'-dimethoxystilbene 
• 79813-32-4 (+/-)-di-O-methylsequirin D 
• 79813-33-5 (+/-)-sequirin D 
• 79754-58-8 7-hydroxy-4-p-hydroxybenzyl-3,4-dihydronaphthalen-1(2H)-one 
• 79754-55-5 4,5-bis-p-methoxyphenylpenta-2,4-dienoic acid 
• 79754-54-4 7-hydroxy-4-p-hydroxybenzyl-1,2,3,4-tetrahydro-1-naphthol 
• 79754-56-6 7-methoxy-4-p-methoxybenzyl-3,4-dihydronaphthalen-1(2H)-one 
• 79754-57-7 7-methoxy-4-p-methoxybenzyl-1,2,3,4-tetrahydro-1-naphthol 
• 79754-48-6 4,5-bis-(p-methoxyphenyl)pentanoic acid 
• 123-11-5 4-methoxy-benzaldehyde 
• 100-09-4 4-methoxybenzoic acid 
• 61732-72-7 meso-1,2-dibromo-1,2-di(4-methoxyphenyl)-2-ethane 

Relevant academic research and scientific papers

A Photoredox Coupling Reaction of Benzylboronic Esters and Carbonyl Compounds in Batch and Flow

Mild cross-coupling reaction between benzylboronic esters with carbonyl compounds and some imines was achieved under visible-light-induced iridium-catalyzed photoredox conditions. Functional group tolerance was demonstrated by 51 examples, including 13 he

Thermally Induced Carbohydroxylation of Styrenes with Aryldiazonium Salts

The radical carbohydroxylation of styrenes with aryldiazonium salts has been achieved under mild thermal conditions. A broad range of aryldiazonium salts was tolerated, and the reaction principle based on a radical–polar crossover mechanism could be exten

Synthesis of early-transition-metal carbide and nitride nanoparticles through the urea route and their use as alkylation catalysts

The use of urea as either a carbon or a nitrogen source enabled the synthesis of various early-transition-metal nitride and carbide nanoparticles (TiN, NbN, Mo2N, 2N, NbCxN1-x, Mo2 C and WC). The abil

Chemoselective control of hydrogenation among aromatic carbonyl and benzyl alcohol derivatives using Pd/C(en) catalyst

The hydrogenolysis of aromatic ketones and aldehydes quite smoothly give the corresponding methylene compounds via the formation of the intermediary benzyl alcohols in the presence of Pd/C as a catalyst. Therefore, it is extremely difficult to isolate the intermediary benzyl alcohol selectively. This paper describes a mild and chemoselective hydrogenation method of an aromatic carbonyl compound to benzyl alcohol using the 10% Pd/C(en) catalyst and its application to the chemoselective deacetoxylation reaction at the benzylic position in the presence of the benzyl alcohol functionality within the molecule.

REDUCTIVE COUPLING OF BENZOIC ACID HALIDES AND ESTERS USING LOW-VALENT TITANIUM

The reductive coupling of (substituted) benzoic acid chlorides and esters is achieved using low-valent titanium, generated from TiCl3 and LiAlH4.Both acid chlorides and esters seem to follow the same two reaction pathways: one path via tolanes to stilbenes, the other via benzils to complex mixtures of products arising from reduction and further coupling reactions.Although the exact product balance depends upon the reaction conditions the major product is (substituted) cis-stilbene.