20965-30-4Relevant academic research and scientific papers
Visible light promoted thiol-ene reactions using titanium dioxide
Bhat, Venugopal T.,Duspara, Petar A.,Seo, Sangwon,Abu Bakar, Nor Syazwani Binti,Greaney, Michael F.
supporting information, p. 4383 - 4385 (2015/03/18)
The radical addition of thiols to alkenes is reported under photoredox conditions, using visible light and TiO2 as a cheap and readily available photocatalyst.
Synthesis of indole, benzofuran and benzothiophene by pyrolysis of 2-anilinoethanol, 2-phenoxyethanol and 2-(phenylthio)ethanol acetates
Afxantidis, Jean,Aune, Jean-Pierre
, p. 395 - 403 (2007/10/03)
The synthesis of indole is possible by pyrolysis of compounds of the general formula : ΦNHCH2CH2X. The pyrolysis of the acetates (X = OCOCH3) of 2-anilinoethanol 3a, 2-phenoxyethanol 3b and 2-(phenylthio)ethanol 3c was studied by surface response methodology. A possible mechanism involving a radical pathway is discussed in terms of bond dissociation energies, thermal stability of the pyrolysis products and configuration of the radical intermediates. Elsevier,.
The Role of Neighboring Group Participation in the Acetolysis of α-(Phenylthio)-ω-alkanes
Rosnati, Vittorio,Saba, Antonio,Angius, Antonella,Casarini, Daniele
, p. 4094 - 4098 (2007/10/02)
In order to evaluate the relative importance of the neighboring group participation by the phenylthio group, the acetolysis of tosylates 1a-e has been studied.The results obtained confirmed that the participation decreases with the increasing ring size of
Soil fungi inhibiting agent
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, (2008/06/13)
Soil fungi-inhibiting agent containing as the active ingredient one or more of the compounds represented by the following general formula STR1 wherein I. WHEN BOTH X and Y are oxygen atoms, Z is hydrogen atom, unsubstituted alkyl group, unsubstituted alkenyl group, STR2 (in this case the compound is p-toluene sulfonate), NH2 CH2 -- (in this case the compound is p-toluene sulfonate), acyl group, ClCH2 CONH--, or alkyl group substituted by substituents such as R1 COO--, CH3 COS--, R2 O--, R2 S--, HO--, HOOC--, CH3 CONH--, acyl group, alkoxyacyl group, where R1 is lower-alkyl group or alkenyl group, R2 is lower-alkyl group or benzyl group; Ii. when X is oxygen and Y is sulfur or --NH--, Z is lower alkyl group; Iii. when X is sulfur and Y is oxygen, Z is lower-alkyl group, acetylmethyl group, methoxymethyl group, 2-methyl-1-propynyl group or nitromethyl group; Iv. when X is sulfur and Y is --NH--, Z is lower-alkyl group.
