22023-25-2

Basic information

• Product Name: Benzenemethanol, a-ethenyl-, benzoate
• CAS NO: 22023-25-2
• Molecular Formula: C16H14O2
• Molecular Weight: 238.286
• Mol File: 22023-25-2.mol
• Article Data: 13

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, a-ethenyl-, benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, a-ethenyl-, benzoate(22023-25-2)
• EPA Substance Registry System: Benzenemethanol, a-ethenyl-, benzoate(22023-25-2)

Safety Data

• Hazardous Substances Data: 22023-25-2(Hazardous Substances Data)

Upstream product

• 300-57-2 allylbenzene 
• 614-45-9 tert-Butyl peroxybenzoate 
• 103729-80-2 2-methyl-1-phenylprop-2-en-1-ol 
• 611-73-4 Benzoylformic acid 
• 108-88-3 toluene 
• 94-36-0 dibenzoyl peroxide 
• 65-85-0 benzoic acid 
• 532-32-1 sodium benzoate 
• 2687-12-9 cinnamyl chloride 
• 104-54-1 3-Phenylpropenol 
• 21087-29-6 trans-3-phenylprop-2-enyl chloride 
• 98-88-4 benzoyl chloride 
• 2243-53-0 trans-styrylacetic acid 
• 7717-48-8 lead(IV) tetrabenzoate 

Downstream Products

• 50555-04-9 cinnamyl benzoate 
• 156382-63-7 C₁₇H₂₂O₄ 
• 156382-65-9 2-methyl-2-(3-phenyl-2-propenyl)malonic acid diethyl ester 
• 84363-90-6 (1S,2R)-(-)-1,2-diphenylbut-3-en-1-ol 

Relevant articles and documents

Cu(OTf)2-DBN/DBU complex as an efficient catalyst for allylic oxidation of olefins with tert-butyl perbenzoate

Olefins, on treatment with tert-butyl perbenzoate in the presence of a catalytic amount of a complex of Cu(OTf)2 and chelating ligands such as DBN and DBU gave allylic benzoates under milder conditions. A variety of olefins were tested in the reaction.

NHPI- and TBAI-Co-Catalyzed Synthesis of Allylic Esters from Toluene Derivatives and Alkenes

An N -hydroxyphthalimide (NHPI) and tetrabutylammonium iodide (TBAI) co-catalyzed oxidative coupling reaction of toluene derivatives and alkenes has been disclosed. This method can serve as a new strategy to access allylic ester using toluene derivatives as oxyacylating reagent. This metal-free protocol also features the readily available starting materials, broad substrate scope, and mild reaction conditions.

Oxidation-Reduction Condensation of Diazaphosphites for Carbon-Heteroatom Bond Formation Based on Mitsunobu Mechanism

An efficient oxidation-reduction condensation reaction of diazaphosphites with various nonacidic pronucleophiles in the presence of DIAD as a weak oxidant has been developed for carbon-heteroatom bond formation. This mild process affords structurally diverse tertiary amines, secondary amines, esters, ethers, and thioethers in moderate to excellent yields. The selective synthesis of secondary amines from primary amines has been achieved. Importantly, a practical application to the synthesis of antiparkinsonian agent piribedil has been demonstrated.

A chiral sulfoxide-ligated ruthenium complex for asymmetric catalysis: Enantio- and regioselective allylic substitution

The design and synthesis of a novel chiral sulfoxide-ligated cyclopentadienyl ruthenium complex is described. Its utility as an asymmetric variant of [CpRu(MeCN)3]PF6 is demonstrated through its ability to function in the branched-selective asymmetric allylic alkylation of phenols and carboxylic acids. Water has also been shown to act as a competent nucleophile in this reaction to generate branched allyl alcohols with good regio- and enantioselectivities.