38604-74-9Relevant academic research and scientific papers
Hypervalent Iodine(III)-Promoted Phenyl Transfer Reaction from Phenyl Hydrazides to Nitriles
Yan, Yan,Zhang, Zhiguo,Wan, Yameng,Zhang, Guisheng,Ma, Nana,Liu, Qingfeng
supporting information, p. 7957 - 7963 (2017/08/14)
A useful transformation of nitriles to N-phenyl amides has been achieved through a novel intermolecular phenyl transfer reaction from phenyl hydrazides and N-addition to nitriles in the presence of PIFA under mild and solvent-free conditions. This cross-coupling reaction includes the oxidative cleavage of sp2 C-N bonds of phenyl hydrazides to form a phenyl radical and the subsequent N-addition to cyanos to form new sp2 C-N bonds and provides efficient access to various N-phenyl amides in moderate to good yields under mild reaction conditions.
Acylation Reactions of Phenylhydrazines. Preparation and Properties of New Diacylphenylhydrazines
Hearn, Michael J.,Magee, Debra J.,Alhart, Randi,Gleva, Marye,Goldstein, Susan,et al.
, p. 129 - 131 (2007/10/02)
Anhydride acylation reactions of a variety of substituted arylhydrazines under mild conditions led to controlled formation of the acid phenylhydrazides I (Table I).The procedures were tallored to the particular state of the starting arylhydrazine.Second-s
