4469-66-3

Basic information

• Product Name: 4-Phenyl-2-methoxycarbonyl-4-enoic acid methyl ester
• Synonyms: 4-Phenyl-2-methoxycarbonyl-4-enoic acid methyl ester
• CAS NO: 4469-66-3
• Molecular Weight: 248.279
• Mol File: 4469-66-3.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 4-Phenyl-2-methoxycarbonyl-4-enoic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Phenyl-2-methoxycarbonyl-4-enoic acid methyl ester(4469-66-3)
• EPA Substance Registry System: 4-Phenyl-2-methoxycarbonyl-4-enoic acid methyl ester(4469-66-3)

Safety Data

• Hazardous Substances Data: 4469-66-3(Hazardous Substances Data)

Upstream product

• 591-50-4 iodobenzene 
• 40637-56-7 dimethyl allylmalonate 
• 3360-54-1 3-bromo-2-phenylprop-1-ene 
• 108-59-8 malonic acid dimethyl ester 
• 95124-07-5 dimethyl (prop-2-yn-1-yl)malonate 
• 98-80-6 phenylboronic acid 
• 3360-53-0 1-bromo-2-phenyl-1-propene 
• 105-53-3 diethyl malonate 
• 4469-64-1 2-(2-phenyl-allyl)-malonic acid diethyl ester 
• 85291-68-5 (1,3-dibromopropan-2-yl)benzene 
• 18424-76-5 dimethyl malonate sodium salt 
• 74866-37-8 [3-(benzenesulfonyl)prop-1-en-2-yl]benzene 
• 54436-58-7 N-benzylpent-4-en-1-amine 
• 186581-53-3 diazomethane 

Downstream Products

• 4469-65-2 2-(2-phenylallyl)malonic acid 
• 1392282-78-8 C₁₇H₂₄O₂ 
• 1392283-17-8 C₁₄H₁₈O₂ 
• 1392283-24-7 C₁₇H₂₀O₄ 
• 115463-41-7 dimethyl 3-phenylcyclohexane-1,1-dicarboxylate 
• 115340-08-4 dimethyl 3-phenylcyclopentane-1,1-dicarboxylate 
• 100747-48-6 dimethyl 3-phenylcyclopent-3-ene-1,1-dicarboxylate 
• 1392282-67-5 C₁₇H₂₂O₂ 
• 1392282-66-4 C₁₆H₁₈O₄ 
• 1392283-15-6 C₁₈H₂₂O₄ 
• 4300-13-4 dimethyl 2-(2-phenylpropyl)malonate 
• 16433-43-5 4-phenyl-1-pentanoic acid 

Relevant articles and documents

Desymmetrization of diolefinic diols by enantioselective amino-thiocarbamate-catalyzed bromoetherification: Synthesis of chiral spirocycles

A facile, efficient, and highly diastereo- and enantioselective bromoetherification of diolefinic diols has been developed using an amino-thiocarbamate catalyst. Further manipulations of the bromoether products enabled entry into a new class of spirocycle

Iridium-catalyzed hydroiodination of functionalized alkynes

The efficiency of an Ir(I)/HI system has been studied. The association of hydroiodic acid with iridium has been tested in the catalytic hydroiodination of alkynes. The use of [Ir(cod)Cl]2 dimer led to clean hydroiodination reactions and afforde

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The Heck reaction of alkenes bearing in δ position an enolate of β-diester, βketo ester or β-sulfonyl ester leads to cyclopentanes issued from the intramolecular displacement of the carbone sp3-palladium bond by this enolate. This cyclisation is not observed when the enolate is in β or ε position or in the case of a δ-ethylenic amine and βelimination products are only obtained.