55705-15-2

Basic information

• Product Name: 1-(4-methoxyphenyl)-2-(benzoyloxy)propan-1-one
• Synonyms: 1-(4-methoxyphenyl)-2-(benzoyloxy)propan-1-one
• CAS NO: 55705-15-2
• Molecular Weight: 284.312
• Mol File: 55705-15-2.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: 1-(4-methoxyphenyl)-2-(benzoyloxy)propan-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(4-methoxyphenyl)-2-(benzoyloxy)propan-1-one(55705-15-2)
• EPA Substance Registry System: 1-(4-methoxyphenyl)-2-(benzoyloxy)propan-1-one(55705-15-2)

Safety Data

• Hazardous Substances Data: 55705-15-2(Hazardous Substances Data)

Upstream product

• 65-85-0 benzoic acid 
• 121-97-1 4-Methoxypropiophenone 
• 100-42-5 styrene 
• 536-74-3 phenylacetylene 
• 5349-60-0 1-(4-methoxyphenyl)-1-propanol 
• 100-52-7 benzaldehyde 
• 108-88-3 toluene 
• 28330-55-4 N-(tert-butyloxycarbonyl)-N-methyl-O-benzoyl-hydroxylamine 
• 27130-46-7 N-methyl-O-(phenylcarbonyl)hydroxylamine hydrochloride 
• 532-32-1 sodium benzoate 
• 21086-33-9 2-bromo-1-(4-methoxyphenyl)-1-propanone 

Downstream Products

• 84672-19-5 4-(5-Methyl-2-phenyl-oxazol-4-yl)-phenol 
• 84686-94-2 2-{4-[2-(4-Chloro-phenyl)-5-methyl-oxazol-4-yl]-phenoxy}-butyric acid ethyl ester 
• 84671-81-8 2-{4-[2-(4-Chloro-phenyl)-5-methyl-oxazol-4-yl]-phenoxy}-propionic acid ethyl ester 
• 84671-98-7 2-{4-[2-(4-Chloro-phenyl)-5-methyl-oxazol-4-yl]-phenoxy}-butyric acid 
• 84671-79-4 2-Methyl-2-[4-(5-methyl-2-phenyl-oxazol-4-yl)-phenoxy]-propionic acid ethyl ester 
• 84671-78-3 2-[4-(5-Methyl-2-phenyl-oxazol-4-yl)-phenoxy]-propionic acid ethyl ester 
• 84671-77-2 [4-(5-Methyl-2-phenyl-oxazol-4-yl)-phenoxy]-acetic acid ethyl ester 
• 84671-96-5 2-Methyl-2-[4-(5-methyl-2-phenyl-oxazol-4-yl)-phenoxy]-propionic acid 
• 84672-13-9 4-(4-methoxyphenyl)-5-methyl-2-phenyloxazole 

Relevant articles and documents

Copper-catalyzed α-C-H acyloxylation of carbonyl compounds with terminal alkynes

Herein, a copper/TBHP catalyst system for the α-C-H acyloxylation of carbonyl compounds is developed using terminal alkynes as the acyloxy source. A variety of carbonyl compounds and terminal alkynes are tolerated in this reaction. In addition, its possible mechanism is proposed.

I2/TBHP-mediated oxidative coupling of ketones and toluene derivatives: a facile method for the preparation of α-benzoyloxy ketones

An efficient oxidative approach was developed for the α-benzoyloxylation of ketones using tert-butyl hydroperoxide (TBHP). This process provided facile access to a wide range of α-benzoyloxy ketones in good to excellent yields via the direct oxidative α-benzoyloxylation of a structurally diverse series of ketones using simple arylmethane compounds.

NBu4NI-catalyzed α-benzoxylation of ketones with terminal aryl alkenes

A metal-free protocol for the α-benzoxylation of ketones has been developed by using terminal aryl alkenes as an arylcarboxy surrogate. Moderate to good yields were attained for a variety of propiophenones and acetophenones by using tetra-n-butylammonium iodide (TBAI) as the catalyst and tert-butyl hydroperoxide (TBHP) as the oxidant under ambient reaction conditions. An efficient synthesis for the α-benzoxylation of aryl ketones has been developed by using terminal aryl alkenes as the arylcarboxy surrogate. The products were obtained in moderate to good yields for a broad scope of substrates. Tetra-n-butylammonium iodide (TBAI) and tert-butyl hydroperoxide (TBHP) were employed as the catalyst and oxidant, respectively.