880-68-2Relevant articles and documents
C-P bond formation of cyclophanyl-, and aryl halides: Via a UV-induced photo Arbuzov reaction: A versatile portal to phosphonate-grafted scaffolds
Br?se, Stefan,Hassan, Zahid,Nieger, Martin,O?wald, Simon,Zippel, Christoph
, p. 3309 - 3312 (2022/02/11)
A new versatile method for the C-P bond formation of (hetero)aryl halides with trimethyl phosphite via a UV-induced photo-Arbuzov reaction, accessing diverse phosphonate-grafted arenes, heteroarenes and co-facially stacked cyclophanes under mild reaction
Efficient energy and electron transfer between donor and acceptor chromophores in aluminophosphate hybrid materials
Lo, Chih-Yuan,Chen, Chih-Hsien,Tsai, Tim W. T.,Zhang, Long,Lim, Tsong-Shin,Fann, Wunshain,Chan, Jerry C. C.,Luh, Tien-Yau
experimental part, p. 539 - 546 (2011/04/22)
The first organic-inorganic hybrid materials (OIHMs) having one or a combination of two chromophores in different ratios are obtained from the aryl phosphonic acid and aluminum lactate via sol gel process. The structures of these OIHMs are analyzed by the 27Al and 31P NMR. The fluorescence resonance energy transfer (FRET) as well as photoinduced electron transfer (PET) between donor and acceptor chromophores in these hybrid materials have been investigated and the efficiencies can be up to 97 and 93%, respectively.
Mesoporous crystalline solid compound of a diphosphonate/phosphite of a tetravalent metal, with a narrow distribution of mesopores
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, (2008/06/13)
The present invention discloses a compound comprising a diphosphonate/phosphite of a tetravalent metal: (where M, R, x and y have the meaning given in the description), in the form of a crystalline solid with an alpha-type lamellar structure with a distance between layers of 7.4 to 20? (depending on the dimensions of radical R), a BET surface area of 250 to 400m2 /g, and porosity within the mesopore range, with at least 50% of the pores measuring 20 to 30?. The compound, depending on the radical R used, may or may not have microporosity in the region between layers. Such a diphosphonate/phosphite of a tetravalent metal is obtained by reaction between diphosphonic acid, phosphorous acid and an oxyhalide of a tetravalent metal, in a solvent comprising dimethyl-sulphoxide/water containing hydrofluoric acid.