935-05-7

Basic information

• Product Name: Nitrous acid benzyl ester
• Synonyms: Nitrous acid benzyl ester
• CAS NO: 935-05-7
• Molecular Formula: C₇H₇NO₂
• Molecular Weight: 137.136
• Mol File: 935-05-7.mol
• Article Data: 9

Chemical Properties

• Boiling Point: 251.96°C (rough estimate)
• Flash Point: 71.2°C
• Appearance: /
• Density: 1.0750
• Vapor Pressure: 1.24mmHg at 25°C
• Refractive Index: 1.5323 (estimate)
• CAS DataBase Reference: Nitrous acid benzyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Nitrous acid benzyl ester(935-05-7)
• EPA Substance Registry System: Nitrous acid benzyl ester(935-05-7)

Safety Data

• Hazardous Substances Data: 935-05-7(Hazardous Substances Data)

Usage

InChI:InChI=1/C7H7NO2/c9-8-10-6-7-4-2-1-3-5-7/h1-5H,6H2

Upstream product

• 60-29-7 diethyl ether 
• 100-39-0 benzyl bromide 
• 100-51-6 benzyl alcohol 
• 62453-13-8 Benzyl-[1-pyrrolidin-1-yl-meth-(E)-ylidene]-amine 
• 64-19-7 acetic acid 
• 7697-37-2 nitric acid 
• 28571-11-1 N-benzyl-N-nitroso-hydroxylamine 
• 19910-09-9 peroxyphenylacetic acid 
• 7782-77-6 cis-nitrous acid 
• 10544-72-6 dinitrogen tetraoxide 
• 108-88-3 toluene 
• 7664-93-9 sulfuric acid 
• 68-12-2 N,N-dimethyl-formamide 
• 57-13-6 urea 

Downstream Products

• 100-52-7 benzaldehyde 
• 65-85-0 benzoic acid 
• 100-51-6 benzyl alcohol 
• 5585-14-8 3,4-diphenyl-furazan 2-oxide 
• 4424-00-4 silicic acid tetrabenzyl ester 
• 16710-22-8 4-benzyloxy-3,4-diphenyl-oxazolidine-2,5-dione 5-(O-benzoyl-oxime) 
• 16710-21-7 4-benzyloxy-3,4-diphenyl-oxazolidine-2,5-dione 5-(O-acetyl-oxime) 
• 103-30-0 (E)-1,2-diphenyl-ethene 
• 92-52-4 biphenyl 
• 103-29-7 1,1'-(1,2-ethanediyl)bisbenzene 
• 71-43-2 benzene 
• 108-95-2 phenol 
• 16710-18-2 4-benzyloxy-3,4-diphenyl-oxazolidine-2,5-dione 5-oxime 
• 55-18-5 N-Nitrosodiethylamine 

Relevant articles and documents

Synthetic method of alpha-cyanobenzoxime sodium

The invention relates to a synthesis method of alpha-cyanobenzoxime sodium, which comprises the following two steps: step 1, reacting an alcohol (alcohol: sodium nitrite: acid = 1: 1-3.5: 1-5) solution and a sodium nitrite (alcohol: sodium nitrite: acid =

Silica-supported 4-OH-TEMPO/NOx: A novel and efficient catalyst for aerobic oxidation of alcohols

Silica-supported 4-OH-2,2,6,6-tetramethylpiperidyl-1-oxy/NOx (4-OH-TEMPO was immobilized on the surface of silica using the sol-gel method, and then it adsorbed NOx), as a heterogeneous catalyst, has exhibited good catalytic performance in alcohol oxidation. A broad range of alcohols were oxidized to their corresponding aldehydes or ketones with more than 99% selectivity and 99% conversion rate by such a catalyst system at room temperature in air. NOx not only acted as an electron bridge between O2 and 4-OH-TEMPO but also were conducive to the formation of the aldehydes as active component. A possible mechanism for oxidation of alcohols promoted by silica-supported 4-OH-TEMPO/NOx was supposed. [Supplementary materials are available for this article. Go to the publisher's online edition of Synthetic Communications for the following free supplemental resource(s): Full experimental and spectral details.] Copyright

Novel and highly selective conversion of alcohols and thiols to alkyl nitrites with triphenylphosphine/2,3-dichloro-5,6-dicyanobenzoquinone/Bu 4NNO2 system

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