Redox potentials for the studied complexes 1Fe, 1Co and 1Ni in anhydrous CH3CN, and CH3CN/H2O mixtures

June 19, 2024

• Title:       

  Redox potentials for the studied complexes 1_Fe, 1_Co and 1_Ni in anhydrous CH₃CN (CAS 75-05-8), and CH₃CN/H₂O (CAS 7732-18-5) mixtures

• Image Source:

  Photo- and electrocatalytic H2 production by new first-row transition-metal complexes based on an aminopyridine pentadentate ligand

• Mark:

  Table 1

• Associated context:

  A summary of the M^I/0, M^II/I, and M^III/II reduction potentials is presented in Table 1. The proton reduction overpotential (h) for complexes 1_Co (590 mV) and 1_Ni  (560 mV) turned to be considerable lower than for 1_Fe  (870 mV) (Table 1).