Comparison of the average metal–oxygen (M–Oav), metal–nitrogen (M–Nav) and metal–halide (M–Xav) bond lengths (Å) in titanium Schiff base complexes

August 15, 2024

• Title:       

  Comparison of the average metal–oxygen (M–O_av), metal–nitrogen (M–N_av) and metal–halide (M–X_av) bond lengths (Å) in titanium Schiff base complexes

• Image Source:

  Halide titanium(IV) Schiff base complexes; fluoride and bromide derivatives and evidence for a new seven-coordinate chloride intermediate

• Mark:

  Table 2

• Associated context:

  Table 2 compares average metal-oxygen (M–O_av), metal–nitrogen (M–N_av) and metal–halide (M–X_av) bond lengths (Å)  in Group 4 Schiff base complexes. The Ti–O bond lengths of 1.858(2) Å and 1.876(2) Å in 2 is comparable to the average Ti–O bond length of 1.835(5) Å reported for [TiCl₂(salen)]ؒ thf.