Synthesis and electrochemical properties of peripheral, non-peripheral tetra [2-(3,5-diphenyl-1H-1,2,4-triazol-1-yl)ethoxy] substituted cobalt(II), manganese(III) phthalocyanines

Add time:08/01/2019    Source:sciencedirect.com

In this study, 4-[2-(3,5-diphenyl-1H-1,2,4-triazol-1-yl)ethoxy]phthalonitrile ET-CN, 3-[2-(3,5-diphenyl-1H-1,2,4-triazol-1-yl)ethoxy]phthalonitrile n-ET-CN and cobalt(II), manganese(III) phthalocyanines bearing [2-(3,5-diphenyl-1H-1,2,4-triazol-1-yl)ethoxy] group at peripheral, non-peripheral positions were synthesized for the first time. The new compounds have been characterized by FT-IR, NMR (only for ET-CN, n-ET-CN), mass and UV-Vis spectroscopy (except ET-CN, n-ET-CN) techniques. Electrochemistry of cobalt(II), manganese(III) phthalocyanines bearing [2-(3,5-diphenyl-1H-1,2,4-triazol-1-yl)ethoxy] group at peripheral, non-peripheral positions were examined by using cyclic voltammetry.

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