Nitrogen-doped graphene quantum dots as highly sensitive and selective fluorescence sensor detection of iodide ions in milk powder

Add time:08/03/2019    Source:sciencedirect.com

In this work, we have successfully designed an “off-on” fluorescent sensor based on nitrogen-doped graphene quantum dots (N-GQDs) system to detect iodide ions in milk powder. The fluorescence intensity of N-GQDs was significantly quenched by Ag+ through forming N-GQDs/Ag+ complexes due to the binding between Ag+ and functional groups on the surface of N-GQDs. However, with the addition of I− to the N-GQDs/Ag+ system, the fluorescence intensity was significantly restored because of the formation of AgI complexes by "hard and soft acids and bases principle"(HSAB) between Ag+ and I−. Under the optimal conditions, Ag+ had a good linear relationship in the range of 0.01–0.6 μM. The fluorescence intensity of N-GQDs/ Ag+ linearly increased with the increasing of I− concentrations in the range of 0.0125–4.0 μM, and the detection limit (LOD) was 5.6 nM. The proposed method has been successfully applied to the detection of milk powder, which is a detection system with good development prospects owing to convenience, rapidity and low toxicity.

We also recommend Trading Suppliers and Manufacturers of nitrogen iodide (cas 13444-85-4). Pls Click Website Link as below: cas 13444-85-4 suppliers

Prev:Freezing-enhanced reduction of chromate by nitrite
Next:Theoretical investigation on the interaction of benzazaborole derivatives with iodide: Structural, binding and fluorescence properties analysis)