Electrdeposition of CoWRe alloys from polyligand citrate-pyrophosphate electrolyte
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Add time:08/07/2019 Source:sciencedirect.com
A polyligand citrate-pyrophosphate electrolyte is proposed, which makes it possible to obtain uniform bright coatings containing 15–40 at.% Re and 10–4 at.% W and a current efficiency of up to 93% depending on the concentration of potassium perrhenate in the solution. The dependence of the chemical composition, current efficiency and morphology of ternary electrolytic alloys CoWRe on the electrolyte components and the electrolysis conditions is presented. The coatings obtained are fine-crystalline and X-ray amorphous and have a high microhardness of 574–788 HV.
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