Regioselective chelation in the reaction of N-trimethylsilyl-N-acetylglycine N’,N’-dimethylamide with chloro(chloromethyl)DIMETHYLSILANE (cas 1111-74-6)

Add time:08/15/2019    Source:sciencedirect.com

Regioselective reaction of N-trimethylsilyl-N-acetylglycine N’,N’-dimethylamide with chloro(chloromethyl)dimethylsilane yields chlorosilane MeC(O)N(CH2SiMe2Cl)CH2C(O)NMe2 with a five-membered C,O-chelate ring involving the N-acetyl group rather than the six-membered ring involving the N’,N’-dimethylamide fragment. According to X-ray data, the pentacoordinate silicon atom in the product has a TBP environment with the halogen and oxygen atoms in axial positions.

We also recommend Trading Suppliers and Manufacturers of DIMETHYLSILANE (cas 1111-74-6). Pls Click Website Link as below: cas 1111-74-6 suppliers

Prev:Adsorption kinetics of DIMETHYLSILANE (cas 1111-74-6) at Si(0 0 1)
Next:Interpretation of initial stage of 3C-SiC growth on Si(1 0 0) using DIMETHYLSILANE (cas 1111-74-6))