The chemistry and stereochemistry of poly(N-alkyliminoalanes). XVII. The syntheses of poly(N-alkyliminoalanes) from dimethylamino- or methoxy-propylamines☆
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Add time:08/20/2019 Source:sciencedirect.com
3-Dimethylamino-n-propylamine, 2-dimethylamino-isopropylamine and 3-methoxy-n-propylamine have been used to synthesize poly(N-alkyliminoalanes) (PIA) by different routes. These amines yielded PIA with open cage structures, in some cases even under the rather drastic conditions of direct synthesis from aluminum, amine and hydrogen. Reaction between LiAIH4 and mines gave open cage complexes with LiH.
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