The sonochemical arylation of malonic esters mediated by manganese triacetate

Add time:08/21/2019    Source:sciencedirect.com

The intermolecular arylation of malonate esters in acetic acid solution in the presence of manganese(III) triacetate is known to proceed via an Electron Transfer mechanism. Under sonication, this reaction undergoes only minor changes. In contrast, the intramolecular reaction of dimethyl α-(3-phenylpropyl)malonate provides a new case of sonochemical switching, with the formation of compounds 7–9, while conventional thermal conditions generate only the bicyclic compound 6. Reactions using the more powerful oxidant, cerium ammonium nitrate are governed by the formation of the nitrate ester 11. Compounds 7–9 are isolated in yields lower than with MnTA, and in proportions depending on the conditions, thermal or sonochemical.

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