Electrochemistry of coordination compounds: XXIII. Rhodium(0): Electrogeneration and characterization of tetrakis(triisopropyl-phosphite)rhodium☆
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Add time:08/26/2019 Source:sciencedirect.com
Cyclic voltammetry on [RhL4]+ (L = triisopropylphosphite) in 1,2-dimethoxyethane has shown that the complex undergoes a two-electron reduction to [RhL4]−, which is reoxidized to [RhL4]+ in two separate one-electron steps. The intermediate d9 species [RhL4] is a long-lived species to which a square-planar geometry has been assigned on the basis of the electronic and ESR spectra.
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