Short communication2-Hydroxybenzophenone (cas 117-99-7)-controlled self-assembly of enneanuclear lanthanide(III) hydroxo coordination clusters with an “hourglass”-like topology☆

Add time:08/26/2019    Source:sciencedirect.com

Enneanuclear lanthanide(III) hydroxo coordination clusters with an “hourglass”- or “sandglass”-like topology have been synthesized via 2-hydroxybenzophenone-controlled hydrolysis of the metal ions in ethanol; the EuIII9 complex displays an intense red, metal-centered emission in the solid state at room temperature which is achieved by an indirect process (antenna effect).

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