NoteFluorous interactions in complexes of lead(II) hexafluoroacetylacetonate
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Add time:08/29/2019 Source:sciencedirect.com
Structure determinations for 2,2′-bipyridine and 1,10-phenanthroline adducts of lead(II) hexafluoroacetylacetonate, [Pb(bipy)2(hfacac)2] (1), [Pb(bipy)(hfacac)2] (2), and [Pb(phen)(hfacac)2] (3), show that the balance of intermolecular forces within the lattices is seemingly sensitive to the adduct stoichiometry but not to the nature of the heteroaromatic base. In 3, a structure, in which there is an apparent preference for CF/aromatic interactions over separate CF/CF and aromatic/aromatic interactions, is essentially identical at both 120 and 293 K.
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