Studies directed toward the synthesis of the Rutamycin (cas 1404-59-7)s. Assemblage of the polypropionate region of Rutamycin (cas 1404-59-7) B
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Add time:09/01/2019 Source:sciencedirect.com
the asymmetric synthesis of the polypropionate segment of Rutamycin (cas 1404-59-7) B is reported. In this convergent synthesis the construction of the C1-C8 and C9-C17 subunits and their union through a double stereodifferentiating aldol fragment coupling are described. The stereoselectivity of this coupling reaction critically depends on both the configuration and choice of protecting group for the C9 oxygen.
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