Application of chiral (E)-crotylsilanes in synthesis: The asymmetric synthesis of the C1C17 polypropionate fragment of Rutamycin (cas 1404-59-7) B
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Add time:09/03/2019 Source:sciencedirect.com
The asymmetric synthesis of the polypropionate fragment of Rutamycin (cas 1404-59-7) B is reported employing chiral allylsilane bond construction methodology for the introduction of six of the nine stereogenic centers. In this paper, the construction of the C3C12 subunit and its coupling to the aldehyde 12 through a Mukaiyama-type aldol reaction are described.
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