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  • Full length articleNanoalumina supported palladium(0) nanoparticle catalyst for releasing H2 from Dimethylamine (cas 124-40-3) borane

  • Add time:09/08/2019    Source:sciencedirect.com

    Palladium(II) 2,4-pentanedionate, impregnated on alumina nanopowder, was reduced by Dimethylamine (cas 124-40-3) borane (DMAB) forming Pd(0) nanoparticles (NPs) at room temperature. Pd(0) NPs could be isolated from solution and characterized by ATR-IR, UV–vis, XRD, SEM, TEM, XPS and BET. The results obtained from TEM images reveal the formation of palladium(0) nanoparticles on gamma-alumina, having a mean particle size of 7.1 ± 2.6 nm. Alumina supported Pd(0) NPs with various metal loadings were employed as catalyst in dehydrogenation of DMAB at room temperature and the sample with 5.0% wt. Pd provides the highest turnover frequency (TOF = 73 h−1) at 25.0 ± 0.5 °C. Kinetics of the catalytic dehydrogenation was also investigated depending on Pd concentration and temperature to determine the kinetic parameters of the H2 release reaction.

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