Revisit to the reaction of [60]fullerene with nitrile ylides generated from imidoyl chlorides and triethylamine

Add time:10/01/2019    Source:infona.pl

The reaction of [60]fullerene (C 60 ) with nitrile ylides generated from N-benzyl-4-nitrobenzimidoyl chloride/N-(4-chlorobenzyl)-4-nitrobenzimidoyl chloride and triethylamine gave only isomeric monoadducts of C 60 with [6,6]-closed structure. No [5,6]-open adduct of C 60 could be identified from these reactions. The previously reported [5,6]-open product of C 60 should be reassigned as a [6,6]-closed product.

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