- COMPOSITION, PRODUCTION METHOD FOR COMPOSITION, AND PRODUCTION METHOD FOR UNSATURATED COMPOUND
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The invention relates to a composition excellent in stability during storage and stability during utilization, and relates to a method of producing the composition. The composition includes a compound (A) represented by general formula (1) and a compound (B) represented by general formula (2), and includes 0.00002 to 0.2 parts by mass of the compound (B) with respect to 100 parts by mass of the compound (A), [in-line-formulae](R1—COO)n—R2—(NCO)m??(1)[/in-line-formulae] [in-line-formulae](R1—COO)n—R2—(R3—R1)m??(2)[/in-line-formulae] wherein in general formulae (1) and (2), R1 is an ethylenically unsaturated group having 2 to 7 carbon atoms; R2 is a (m+n)-valent hydrocarbon group having 1 to 7 carbon atoms and optionally contains an ether group; R1 and R2 in the general formula (1) are the same as R1 and R2 in the general formula (2); in general formula (2), R3 is —NHC(═O)—; and n and m each represent an integer of one or two.
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Paragraph 0131; 0132
(2021/07/02)
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- METHOD FOR PRODUCING CARBAMATE AND METHOD FOR PRODUCING ISOCYANATE
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The present invention provides a method for producing a carbamate that includes a step (1) and a step (2) described below: (1) a step of producing a compound (A) having a urea linkage, using an organic primary amine having at least one primary amino group per molecule and at least one compound selected from among carbon dioxide and carbonic acid derivatives, at a temperature lower than the thermal dissociation temperature of the urea linkage; and(2) a step of reacting the compound (A) with a carbonate ester to produce a carbamate.
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- ISOCYANATE PRODUCTION METHOD
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An isocyanate production method according to the present invention is a method in which an isocyanate is produced by subjecting a carbamate to thermal decomposition, and includes: a step of preparing a mixture liquid containing the carbamate, an inactive solvent and a polyisocyanate compound; a step of conducting a thermal decomposition reaction of the carbamate by continuously introducing the mixture liquid into a thermal decomposition reactor; a step of collecting a low-boiling decomposition product by continuously extracting the low-boiling decomposition product in a gaseous state from the reactor, the low-boiling decomposition product having a boiling point lower than the polyisocyanate compound; and a step of collecting a high-boiling component by continuously extracting, from the reactor, a liquid phase component which is not collected in a gaseous state at the step of collecting the low-boiling decomposition product.
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Paragraph 0447-0450; 0459; 0478
(2020/05/02)
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- COMPOSITION, CURABLE COMPOSITION, PRODUCTION METHOD THEREFOR, AND CURED PRODUCT
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A composition is provided which includes a polymerizable compound (A) which includes a (meth)acryloyl group and an isocyanate group in a molecule thereof; and a reaction accelerator (B) which is a compound including a (meth)acryloyl group and a halogenated carbamoyl group in a molecule.
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Paragraph 0162-0163
(2017/01/12)
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- The ethylenically unsaturated group-containing isocyanate compound
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PROBLEM TO BE SOLVED: To provide a production method capable of obtaining an ethylenically unsaturated group-containing isocyanate compound with high yield, which is excellent in safety to human bodies or environments without using phosgene and in which the production processes and production facilities are simplified.SOLUTION: There is a method for producing an ethylenically unsaturated group-containing isocyanate compound which produces a compound having an ethylenically unsaturated bond and an isocyanate group in the molecule using an amino alcohol as a raw material, wherein the method has a step of producing a cyclic compound having a urethane bond in the molecule as an intermediate.
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Paragraph 0134; 0141
(2019/01/04)
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- PROCESS FOR PRODUCING ISOCYANATES
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The invention relates a process for producing isocyanates comprising the steps of a) providing an azolide and optionally a solvent, and b) adding an acid at a temperature below about 40C. The invention also relates to the isocyanate obtainable by such a process.
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- Process for producing isocyanates
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The invention relates a process for producing isocyanates comprising the steps of a) providing an azolide and optionally a solvent, and b) adding an acid at a temperature below about 40°C. The invention also relates to the isocyanate obtainable by such a process.
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- METHOD FOR PRODUCING (METH)ACRYLATE DERIVATIVE HAVING ISOCYANATE GROUP
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The invention aims to provide a method whereby (meth)acrylate derivatives having an isocyanate group can be obtained in high yield by dehydrochlorination of 3-chloropropionate derivatives having an isocyanate group under industrially advantageous and mild conditions, and the content of residual hydrolyzable chlorine can be reduced. A method for producing a (meth)acrylate derivative having an isocyanate group comprises performing dehydrochlorination of a 3-chloropropionate derivative having an isocyanate group in the presence of a basic nitrogen compound having a tertiary nitrogen, the tertiary nitrogen of the basic nitrogen compound having
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Page/Page column 22-23
(2008/06/13)
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- PROCESS FOR PREPARING HIGH PURITY (METH)ACRYLOYLOXYALKYL ISOCYANATE
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A process for preparing a high purity (meth)acryloyloxyalkyl isocyanate having a very small hydrolyzable chlorine content is provided. The high purity (meth)acryloyloxyalkyl isocyanate is prepared by subjecting a hydrolyzable chlorine containing (meth)acryloyloxyalkyl isocyanate to mixing treatment with an epoxy compound and an amine at a temperature of from 110 to 160oC to prepare a mixture; and preparing a high purity (meth)acryloyloxyalkyl isocyanate from the resulting mixture with distillation. In particular, it is possible to effectively prevent (meth)acryloyloxyalkyl isocyanate from polymerization during the distillation by adding a polymerization inhibitor such as phenothiazine and the like.
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Page/Page column 21-23; 24; 26-27
(2008/06/13)
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