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Cas Database

141-52-6

141-52-6

Identification

  • Product Name:Ethanol, sodium salt(1:1)

  • CAS Number: 141-52-6

  • EINECS:205-487-5

  • Molecular Weight:68.0509

  • Molecular Formula: C2H5NaO

  • HS Code:2905.19

  • Mol File:141-52-6.mol

Synonyms:Ethanol, sodiumsalt (9CI);Ethyl alcohol, sodium salt (8CI);Caustic alcohol;Ethoxysodium;Sodium ethanolate;Sodium ethoxylate;Sodium ethylate;

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Safety information and MSDS view more

  • Pictogram(s):FlammableF,CorrosiveC,IrritantXi

  • Hazard Codes:F,C,Xi,N

  • Signal Word:Danger

  • Hazard Statement:H251 Self-heating; may catch fireH314 Causes severe skin burns and eye damage

  • First-aid measures: General adviceConsult a physician. Show this safety data sheet to the doctor in attendance.If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

  • Fire-fighting measures: Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Wear self-contained breathing apparatus for firefighting if necessary.

  • Accidental release measures: Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8. Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Pick up and arrange disposal. Sweep up and shovel. Keep in suitable, closed containers for disposal.

  • Handling and storage: Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2. Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

  • Exposure controls/personal protection:Occupational Exposure limit valuesBiological limit values Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Eye/face protection Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Respiratory protection Wear dust mask when handling large quantities. Thermal hazards

Supplier and reference price

  • Manufacture/Brand
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  • Manufacture/Brand:Usbiological
  • Product Description:Sodium ethoxide
  • Packaging:250g
  • Price:$ 365
  • Delivery:In stock
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  • Manufacture/Brand:TRC
  • Product Description:SodiumEthoxide(>85%)
  • Packaging:1g
  • Price:$ 65
  • Delivery:In stock
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  • Manufacture/Brand:TCI Chemical
  • Product Description:Sodium Ethoxide (ca. 20% in Ethanol)
  • Packaging:500mL
  • Price:$ 55
  • Delivery:In stock
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  • Manufacture/Brand:TCI Chemical
  • Product Description:Sodium Ethoxide >95.0%(T)
  • Packaging:100g
  • Price:$ 29
  • Delivery:In stock
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  • Manufacture/Brand:Strem Chemicals
  • Product Description:Sodium ethoxide, 96%
  • Packaging:50g
  • Price:$ 16
  • Delivery:In stock
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  • Manufacture/Brand:Strem Chemicals
  • Product Description:Sodium ethoxide, 96%
  • Packaging:250g
  • Price:$ 68
  • Delivery:In stock
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  • Manufacture/Brand:Sigma-Aldrich
  • Product Description:Sodium ethoxide 95%
  • Packaging:100g
  • Price:$ 57.4
  • Delivery:In stock
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  • Manufacture/Brand:Sigma-Aldrich
  • Product Description:Sodium ethoxide solution 21 wt. % in ethanol
  • Packaging:500ml
  • Price:$ 74.4
  • Delivery:In stock
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  • Manufacture/Brand:Sigma-Aldrich
  • Product Description:Sodium ethoxide 95%
  • Packaging:500g
  • Price:$ 102
  • Delivery:In stock
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  • Manufacture/Brand:Sigma-Aldrich
  • Product Description:Sodium ethylate Msynth plus. CAS No. 141-52-6, EC Number 205-487-5., Msynth plus
  • Packaging:8451011000
  • Price:$ 138
  • Delivery:In stock
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Relevant articles and documentsAll total 311 Articles be found

Enhanced vapor-phase processing in fluorinated Fe4 single-molecule magnets

Rigamonti, Luca,Piccioli, Marco,Malavolti, Luigi,Poggini, Lorenzo,Mannini, Matteo,Totti, Federico,Cortigiani, Brunetto,Magnani, Agnese,Sessoli, Roberta,Cornia, Andrea

, p. 5897 - 5905 (2013)

A new tetrairon(III) single-molecule magnet with enhanced volatility and processability was obtained by partial fluorination of the ancillary β-diketonato ligands. Fluorinated proligand Hpta = pivaloyltrifluoroacetone was used to assemble the bis(alkoxido

A contamination-insensitive probe for imaging specific biomolecules by secondary ion mass spectrometry

Kabatas, Selda,Vreja, Ingrid C.,Saka, Sinem K.,H?schen, Carmen,Kr?hnert, Katharina,Opazo, Felipe,Rizzoli, Silvio O.,Diederichsen, Ulf

, p. 13221 - 13224 (2015)

Imaging techniques should differentiate between specific signals, from the biomolecules of interest, and non-specific signals, from the background. We present a probe containing 15N and 14N isotopes in approximately equal proportion, for secondary ion mass spectrometry imaging. This probe designed for a precise biomolecule analysis is insensitive to background signals.

Scavenging Reaction of Solvated Electron Produced by UV Laser from Iodide Anion in Liquid Beam

Matsumura, Hisashi,Mafune, Fumitaka,Kondow, Tamotsu

, p. 5861 - 5864 (1995)

A sodium iodide (NaI) solution in ethanol was introduced into vacuum as a continuous liquid flow (liquid beam) and irradiated with a 220 nm UV laser.Cluster cations containing ethoxide such as Na+(NaOEt), Na+(NaI)n(NaOEt) (n = 1-4), and Na+(NaI)n(NaOEt)2 (n = 1-4) were observed by a time-of-flight (TOF) mass spectrometer.Furthermore, addition of NH4+ or n-BuOH into the NaI ethanol solution resulted in suppressing the intensities of the peaks associated with these cluster ions.It is concluded that the ethoxide is produced by a scavenging reaction of a solvated electron with an ethanol molecule, and the reaction of the ethoxide formation competes with a scavenging reaction by NH4+ or n-BuOH.The rate equations of these competing processes predict the dependence of the ethoxide formation on the concentration of NH4+ or n-BuOH.Similar reaction products were observed from alcohol solutions of several iodides.

Characterization of new Co(II) complexes and photographic monitoring for their toxic impact on breast cancer cells according to simulation study

Shah, Reem,Habeebullah, Turki M.,Saad, Fawaz,Althagafi, Ismail,Al-dawood, Aisha Y.,Al-Solimy, Amerah M.,Al-Ahmed, Zehba A.,Al-Zahrani, Fatimah,Farghaly, Thoraya A.,El-Metwaly, Nashwa

, (2020)

Five new nitrogen-rich ligands (thioanhydrides) were synthesized and fully characterized. Then, their corresponding Co(II) complexes were prepared and also elucidated by analytical and spectral conformational techniques. First of all, the mono-negative tr

Synthesis of new polysubstituted (pyrazoles, pyrimidines and quinolines) five and six-membered heterocycles: Reaction of α,α-dioxoketene dithioacetals with nucleophiles

Ebraheem,Lokanatha Rai,Kudva.n,Bahjat

, p. 3486 - 3492 (2010)

A novel synthesis of polysubstituted pyrazoles 3a-d, pyrimidines 4a-f and quinolines 5a-c via the reaction of α,α-oxoketene dithioacetals 2a-c with hydrazine hydrate, malonohydrazide, urea, thiourea and aniline is reported and the synthetic potential of the method is demonstrated. The structure of the new compounds was established upon their elemental analysis, IR, 1H NMR and 13C NMR.

Synthesis and photophysical properties of europium pentafluorinated β-diketonate complexes

Wan, Yupeng,Lyu, Heng,Du, Hengyi,Wang, Dunjia,Yin, Guodong

, p. 1669 - 1687 (2019)

Two pentafluorinated β-diketone ligands, 4,4,5,5,5-pentafluoro-1-(4-methoxyphenyl)pentane-1,3-dione (PFMP) and 4,4,5,5,5-pentafluoro-1-(4-dimethyl amino-phenyl)pentane-1,3-dione (PFAP), had been employed to synthesize six novel europium (III) complexes wi

Iron(ii) complexes of 2,6-di(1H-pyrazol-3-yl)-pyridine derivatives with hydrogen bonding and sterically bulky substituents

Roberts, Thomas D.,Little, Marc A.,Kershaw Cook, Laurence J.,Halcrow, Malcolm A.

, p. 7577 - 7588 (2014)

Syntheses of 2,6-di(5-aminopyrazol-3-yl)pyridine (L1), 2,6-di(5-tertbutylcarboxamidopyrazol-3-yl)pyridine (L2), 2,6-di(5-tertbutylpyrazol-3-yl)pyridine (L3), 2-(5-tertbutylpyrazol- 3-yl)-6-(5-methylpyrazol-3-yl)pyridine (L4) and 2-(5- tertbutylpyrazol-3-yl)-6-(5-aminopyrazol-3-yl)pyridine (L5) are reported. Iron complex salts of the first four ligands were crystallographically characterised. The structures exhibit intermolecular hydrogen bonding between the cations and the anions and/or solvent, leading to a fluorite (flu) net, a 1D ladder structure, and a homochiral self-penetrating helical network related to the (10,3)-a (srs) topology. All the complexes are high-spin in the crystal, and bulk samples are also fully or predominantly high-spin at room temperature and below although two of the dried materials exhibit partial spin-state transitions on cooling. This journal is the Partner Organisations 2014.

Further studies on the biodegradation of ionic liquids

Ford, Leigh,Harjani, Jitendra R.,Atefi, Farzad,Garcia, M. Teresa,Singer, Robert D.,Scammells, Peter J.

, p. 1783 - 1789 (2010)

A range of ionic liquids (ILs) containing a pyridinium cation were synthesised and their biodegradability was evaluated using the CO2 headspace test (ISO 14593). ILs bearing a 1-(2-hydroxyethyl) side chain were prepared from either pyridine or nicotinic acid derivatives. These ILs showed high levels of biodegradation under aerobic conditions and can be classified as 'readily biodegradable'. In contrast, pyridinium ILs with methyl or ethyl ether side chains showed significantly lower levels of biodegradability in the same test. Biodegradation studies on a range of novel ILs with acetal and carbamate functionalities, as well as thiazolium-based salts, also showed low levels of mineralization.

The AAAA?DDDD hydrogen bond dimer. Synthesis of a soluble sulfurane as AAAA domain and generation of a DDDD counterpart

Taubitz, Joerg,Luening, Ulrich

, p. 1550 - 1555 (2009)

Sulfurane 5b with solubility enhancing substituents has been synthesized to be used as an AAAA recognition site in quadruple hydrogen bond heterodimers. A complementary DDDD partner [4b + H+] has been generated from a DDAD domain 4b by protonation. The association constant for the heterodimer complex formation has been determined by NMR titration in chloroform. CSIRO 2009.

Synthesis and nicotinic activity of epiboxidine: An isoxazole analogue of epibatidine

Badio, Barbara,Garraffo, H. Martin,Plummer, Carlton V.,Padgett, William L.,Daly, John W.

, p. 189 - 194 (1997)

Synthetic (±)-epiboxidine (exo-2-(3-methyl-5-isoxazolyl)-7-azabicyclo[2.2.1]heptane) is a methylisoxazole analog of the alkaloid epibatidine, itself a potent nicotinic receptor agonist with antinociceptive activity. Epiboxidine contains a methylisoxazolyl ring replacing the chloropyridinyl ring of epibatidine. Thus, it is also an analog of another nicotinic receptor agonist, ABT 418 ((S)-3-methyl-5-(1-methyl-2-pyrrolidinyl)isoxazole), in which the pyridinyl ring of nicotine has been replaced by the methylisoxazolyl ring. Epiboxidine was about 10-fold less potent than epibatidine and about 17-fold more potent than ABT 418 in inhibiting [3H]nicotine binding to α4β2 nicotinic receptors in rat cerebral cortical membranes. In cultured cells with functional ion flux assays, epiboxidine was nearly equipotent to epibatidine and 200-fold more potent than ABT 418 at α3β(4(5)) nicotinic receptors in PC12 cells. Epiboxidine was about 5-fold less potent than epibatidine and about 30-fold more potent than ABT 418 in TE671 cells with α1β1γδ nicotinic receptors. In a hot-plate antinociceptive assay with mice, epiboxidine was about 10-fold less potent than epibatidine. However, epiboxidine was also much less toxic than epibatidine in mice.

Crystal structure of sodium ethoxide (C2H5ONa), unravelled after 180 years

Beske, Maurice,Tapmeyer, Lukas,Schmidt, Martin U.

, p. 3520 - 3523 (2020)

As early as 1837, Liebig synthesised solid C2H5ONa. Today, C2H5ONa is one of the standard bases in organic synthesis. Here, we report the identification of different solid phases and the crystal structures and p

Eagle, S.,Warner, J. C.

, p. 488 - 495 (1939)

Substituent dependence on the spin crossover behaviour of mononuclear Fe(ii) complexes with asymmetric tridentate ligands

Saiki, Ryo,Miyamoto, Haruka,Shiga, Takuya,Oshio, Hiroki,Sagayama, Hajime,Kumai, Reiji,Newton, Graham N.

, p. 3231 - 3236 (2019)

Three mononuclear iron(ii) complexes of the formula [FeII(H2L1-3)2](BF4)2·x(solv.) (H2L1-3 = 2-[5-(R-phenyl)-1H-pyrazole-3-yl] 6-benzimidazole pyridine; H2L1: R = 4-methylphenyl, H2L2, R = 2,4,6-trimethylphenyl, H2L3, R = 2,3,4,5,6-pentamethylphenyl) (1, H2L1; 2, H2L2; 3, H2L3) with asymmetric tridentate ligands (H2L1-3) were synthesized and their structures and magnetic behaviour investigated. Significant structural distortions of the dihedral angles between phenyl and pyrazole groups were observed and found to depend on the nature of the substituent groups. Cryomagnetic studies reveal that 1 and 2 show gradual spin crossover behavior, while 3 remains in the high spin state between 1.8 and 300 K.

Molecular Routes to Group IV Magnesium and Calcium Nanocrystalline Ceramics

Petrus, Rafa?,Dr?g-Jarz?bek, Anna,Utko, Józef,Bykowski, Dominik,Lis, Tadeusz,Sobota, Piotr

, p. 11365 - 11374 (2017)

The effect of alkaline-earth-metal alkoxides on the protonolysis of Cp2M′Cl2 (M′ = Ti, Zr, Hf; Cp = cyclopentadiene) was investigated. This approach enabled the design of compounds with well-defined molecular structures to generate high-purity binary metal oxides. Single-source molecular precursors with structures of [M2M′2(μ3-OEt)2(μ-OEt)4(OEt)6(EtOH)4] with M = Mg and M′ = Ti (1), Zr (2), and Hf (3), [Ca6Ti4(μ6-O)2(μ4-O)2(μ3-OEt)12(OEt)12(EtOH)6Cl4] (4), and [M2M′2(μ4-O)(μ-OEt)5(OEt)4(EtOH)4Cl]n with M = Ca and M′ = Zr (5) and Hf (6) were prepared via elimination of the cyclopentadienyl ring from Cp2M′Cl2 as CpH in the presence of M(OEt)2 and ethanol (EtOH) as a source of protons. Meanwhile, similar reactions involving the initial substitution of Cl ligands by OEt groups in Cp2M′Cl2 (M′ = Ti, Zr, Hf) resulted in the formation of [M2M′2(μ3-OEt)2(μ-OEt)4(OEt)6(EtOH)4] with M = Ca and M′ = Ti (7), Zr (8), and Hf (9). The precursors were characterized by elemental analysis, NMR spectroscopy, and single-crystal X-ray structural analysis. Magnesium compounds 1-3 decomposed at 750-850 °C to give MgTiO3 along with small amounts of Mg2TiO4, Mg2Zr5O12, or Mg2Hf5O12 binary metal oxides. The thermolysis of calcium compounds 4 and 7-9 led to highly pure CaTiO3, CaZrO3, or CaHfO3 perovskite-like oxide particles with diameters of 20-30 nm.

Synthesis and characterization of new 5,5′-dimethyl- and 5,5′-diphenylhydantoin-conjugated hemorphin derivatives designed as potential anticonvulsant agents

Georgieva, Stela,Peneva, Petia,Rangelov, Miroslav,Tchekalarova, Jana,Todorov, Petar,Todorova, Nadezhda

, p. 2198 - 2217 (2022/02/16)

Herein, the synthesis and characterization of some novel N-modified hybrid analogues of hemorphins containing a C-5 substituted hydantoin residue as potential anticonvulsants and for the blockade of sodium channels are presented. Their structure-property relationships are highlighted by electrochemical and Fourier transform infrared spectroscopy (FT-IR) analysis methods. The lipophilicity and molecular docking of voltage-gated sodium channels were also determined. The new series of 5,5′-dimethyl- and 5,5′-diphenylhydantoin-conjugated hemorphin derivatives were obtained as C-terminal amides via solid-phase peptide synthesis, an Fmoc-strategy using 2-(1H-benzotriazole-1-yl)-1,1,3,3-tetramethylaminium tetrafluoroborate (TBTU). The anticonvulsant activity of the hybrid-peptides (0.25, 0.5 and 1 μg) was tested by maximal electroshock (MES) and 6 Hz psychomotor seizure tests using male ICR mice. None of the compounds tested showed neurotoxicity in the rotarod test. The reference drug phenytoin was used as a positive control. The most active compound Ph-5 showed 100% efficacy against the 6 Hz-induced psychomotor seizures at a dose of 1.0 μg and tonic seizures in the MES test at a lower dose of 0.5 μg. This analogue of VV-hemorphin-5 contained a 5,5′-diphenylhydantoin residue at the N-terminus and a hydrophobic Val-Val-Tyr-Pro-Trp-Thr-Gln-CONH2 amino acid sequence of the peptide molecule. The quantitative data for the 6 Hz test demonstrated that the peptide Ph-5 exhibited a median effective dose (ED50) value of 0.358 μg and PI >13.97, and ED50 of 0.25 μg and PI >20.35 in the MES test, respectively. Results from the docking study suggest that the neuropeptide Ph-5 is a potent inhibitor of sodium channels, and blockade of voltage-gated sodium channels could be the mechanism of action of the hybrid-peptide derivatives with anticonvulsant activity.

Catalyst system for producing polyethylene copolymers in a high temperature solution polymerization process

-

, (2022/03/27)

Catalyst system for producing ethylene copolymers in a high temperature solution process, the catalyst system comprising: (i) a metallocene complex of formula (I) wherein M is Hf or a mixture with Zr, provided that more than 50% by moles of the complex of Formula I has M=Hf; X is a sigma ligand; R are the same or different from each other and can be saturated linear or branched C1-C10 alkyl, C6-C10 aryl, C4-C10 heteroaryl, C6-C20 alkylaryl or C6-C20 arylalkyl groups, which can optionally contain up to 2 heteroatoms or silicon atoms; R1 is a C6-C10 aryl or C6-C20 alkylaryl group optionally containing up to 2 heteroatoms or silicon atoms or a C4-C10 heteroaryl group; R2 is a C4-C20 cycloalkyl group, optionally carrying alkyl substituents in beta-positions, of formula (II) in which R′ can be the same or can be different from each other and can be hydrogen or is defined as R and n is 1 to 17; and (ii) a boron containing cocatalyst.

Process route upstream and downstream products

Process route

C<sub>10</sub>H<sub>13</sub>N<sub>2</sub>O<sub>6</sub><sup>(1-)</sup>*Na<sup>(1+)</sup>

C10H13N2O6(1-)*Na(1+)

2,4-dinitro-1-ethoxybenzene
610-54-8

2,4-dinitro-1-ethoxybenzene

sodium ethanolate
141-52-6

sodium ethanolate

Conditions
Conditions Yield
In ethanol; at 25 ℃; Equilibrium constant;
sodium ethanolate
141-52-6

sodium ethanolate

guanidine nitrate
506-93-4

guanidine nitrate

Conditions
Conditions Yield
ethanol
64-17-5

ethanol

sodium cyclopentadienide

sodium cyclopentadienide

sodium ethanolate
141-52-6

sodium ethanolate

cyclopenta-1,3-diene
542-92-7,25568-84-7,7313-32-8

cyclopenta-1,3-diene

Conditions
Conditions Yield
Further Variations:; Reagents; Activation energy;
sodium ethanolate
141-52-6

sodium ethanolate

2-pyrimidinemethanol
42839-09-8

2-pyrimidinemethanol

Conditions
Conditions Yield
46%
disodium cyanamide
20611-81-8

disodium cyanamide

sodium ethanolate
141-52-6

sodium ethanolate

Conditions
Conditions Yield
With ethanol;
With ethanol;
1,2,3-triazole
288-36-8

1,2,3-triazole

sodium ethanolate
141-52-6

sodium ethanolate

Conditions
Conditions Yield
acetamidine hydrochloride
124-42-5

acetamidine hydrochloride

sodium ethanolate
141-52-6

sodium ethanolate

Conditions
Conditions Yield
oxalic acid diethyl ester
95-92-1

oxalic acid diethyl ester

spiro [4H-1-benzopyran-4,2'-pyrrolidine]3'-carboxylic acid

spiro [4H-1-benzopyran-4,2'-pyrrolidine]3'-carboxylic acid

sodium ethanolate
141-52-6

sodium ethanolate

Conditions
Conditions Yield
With sodium; In ethanol;
84%
diethyl malonate
105-53-3

diethyl malonate

sodium ethanolate
141-52-6

sodium ethanolate

Conditions
Conditions Yield
With sodium; In ethanol;
With sodium; In ethanol;
With sodium; In ethanol;
With sodium; In ethanol;
phenythoin
57-41-0

phenythoin

ethyl bromoacetate
105-36-2

ethyl bromoacetate

ethyl 2-(2,5-dioxo-4,4-diphenylimidazolidin-1-yl)acetate
976-85-2

ethyl 2-(2,5-dioxo-4,4-diphenylimidazolidin-1-yl)acetate

sodium ethanolate
141-52-6

sodium ethanolate

Conditions
Conditions Yield
In ethanol;
96%

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  • Hangzhou Dingyan Chem Co., Ltd
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  • Simagchem Corporation
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