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Carbon disulphide

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Name

Carbon disulphide

EINECS 200-843-6
CAS No. 75-15-0 Density 1.259 g/cm3
PSA 64.18000 LogP 1.01810
Solubility 2.9 g/L (20 °C) in water Melting Point -111 °C
Formula CS2 Boiling Point 46.22 °C at 760 mmHg
Molecular Weight 76.143 Flash Point -30 °C
Transport Information UN 1131 3/PG 1 Appearance colourless to light yellow liquid with an unpleasant odour
Safety 16-33-36/37-45-7 Risk Codes 11-36/38-48/23-62-63-39/23/24/25-23/24/25
Molecular Structure Molecular Structure of 75-15-0 (Carbon disulfide) Hazard Symbols FlammableF, ToxicT
Synonyms

Carbonbisulfide;Carbon bisulphide;Carbon sulfide (CS2);Dithiocarbonic anhydride;

Article Data 609

Carbon disulphide Synthetic route

56-23-5

tetrachloromethane

A

10025-67-9

disulfur dichloride

B

75-15-0

carbon disulfide

Conditions
ConditionsYield
byproducts: S(x)Cl2; (N2), bomb reed, heated at 250°C for 24 h; cooled in liquid air in vac., distd.;A 95%
B n/a
byproducts: S(x)Cl2; (N2), bomb reed, heated at 250°C for 15 h; cooled in liquid air in vac., distd.;A 86%
B n/a
byproducts: S(x)Cl2; (N2), bomb reed, heated at 210°C for 8 d; cooled in liquid air in vac., distd.;A 70%
B n/a
67-56-1

methanol

74-93-1

methylthiol

A

75-15-0

carbon disulfide

B

624-92-0

Dimethyldisulphide

C

3658-80-8

dimethyltrisulfane

Conditions
ConditionsYield
Stage #1: methanol; methylthiol With hydrogen sulfide; aluminum oxide with 14percent by weight of potassium tungstate at 400℃;
Stage #2: With sulfur; N-cyclohexyl-cyclohexanamine
A n/a
B 94.9%
C n/a

C33H39CuN2S2

A

75-15-0

carbon disulfide

B

C32H39CuN2

Conditions
ConditionsYield
In melt at 180℃; for 0.166667h; Inert atmosphere;A n/a
B 88%

graphite

7446-09-5

sulfur dioxide

A

75-15-0

carbon disulfide

B

23550-45-0

disulfur

C

463-58-1

carbon oxide sulfide

Conditions
ConditionsYield
byproducts: CO, CO2; at 1400 K, with excess of carbon;A 81.16%
B 10.82%
C 8.02%
byproducts: CO, CO2; at 1000 K, with excess of carbon;A 37.08%
B 3.22%
C 59.7%
67-66-3

chloroform

A

7647-01-0

hydrogenchloride

B

10025-67-9

disulfur dichloride

C

75-15-0

carbon disulfide

Conditions
ConditionsYield
(N2), bomb reed, heated at 205°C for 60 h; cooled in liquid air in vac. for a week, distd.; Raman spectr.;A n/a
B 80%
C n/a
56-23-5

tetrachloromethane

A

7647-01-0

hydrogenchloride

B

75-15-0

carbon disulfide

Conditions
ConditionsYield
With hydrogen sulfide In neat (no solvent) reaction of H2S with gaseous CCl4 on heating to 870°C; catalyst: asbestos powder;;A n/a
B 71.5%
With hydrogen sulfide In neat (no solvent) reaction of H2S with gaseous CCl4 on heating to 870°C;;A n/a
B 58%
With hydrogen sulfide In neat (no solvent) reaction of H2S with gaseous CCl4 on heating to 870°C;;A n/a
B 22.1%
505-60-2

bis (2-chloroethyl) sulphide

74-86-2

acetylene

A

188290-36-0

thiophene

B

75-15-0

carbon disulfide

C

95-15-8

Benzo[b]thiophene

D

71-43-2

benzene

Conditions
ConditionsYield
With disulfide oil at 650℃; for 1.75h; Further byproducts given;A 68%
B 0.09 g
C 0.12 g
D 0.25 g
17356-08-0

thiourea

A

75-15-0

carbon disulfide

B

Triguanidinium-trithiophosphat

C

Triguanidinium-tetrathiophosphat

Conditions
ConditionsYield
With tetraphosphorus decasulfide at 140℃; for 40h;A n/a
B 5%
C 58%
With ammonium hydroxide; tetraphosphorus decasulfide 1.) 40 h, 140 deg C; Yield given. Multistep reaction. Yields of byproduct given;
101855-29-2

C13H11NO4S2

A

75-15-0

carbon disulfide

B

6974-10-3

phthalimidoacetic acid ethyl ester

Conditions
ConditionsYield
at 150 - 200℃; for 0.5h; further O-alkyl-S-phthalylglycyl xanthates;A n/a
B 53%
143601-38-1

2,2-Dimethyl-1,3-diphenyl-7-thia-2-sila-bicyclo[3.2.0]hept-3-ene-6-thione

A

75-15-0

carbon disulfide

B

7688-03-1

1,1-dimethyl-2,5-diphenylsilole

Conditions
ConditionsYield
In tetrahydrofuran for 67h; Irradiation; or 180 deg C, 15 h;A n/a
B 40%

Carbon disulphide Chemical Properties

Molecular Formula: CS2
Molecular Weight: 76.139 g/mol 
EINECS: 200-843-6
Flashing point: -30 °C
Index of Refraction: 1.627
Density: 1.262 g/mL
Vapour Pressure: 352 mmHg at 25 °C
Boiling Point: 46 °C
Melting point: -111 °C
Storage tempreture: 2-8 °C
Water solubility: 2.9 g/L at 20 °C
Solubility: Soluble in water
Sensitive: Hygroscopic
Appearance: Colourless to light yellow liquid with an unpleasant odour
Structure of Carbon disulphide (CAS NO.75-15-0):
                   
IUPAC Name: Methanedithione
Product Category of Carbon disulphide (CAS NO.75-15-0): Inorganics;Pesticides;Stable Isotopes;Aluminum Bottles;Alphabetical Listings

Carbon disulphide Uses

 Carbon disulphide (CAS NO.75-15-0) is used frequently as a building block in organic chemistry as well as an industrial and chemical non-polar solvent.

Carbon disulphide Production

 Carbon disulphide (CAS NO.75-15-0) once was manufactured by combining carbon and sulfur at high temperatures. A lower temperature reaction, requiring only 600 °C utilizes natural gas as the carbon source in the presence of silica gel or alumina catalysts.

Carbon disulphide Toxicity Data With Reference

1.    

mmo-sat 100 µL/plate

    NIOSH*    National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda 5AUG77 .
2.    

sce-hmn:lym 10,200 µg/L

    BCTKAG    Bromatologia i Chemia Toksykologiczna. 14 (1981),115.
3.    

ihl-hmn LCLo:4000 ppm/30M

    29ZWAE    Practical Toxicology of Plastics Lefaux, R.,Cleveland, OH.: Chemical Rubber Company,1968,118.
4.    

ihl-hmn LCLo:2000 ppm/5M

    TABIA2    Tabulae Biologicae. 3 (1933),231.
5.    

unr-man LDLo:186 mg/kg

    85DCAI    Poisoning; Toxicology, Symptoms, Treatments. 2 (1970),73.
6.    

orl-rat LD50:3188 mg/kg

    GISAAA    Gigiena i Sanitariya. 31 (1)(1966),13.
7.    

ihl-rat LC50:25 g/m3/2H

    85GMAT    Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure Izmerov, N.F., et al.,Moscow, USSR.: Centre of International Projects, GKNT,1982,32.
8.    

orl-mus LD50:2780 mg/kg

    GISAAA    Gigiena i Sanitariya. 31 (1)(1966),13.
9.    

ihl-mus LC50:10 g/m3/2H

    85GMAT    Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure Izmerov, N.F., et al.,Moscow, USSR.: Centre of International Projects, GKNT,1982,32. GISAAA    Gigiena i Sanitar

Carbon disulphide Consensus Reports

Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. Community Right-To-Know List. EPA Extremely Hazardous Substances List.

Carbon disulphide Safety Profile

Hazard Codes: FlammableF,ToxicT
Risk Statements: 11-36/38-48/23-62-63-39/23/24/25-23/24/25 
R11:Highly flammable. 
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed. 
R36/38:Irritating to eyes and skin. 
R48:Danger of serious damage to health by prolonged exposure. 
R62:Risk of impaired fertility. 
R63:Possible risk of harm to the unborn child.
Safety Statements: 16-33-36/37-45-7 
S7:Keep container tightly closed. 
S16:Keep away from sources of ignition. 
S33:Take precautionary measures against static discharges. 
S36/37:Wear suitable protective clothing and gloves. 
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)

Carbon disulphide Standards and Recommendations

OSHA PEL: TWA 4 ppm; STEL 12 ppm (skin)
ACGIH TLV: TWA 10 ppm (skin); BEI: 5 mg (2-thiothiazolidine-4-carboxylic acid (TTCA))/g creatinine in urine
DFG MAK: 5 ppm (16 mg/m3); BAT: 8 mg/L of 4-thio-4-thiazolidine carboxylic acid (TTCA) at end of shift
NIOSH REL: (Carbon Disulfide) TWA 1 ppm; CL 10 ppm/15M
DOT Classification:  3; Label: Flammable Liquid, Poison

Carbon disulphide Analytical Methods

For occupational chemical analysis use NIOSH: Carbon Disulfide, 1600.

Carbon disulphide Specification

 Carbon disulphide , its cas register number is 75-15-0. At very high levels, carbon disulfide may be life-threatening because it affects the nervous system. Significant safety data come from the viscose rayon industry, where both carbon disulfide as well as small amounts of H2S may be present. A human poison by unspecified route. Human reproductive effects on spermatogenesis by inhalation. Experimental teratogenic and reproductive effects. The main toxic effect is on the central nervous system, acting as a narcotic and anesthetic in acute poisoning with death following from respiratory failure. Flammable liquid. A dangerous fire hazard when exposed to heat, flame, sparks, friction, or oxidizing materials. Severe explosion hazard when exposed to heat or flame. Ignition and potentially explosive reaction when heated in contact with rust or iron. Mixtures with sodium or potassium-sodium alloys are powerful, shock-sensitive explosives. Explodes on contact with permanganic acid. Potentially explosive reaction with nitrogen oxide, chlorine (catalyzed by iron). Reacts with metal azides to produce shock- and heat-sensitive, explosive metal azidodithioformates.
 Carbon disulphide (CAS NO.75-15-0) is hazardous, so the first aid measures and others should be known. Such as: When on the skin: first, should flush skin with plenty of water immediately for at least 15 minutes while removing contaminated clothing. Secondly, get medical aid. Or in the eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Then get medical aid soon. While, it's inhaled: Remove from exposure and move to fresh air immediately. Give artificial respiration while not breathing. When breathing is difficult, give oxygen. And as soon as to get medical aid. Then you have the ingesting of the product: Do not induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water, and get medical aid immediately. Notes to physician: Effects may be delayed. Observe patient.

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