Journal of the American Chemical Society p. 6095 - 6097 (1980)
Update date:2022-08-03
Topics: Reactivity Solvent Experimental
Steele, Kent P.
Weber, William P.
The insertion of dimethylsilylene into the oxygen-hydrogen single bond of alcohols to yield alkoxydimethylsilanes has been used to probe the effect of solvent on dimethylsilylene reactivity.Competition reactions between pairs of alcohols for dimethylsilylene in various solvents have been carried out.The selectivity of dimethylsilylene is influenced by solvent.Dimethylsilylene is more selective in ether than in hydrocarbon solvents.This difference may result from the formation of complexes between donor solvents and dimethylsilylene.These complexes can deliver dimethylsilylene which is less reactive and more selective than free dimethylsilylene.
View MoreShao Xing Empire Import&Export CO.,ltd
Contact:86-575-82127757
Address:11#, Weiwu Road, Shangyu Industrial Park, Hangzhou Bay, Hangzhou, Zhejiang Province, China
Contact:021-36356756
Address:Room601,Building No.14,280 Yangcheng Road,Shanghai
Suzhou Howsine Biological Technology Co.,Ltd(expird)
website:http://www.howsine.com
Contact:86-512-67262751
Address:No 3,Weihua Road ,Suzhou Industrial Park ,Jiangsu ,China.
Zhushan County Tianxin Pharmaceutical & Chemical Co., Ltd.
Contact:0086-719-4224892
Address:Tutang Road, Chengguan Town, Zhushan County, Hubei Province
Chongqing Shuangfeng Chemical Co.,Ltd
Contact:+86-23-49850156
Address:No.663,xuanhua Rd,yongchuan,chongqing,China
Doi:10.1055/s-2008-1078246
(2008)Doi:10.1021/ja00265a032
(1986)Doi:10.1021/ja01156a536
(1951)Doi:10.1016/j.tet.2003.10.098
(2004)Doi:10.1002/ejoc.200700558
(2007)Doi:10.1016/j.ejmech.2018.07.002
(2018)
