Journal of the American Chemical Society p. 6095 - 6097 (1980)
Update date:2022-08-03
Steele, Kent P.
Weber, William P.
The insertion of dimethylsilylene into the oxygen-hydrogen single bond of alcohols to yield alkoxydimethylsilanes has been used to probe the effect of solvent on dimethylsilylene reactivity.Competition reactions between pairs of alcohols for dimethylsilylene in various solvents have been carried out.The selectivity of dimethylsilylene is influenced by solvent.Dimethylsilylene is more selective in ether than in hydrocarbon solvents.This difference may result from the formation of complexes between donor solvents and dimethylsilylene.These complexes can deliver dimethylsilylene which is less reactive and more selective than free dimethylsilylene.
View MoreShaanxi HuaTai Bio-fine chemical company Ltd
Contact:86-029-87862197
Address:No. 5, 3rd Floor, 29 Yanta North Road, Beilin Dist.
Shanghai Yuking Water Soluble Material Tech Co., Ltd
Contact:86-21-68286299
Address:4F, 13B, No. 600, South Xinyuan Road 201306, Shanghai, China
Xinchang Yueding Chemical Co., Ltd.
Contact:86-571-56926323
Address:NO.90 BEIMENCHENGWAI CHENGGUAN TOWN XINCHANG
Suzhou Health Chemicals Co., Ltd.
website:http://www.healthchems.com
Contact:13776257979
Address:No. 338, Jingang Avenue,
Shanghai Haoyuan Chemexpress Co., Ltd.
Contact:86-21-51870955;58998985;58999585
Address:Room 601, No. 2 BLD, NO. 720, Cailun Road, Zhangjiang, Shanghai, China
Doi:10.1055/s-2008-1078246
(2008)Doi:10.1021/ja00265a032
(1986)Doi:10.1021/ja01156a536
(1951)Doi:10.1016/j.tet.2003.10.098
(2004)Doi:10.1002/ejoc.200700558
(2007)Doi:10.1016/j.ejmech.2018.07.002
(2018)