Journal of the American Chemical Society p. 7778 - 7786 (1986)
Update date:2022-09-26
Topics: Stereoselective Asymmetric Induction Reaction Chiral imines
Yamamoto, Yoshinori
Nishii, Shinji
Maruyama, Kazuhiro
Komatsu, Toshiaki
Ito, Wataru
The reaction of allyl-9-borabicyclo<3.3.1>nonane (allyl-9-BBN) with chiral imines 3 produced the Cram isomer 4 either exclusively or very predominantly.The very high 1,2-asymmetric induction is explained by a six-membered chairlike transition state, in wh
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(1986)
