HYDRIDO-SILYL-KOMPLEXE. VI. ELEKTRONISCHE UND STERISCHE EINFLUESSE VON PHOSPHIN-LIGANDEN AUF DIE AKTIVIERUNGS-PARAMETER DER REDUKTIVEN ELIMINIERUNG VON DIPHENYLSILAN AUS (η5-CH3C5H4)(CO)(PR3)Mn(H)SiHPh2-KOMPLEXEN

DOI: 10.1016/0022-328X(85)87402-7

Source and publish data:

Journal of Organometallic Chemistry p. 247 - 256 (1985)

Update date:2022-09-26

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Authors:

Kraft, G.

Kalbas, C.

Schubert, U.

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Article abstract of DOI:10.1016/0022-328X(85)87402-7

The photochemical reaction of diphenylsilane or diethylsilane with (η⁵-CH3C5H4)(CO)2(PR3)Mn gives the hydrido silyl complexes of the type (η⁵-CH3C5H4)(CO)(PR3)Mn(H)SiHR'2 containing Mn-H-Si three-centre bonds (R'=Ph: PR3=PMe3, PBu View More

Full text of DOI:10.1016/0022-328X(85)87402-7

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