An Efficient Synthesis of Dialkyl 2-Oxoalkanephosphonates and Diphenyl-2-oxoalkylphosphine Oxides from 1-Chloralkyl Ketones

DOI: 10.1055/s-1985-31424

Source and publish data:

Synthesis p. 1048 - 1051 (1985)

Update date:2022-08-04

Topics:

Authors:

Corbel, Bernard

Medinger, Luc

Haelters, Jean Pierre

Sturtz, Georges

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1055/s-1985-31424

The synthesis of dialkyl 2-oxoalkanephosphonates and diphenyl-2-oxoalkylphosphine oxides, via an Arbuzov reaction of trialkyl phosphites or ethoxydiphenylphosphine with methoxycarbonylhydrazono derivatives of 1-chloroalkyl ketones followed by carbonyl deprotection, is described.

Full text of DOI:10.1055/s-1985-31424

Products guided by the article

Product name:N'-[2-Chloro-1-phenyl-eth-(Z)-ylidene]-hydrazinecarboxylic acid methyl ester

Cas No:100677-59-6

R&D Labs maybe for 100677-59-6

Fujian Wanke Pharmaceutical Co., LTD.

Contact:+86-598-5026002

Address:Economic development zone,jiangle county
Hangzhou Zyter Biological & Chemical Technology Co., Ltd.

website:http://www.zyterpharm.com

Contact:+86-18858184290

Address:West Wenyi Road, Cangqian, Yuhang
Jurong Huaheng Natural Biological Products Factory

website:http://www.risebiochem.com

Contact:+86-13921007726

Address:Chuncheng town,Jurong city,Jiangsu province,China
Anyang Double Circle Auxiliary CO.,LTD

Contact:0086-134 6082 4403

Address:dongfeng road, anyang city, henan province,china
shijiazhuang alkay chemicals co..ltd(expird)

Contact:86-311-67692035

Address:2601,juntang building,qiaodong district,shijiazhuang

Relevant to this article

Efficient synthesis of 6-substituted purine derivatives using Pd-catalyzed cross-coupling reactions with 2'-deoxyguanosine O⁶-tosylate

Doi:10.3987/COM-07-S(U)24
(2007)
ORGANOPALLADIQUES ISSUS DES ESTERS D'ALCOOLS α-ALLENIQUES: REACTIONS AVEC LES ANIONS DELOCALISES.

Doi:10.1016/S0040-4020(01)81635-5
(1987)
Doi:10.1016/S0040-4020(01)81636-7
(1987)
Novel germanium(II) binaphthoxide complexes

Doi:10.1039/b204299a
(2002)
Chemistry of unsaturated group 6 metal complexes with bridging hydroxy and methoxycarbyne ligands. 6. C-E bond formation and C-O bond cleavage processes in the reactions of [Mo₂(η⁵-C₅H ₅)₂(μ-COMe)(μ-PCy₂)(μ-CO)] with several p -block elements (E) and their hydride derivatives

Doi:10.1021/om100117a
(2010)
Stereocontrolled synthesis of (S)-9-cis- and (S)-11-cis-13,14-dihydroretinoic acid

Doi:10.1016/j.tet.2016.05.006
(2016)

Article Doi