An Efficient Synthesis of Dialkyl 2-Oxoalkanephosphonates and Diphenyl-2-oxoalkylphosphine Oxides from 1-Chloralkyl Ketones

DOI: 10.1055/s-1985-31424

Source and publish data:

Synthesis p. 1048 - 1051 (1985)

Update date:2022-08-04

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Authors:

Corbel, Bernard

Medinger, Luc

Haelters, Jean Pierre

Sturtz, Georges

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Article abstract of DOI:10.1055/s-1985-31424

The synthesis of dialkyl 2-oxoalkanephosphonates and diphenyl-2-oxoalkylphosphine oxides, via an Arbuzov reaction of trialkyl phosphites or ethoxydiphenylphosphine with methoxycarbonylhydrazono derivatives of 1-chloroalkyl ketones followed by carbonyl deprotection, is described.

Full text of DOI:10.1055/s-1985-31424

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